Abstract: Fire protection and/or fire fighting additives including a water-swellable polymer, a water immiscible phase, an emulsifier, an inverter, and a remainder water are disclosed. The water-swellable polymer is acrylamide-free and crosslinked and may be prepared by inverse phase polymerization. Such fire protection and/or fire fighting additives and fire protection and/or fire fighting compositions made using the additives exhibit exceptionally low corrosion properties. For example, when contacted with any one of a 2024-T3 aluminum alloy, 4130 steel, yellow brass, or AZ31B magnesium alloy, the corrosion rate is less than about 5 mils/yr for the fire protection and/or fire fighting additives.