Abstract: An electrochemical cell that cycles lithium ions includes a positive electrode that includes a positive electroactive material, a negative electrode that includes a silicon-containing negative electroactive material, a separating layer disposed between the positive electrode and the negative electrode, and an electrolyte that is in contact with at least one of the positive electroactive material, the negative electroactive material, and the separating layer. The electrolyte includes greater than or equal to about 0.1 wt. % to less than or equal to about 10 wt. % of a phosphite-type additive.

Abstract: A negative electrode for an electrochemical cell that cycles lithium includes a negative electrode including an electroactive material layer disposed on a current collector that has lithiated silicon oxide (LSO) negative electroactive material at ? about 10 weight % to ? about 30 weight % of a total weight of the electroactive material layer and a carbonaceous negative electroactive material, such as graphite. An electrochemical cell that incorporates such a negative electrode may also include a second electrode comprising a porous positive active material layer comprising a positive lithium containing, nickel-rich electroactive material, such as a lithium nickel manganese cobalt aluminum oxide, a porous separating layer disposed between the first electrode and the second electrode and an electrolyte disposed in pores of the separating layer.

Abstract: A battery cell includes a cathode electrode comprising a cathode coating arranged on a cathode current collector and a separator. A dual function interlayer comprising capacitor material and lithium-ion source material is arranged one of between the cathode coating and the cathode current collector and between the cathode coating and the separator. An anode electrode is arranged adjacent to the separator and comprising an anode coating arranged on an anode current collector.

Abstract: A vehicle system is provided and includes a modular dynamically allocated capacity storage system (MODACS) and an active management module. The MODACS includes blocks of cells. The active management module is configured to: detect a first state of a first block of cells of the blocks of cells; determine whether a safety fault condition exists with the first block of cells based on the first state of the first block of cells; in response to detecting existence of the safety fault condition, isolate the first block of cells from other ones of the blocks of cells; subsequent to isolating the first block of cells, actively discharge and detect a second state of the first block of cells; and based on the second state, continue isolating the first block of cells or reconnecting the first block of cells such that the first block of cells is no longer isolated.

Abstract: A battery module includes C battery cells, wherein each of the C battery cells comprises a housing and a terminals extending from the housing. T thermal interlayer devices are arranged between adjacent ones of the C battery cells. C and T are integers greater than one. Each of the T thermal interlayer devices comprises a first thermally conducting layer in thermal communication with a first one of the C battery cells, a second thermally conducting layer in thermal communication with a second one of the C battery cells, and a thermally resistant layer arranged between the first thermally conducting layer and the second thermally conducting layer. A cooling manifold is in thermal communication with at least one of the first thermally conducting layer and the second thermally conducting layer.

Abstract: An electrode for an electrochemical cell includes a silicon-containing electroactive material that includes a plurality of silicon-containing electroactive material particles and a polymeric network that forms polymeric cages around each of the silicon-containing electroactive material particles of the plurality. The polymeric cages include polyacrylic acid (PAA), lithiated polyacrylic acid (PAALi), or a combination of polyacrylic acid (PAA) and lithiated polyacrylic acid (PAALi) covalently bonded with poly(2-hydroxyethyl acrylate) (PHEA). The polymeric network has a mass ratio of the polyacrylic acid (PAA), the lithiated polyacrylic acid (PAALi), or the combination of the polyacrylic acid (PAA) and the lithiated polyacrylic acid (PAALi) to the poly(2-hydroxyethyl acrylate) (PHEA) of greater than or equal to about 0.5 to less than or equal to about 10.

Abstract: Hybrid electrochemical cells and modules include an anode two-sided current collector a coated with host material in anode region(s) and a cathode two-sided current collector coated with active material in cathode region(s), and one or more of the anode current collector and the cathode current collector is coated with capacitor material in one or more distinct, non-overlapping capacitor regions. A hybrid anode and/or cathode can include gaps between capacitor regions and anode regions and cathode regions. The capacitor material applied to an electrode is different from the host or active material thereof. Active material includes lithium metal oxides and lithium metal phosphates such as LiFePO4, Li(NixMnyCoz)O2, and/or LiMn2O4; host material includes graphite, silicon, silicon-Li/Sn/Cu alloys, Si/Co/Fe/TiSn oxides, and low-surface area carbon; and capacitor material includes activated carbon, metal oxides, and metal sulfides.

Abstract: A battery includes: an anode electrode including a lithium metal; a cathode electrode; and a lithium fluoride (LiF) layer disposed on at least one of the anode electrode and the cathode electrode formed via a reaction between a polytetrafluoroethylene (PTFE) layer and the at least one of anode electrode and the cathode electrode during a formation process of the battery.

Abstract: A mixed chemistry battery is provided. The mixed chemistry battery includes a reference module having a first chemistry and a battery module having a second chemistry that is different that the first chemistry, the battery module is connected to the reference module in series. The mixed chemistry battery also includes a battery monitoring system configured to monitor an open circuit voltage of the reference module, an open circuit voltage of the battery module, and a current flow through the reference module and the battery module. The battery monitoring system is further configured to calculate a state-of-charge (SOC) and state-of-health (SOH) of the battery module based at least in part on a SOC of the reference module.

Abstract: The present disclosure provides a modified binder for use in an electrochemical cell that cycles lithium ions. The modified binder includes one or more agglomerates of polytetrafluoroethylene nanoparticles, where each of the polytetrafluoroethylene nanoparticles includes a polytetrafluoroethylene core and a polymeric shell that is disposed on exposed surfaces of the core. The polymeric shell can include a polymer selected from the group consisting of: polyethylene oxide, polyglycidyl methacrylate, polyvinylidene difluoride, fluoride-hexafluoropropylene, polypropylene oxide, polyacrylonitrile, polymethacrylonitrile, polymethyl methacrylate, derivatives and co-polymers, and combinations thereof, and in certain instances, also a humidity tolerant lithium salt.

Abstract: A battery system for a vehicle includes: first and second positive terminals and a negative terminal; switches; at least three strings of battery cells, each of the strings configured to, at different times be: connected to the first positive terminal via first ones of the switches; connected to the second positive terminal via second ones of the switches; and disconnected from both of the first and second positive terminals; and a switch control module configured to: identify one of a short circuit and an over voltage condition in a first voltage bus; when the one of the short circuit and the over voltage condition is identified, identify N of the strings of battery cells with the N lowest state of health values; and control switching of the switches and connect the identified N strings of battery cells to the first voltage bus.

Abstract: A low-voltage mitigation and recovery system includes: an auxiliary power module that converts an output voltage of a power source of a vehicle to a charging voltage, the power source provides power to power a propulsion system of the vehicle; a contactor that supplies power from the power source to the auxiliary power module; a first control module that controls states of the auxiliary power module and the contactor. A second control module is integrated within a MODACS, monitors parameters of blocks of cells of the MODACS, and, based on at least one of the parameters: configures a switch network of the MODACS to disconnect a first set of blocks of the MODACS from loads and to connect or maintain connection of a second set of blocks of the MODACS to selected ones of the loads; and wakes up the first control module to jump start and recover the MODACS.

Abstract: A method of manufacturing an electrode for an electrochemical cell includes providing an admixture including an electroactive material, a binder, and a solvent. The method further includes rolling the admixture to form a sheet and forming a multi-layer stack from the sheet. The method further includes forming an electrode film precursor by performing a plurality of sequential rollings, each including rolling the stack through a first gap. The plurality of sequential rollings includes first and second rollings. In the first rolling, the stack is in a first orientation. In the second rolling, the stack is in a second orientation different from the first orientation. The method further includes forming an electrode film by rolling the electrode film precursor through a second gap less than or equal to the first gap. The method further includes drying the electrode film to remove at least a portion of the solvent.

Abstract: A method for fabricating a dual-layer capacitive cabode electrode includes fabricating a first film including capacitive active material; fabricating a second film including cathode active material; hot jointing the first film and the second film to create a cabode film; and laminating the cabode film onto opposite sides of a current collector using conductive adhesive.

Abstract: A battery system for a vehicle includes: a first positive terminal, a second positive terminal, and a negative terminal; switches; at least two battery modules each including at least three strings of battery cells that are configured to, at different times be: connected in series and to the first positive terminal via first ones of the switches; connected in parallel and to the second positive terminal via second ones of the switches; and disconnected from both of the first and second positive terminals; and a switch control module configured to, based on a derated state of the vehicle, adjust at least one of an upper limit for charging of the battery strings and a lower limit for discharging of the battery strings.

Abstract: The present disclosure provides an electrochemical device that cycles lithium ions. The electrochemical device includes at least one first cell unit and at least one second cell unit. The at least one first cell unit includes a nickel-rich positive electroactive material. The nickel-rich positive electroactive material can be represented by: LiM1xM2yM3zM4(1-x-y-z)O2 where M1, M2, M3, and M4 are each a transition metal independently selected from the group consisting of: nickel, manganese, cobalt, aluminum, and combinations thereof, where 0?x?1, 0?y?1, and 0?z?1. The at least one second cell unit includes a phosphate-based positive electroactive material. The phosphate-based electroactive material can be selected from the group consisting of: lithium manganese iron phosphates (LiMnxFe1-xPO4, where 0?x?1) (LMFP), lithium vanadium oxygen phosphates (LixVOPO4, where 0?x?1), lithium vanadium phosphates, lithium vanadium fluorophosphates, and combinations thereof.

Abstract: A method of making a capacitor-assisted hybrid electrode for a lithium-ion electrochemical cell includes admixing a solvent, a cellulose-based dispersant, and a plurality of capacitive particles comprising carbon to form a dispersion. The cellulose-based dispersant forms hydrogen bonds with one or more carbonyl-groups on the capacitive particles comprising carbon. The dispersion is combined with an electroactive material, an electrically conductive material, and a binder to form a slurry. The slurry is applied to a current collector and solidified to form the capacitor-assisted hybrid electrode having a composite hybrid active layer on the current collector. Capacitor-assisted hybrid electrodes formed from such methods are also provided.

Abstract: An electrode assembly for an electrochemical cell that cycles lithium ions is provided. The electrode assembly includes one or more electroactive material layers including a plurality of electroactive material particles and a plurality of binder material fibers dispersed with the electroactive material particles. At least one electroactive material particle of the plurality may have a first protective layer coated thereon, and at least one binder material fiber of the plurality may have a second protective layer coated thereon. The first and second protective layers may be the same or different. The binder material fibers can include polytetrafluoroethylene (PTFE).

Abstract: A state of health (SOH) based control system includes: a memory configured to store an algorithm including instructions for determining a SOH of a power source; and a control module configured to receive a voltage signal indicating a voltage of the power source and execute the instructions. The instructions include: determining a state of charge (SOC) of the power source; generating a differential signal based on a change in the voltage and a change in the state of charge; determining an inflection point and an end of charge point of the differential signal; determining the SOH of the power source based on the inflection point and the end of charge point; and performing at least one of a control operation or a countermeasure based on the SOH.

Abstract: A battery cell comprises C electrodes each including a first current collector, first and second capacitive layers, and first and second active material layers. The first and second capacitive layers and the first and second active material layers are arranged on the first current collector. E anode electrodes include a second current collector and third and fourth active material layers arranged on the second current collector. E and C are integers greater than zero.