Abstract: The present disclosure discloses a method for preparing a hierarchical porous material for a molecular sieve with an MFI structure. In the present disclosure, porous silicon dioxide is used as a carrier on a surface of which a nano zeolite seed is loaded, and then subjected to treatment with a secondary growth compound fluid and hydrothermal crystallization, so that a nano zeolite molecular sieve membrane is further grown on the surface of the porous silicon dioxide. The specific surface area and pore volume of the hierarchical porous material for the molecular sieve with the MFI structure prepared by the present disclosure are greatly improved compared with those of the original porous silicon dioxide. The material not only has the macroporous structure of the porous silicon dioxide, but also incorporates micropores of the molecular sieve itself and mesopores formed by molecular sieve agglomeration.