Abstract: To apply a thermal barrier coating (10), a plasma jet (5) is generated by a plasma torch in a work chamber (2) and is directed to the surface of a substrate (3) introduced into the work chamber, and a ceramic coating material is applied to the substrate surface by means of PS-PVD, wherein the coating material is injected into the plasma jet as a powder and is partly or completely vaporized there. On applying the thermal barrier coating, in a first workstep the feed rate of the injected powder is set so that a large part of the injected powder vaporizes, wherein the coating material condenses from the vapor phase on the substrate surface and forms mixed phases with the material of the substrate surface.

Abstract: A system for gas separation has a mechanically stable metallic substrate layer having a pair of opposite faces and formed throughout with open pores. Respective functional layers laminated on each of the faces are composed of TiO2 or ZrO2. These functional layers are formed throughout with pores having an average pore diameter of less than 1 nm.

Abstract: A heat-insulating material has a first phase with the stoichiometric composition of 0.1 to 10 mol-% M12O3, 0.1 to 10 mol-% Li2O, and as the remainder M22O3 with possible impurities. M1 is selected from the elements lanthanum, neodymium, gadolinium, or a mixture thereof, and M2 is selected from the elements aluminum, gallium, iron, or a mixture thereof. The first phase is present in a magnetoplumbite structure.

Abstract: The invention relates to a method for the hydrothermal production of a microporous membrane. According to said method, a colloidal solution comprising zeolite frameworks with 4-ring, 6-ring, and/or 8-ring pores which are provided as crystallites whose size ranges from 2 to 25 nm is applied to a porous substrate with the aid of a wet application technique. The applied layer is contacted with a hydrothermal liquid, and a nanocrystalline, microporous zeolite layer having an average pore diameter of 0.2 to 0.45 nm is synthesized at temperatures ranging between 50 and 250° C. and at an autogenous pressure. Such a microporous membrane comprising a porous substrate and at least one nanocrystalline zeolite layer that is disposed thereupon and has an average pore diameter of 0.2 to 0.45 nm is advantageously suitable for use as a separating device for gas phase separation, making it possible to separate particularly N2O2, N2/CO2, H2/CO2, or CO2/CH4 gas mixtures.

Abstract: The aim of the invention is to produce complete high temperature fuel cells by means of thermal injection processes (e.g. atmospheric plasma injection, vacuum plasma injection, high speed flame injection). The production method is especially simplified and is economical by virtue of the fact that the carrier substrate is also produced on a base with the aid of a thermal injection method. The base or an intermediate layer placed thereon can be advantageously dissolved or decomposed such that the carrier substrate provided with layers arranged thereon can be separated in a very simple manner from the base which becomes unnecessary. Said method advantageously enables the production of all layers of a high temperature fuel cell, exclusively with the aid of a thermal injection method.

Abstract: The invention relates to a method for producing a device for gas separation, said device comprising a layer system wherein a functional layer consisting of TiO2 and/or ZrO2 having an average pore diameter of less than 1 nm is applied to at least one side of a carrier layer that is porous throughout. Said carrier layer is preferably between 100 ?m and 1 mm thick and comprises continuous pores with an average pore diameter in the ?m range. The functional layer which is applied directly or by means of at least one intermediate layer comprises continuous pores with an average pore diameter of less than 1 nm, especially less than 0.8 nm. The functional layer can advantageously be embodied as a graduated layer. The invention is especially characterised by the symmetrical structure of the device, in which functional layers are applied to both sides of the carrier layer, optionally by means of respectively at least one intermediate layer.

Abstract: A heat-insulating layer has a melting point above 2500° C., a thermal expansion coefficient in excess of 8×10?6 K?1, and a sintering temperature greater than 1400° C. This material has a perovskite structure of the general formula A1+r(B?1/2+xB?1/2+y)O3+z in which: A=at least one element of the group (Ba, Sr, Ca, Be), B?=at least one element of the group (Al, La, Nd, Gd, Er, Lu, Dy, Tb), B?=at least one element of the group (Ta, Nb), and 0.1<r, x, y, z<0.1.

Abstract: A heat-insulating material has a melting point above 2500° C., a thermal expansion coefficient in excess of 8×10?6 K?1, and a sintering temperature greater than 1400° C. It has a perovskite structure of the general formula A1+r(B?1/3+xB?2/3+y)O3+z where A=at least one element of the group (Ba, Sr, Ca, Be), B?=at least one element of the group (Mg, Ca, Sr, Ba, Be), B?=at least one element of the group (Ta, Nb), r, x, and z?0, and ?0.1<r, x, y, z<0.1; or of the general formula A1+r(B?1/2+xB?1/2+y)O3+z where A and B? are as above and B?=at least one element of the group (Al, La, Nd, Gd, Er, Lu, Dy, Tb), and ?1.0<r, x, y, z<0.1.

Abstract: The invention relates to a heat-insulating material, which is phase-stable particularly for high temperatures above 1150° C., especially above 1200° C., and which has a very good long-time stability. The heat-insulating material can exist in a number of phases of which at least one has the magnetoplumbite structure and stoichiometrically contains 0.1 to 10 mol % M12O3, 0.1 to 10 mol % Li2O and, as the remaining, M22O3 with incidental impurities. M1 is selected from the following elements: lanthanum, neodymium and gadolinium or mixtures thereof, and M2 is selected from the following elements: aluminum, gallium, iron or a mixture thereof. A particularly advantageous composition arises for this phase with the composition LaLiAl11O18.5 or LaLi0.5Al11.5O19. By using conventional methods, the heat-insulating material can be applied to the components subjected to a high level of thermal stress, for example, turbine blades.

Abstract: The invention relates to a method for producing a tight crystalline mullite layer on a metallic and/or ceramic substrate by using the plasma spraying technique. To this end, a sol containing mullite precursors with a proportion of 2 to 25% by weight with regard to the oxides (3 Al2O3/2 SiO2) is used as a spraying additive. This method is carried out under atmospheric conditions, and the sol is injected with a focussed jet and with an overpressure of at least one I bar into the plasma flame. An additional compacting of the layer can be advantageously effected by repeatedly passing over the layer with the plasma flame. The method is particularly suited for applying a gas-tight crystalline mullite layer to a steel substrate.

Abstract: A porous near-net-shape metallic parts with an open porosity of at least 10% by volume is made by first forming an injectable mass of a metallic powder of stainless steel, Ti, NiTi, or a titanium alloy, at least one thermoplastic binder, and at least one place holder. The mass then injection molded into the shape of the part to be produced, cooled, set in a capillary-active material, and subjected to a first-stage binder removal to produce an open porosity. The place holder is then removed at least partially from the part with a fluid, and the part is subjected to a thermal binder-removing process. Finally the part is sintered.

Abstract: The invention relates to a high-temperature resistant seal, particularly a seal for use in a high-temperature fuel cell. The inventive seal comprises a structured metallic layer having at least one area on whose surface a filler is placed. The filler is comprised, in particular, of clay minerals or ceramic materials. The seal thus advantageously combines the sealing properties of a metallic layer, for example, of an undulated metal foil with the elastic properties of the filler. The seal is particularly suited for use at high temperatures and thus, for example, in high-temperature fuel cells.

Abstract: The invention relates to a cathode material, particularly for use in a high-temperature fuel cell, comprising substoichiometric Ln1-x-yMyFe1-zCzO3-?, with 0.02?×x?0.05, 0.1?y?0.6, 0.1?z?0.3, 0???0.25 and with Ln=lanthanides, M=strontium or calcium and C=cobalt or copper. By using a particular production method, in which this cathode material having a specified grain size is used, and in which a (Ce, Gd)O2-?-intermediate layer is advantageously formed between the cathode and electrolyte, a cathode is obtained that, when used in a high-temperature fuel cell, can achieve a power greater than 1 W/cm2 already at 750° C. and a cell voltage of 0.7 V.

Abstract: The aim of the invention is to produce complete high temperature fuel cells by means of thermal injection processes (e.g. atmospheric plasma injection, vacuum plasma injection, high speed flame injection). The production method is especially simplified and is economical by virtue of the fact that the carrier substrate is also produced on a base with the aid of a thermal injection method. The base or an intermediate layer placed thereon can be advantageously dissolved or decomposed such that the carrier substrate provided with layers arranged thereon can be separated in a very simple manner from the base which becomes unnecessary. Said method advantageously enables the production of all layers of a high temperature fuel cell, exclusively with the aid of a thermal injection method.

Abstract: The invention relates to a method for producing highly porous, metallic molded bodies. The inventive method consists of the following steps: a metallic powder used as a starting material is mixed with a dummy; a green body is pressed out of the mixture; the green body is subjected to conventional mechanical machining, the dummy advantageously increasing the stability of the green body; the dummy material is thermally separated from the green body by means of air, a vacuum or an inert gas; and the green body is sintered to form the molded body and is then advantageously finished. Suitable materials for the dummy are, for example, ammonium bicarbonate or carbamide. The mechanical machining carried out before the sintering advantageously enables a simple production close to the desired final contours, even for complicated geometries of the molded body to be produced, without impairing the porosity, and without high wear of the tools.

Abstract: Disclosed is a modified powder injection molding method which is advantageously used for producing highly porous, near net-shaped parts having complex geometries from initial metallic and/or ceramic powders. The placeholders that are used are non-toxic and can be quickly and almost entirely removed from the parts. Said placeholders make it possible to specifically adjust the pore sizes of the parts within a range of 20 ?m to 2 mm and the porosities thereof within a range of 10 to 85 percent by volume, the distribution of pores being very homogeneous. The duration of the entire process is determined to a considerable degree by the removal of the binder and the placeholders. The total time required from the step of preliminary surface-active binder removal is no more than 14 to 20 hours, even if preliminary thermal binder removal is added (for metal powders and ceramic powders <20 ?m).

Abstract: The invention relates to a heat-insulating layer made of a heat-insulating material which has a complex perovskite structure, having a melting point greater than 2500° C. and a thermal coefficient of expansion greater than 8*10?6 K?1 in addition to a sintering temperature of more than 1400° C. The inventive heat insulating material is characterised by a first general formula A1+r(B?1/3+xB?2/3+y)03+2, wherein: A=at least one element from the group (Ba, Sr, Ca, Be), B?=at least one element from the group (Mg, Ca, Sr, Ba, Be), B?=at least one element from the group (Ta, Nb) and ?0.1<r, x, y, z<0,1; or by a second general formula A1+r(B?1/2+x, B?1/2 +y)03 +2, wherein: A =at least one element from the group (Ba, Sr, Ca, Be), B?=at least one element from the group (Al, La, Nd, Gd, Er, Lu, Dy, Th), B?=at least one element from the group (Ta, Nb) and ?0, 1<r, x, y, z<0,1.

Abstract: The invention relates to a method for producing highly porous, metallic moulded bodies. The inventive method consists of the following steps: a metallic powder used as a starting material is mixed with a dummy; a green body is pressed out of the mixture; the green body is subjected to conventional mechanical machining, the dummy advantageously increasing the stability of the green body; the dummy material is thermally separated from the green body by means of air, a vacuum or an inert gas; and the green body is sintered to form the moulded body and is then advantageously finished. Suitable materials for the dummy are, for example, ammonium bicarbonate or carbamide. The mechanical machining carried out before the sintering advantageously enables a simple production close to the desired final contours, even for complicated geometries of the moulded body to be produced, without impairing the porosity, and without high wear of the tools.

Abstract: The invention relates to a material, in particular for a thermal insulation layer, with increased thermal stability, a low heat conductivity and a large thermal coefficient of expansion. According to the invention, said material comprises lanthanides, in particular the elements La, Ce, Nd, Yb, Lu, Er or Tm, which preferably occur as a mixture in a Perovskite structure. Said thermal insulation layer is particularly suitable for replacing thermal insulation layers comprising yttrium stabilized zirconium oxides (YSZ) as the thermal stability thereof is given as well over 1200° C.

Abstract: The invention relates to a high-temperature resistant seal, particularly a seal for use in a high-temperature fuel cell. The inventive seal comprises a structured metallic layer having at least one area on whose surface a filler is placed. The filler is comprised, in particular, of clay minerals or ceramic materials. The seal thus advantageously combines the sealing properties of a metallic layer, for example, of an undulated metal foil with the elastic properties of the filler. The seal is particularly suited for use at high temperatures and thus, for example, in high-temperature fuel cells.