Abstract: The present invention relates to an ethylene polymer comprising moieties according to formula (I): wherein R is a moiety comprising ?1 and ?10 carbon atoms; wherein the ethylene polymer has a molecular weight distribution of ?3.0 and ?13.0; the ethylene polymer has a melting temperature of ?115° C.; the ethylene polymer has a density ?935 and ?960 kg/m3; the ethylene polymer is essentially free from chromium, hafnium, zirconium and tetrahydrofuran; for the fraction of the ethylene polymer having a molecular weight ?100 kg/mol, the intrinsic viscosity of the ethylene polymer is related to the molecular weight according to the inequality: log I. V. <0.65*log M?3.10 Such polymers have high density, high purity and good processability, whilst maintaining barrier properties for oxygen and water vapour at a level similar to high-density polyethylenes produced via catalytic processes.

Abstract: The present invention relates to a process for the production of ethylene polymers in a tubular reactor comprising reacting in said tubular reactor a feed composition comprising ethylene and one or more composition comprising one or more cyclic olefin wherein the cyclic olefin is a compound having the structure of Formula (I): wherein R may be a moiety comprising ?1 and ?10 carbon atoms; wherein R1 and R2 may each individually be hydrogen or a moiety comprising ?1 and ?5 carbon atoms, R1 and R2 may be the same or different; wherein ? the tubular reactor may be operated at a pressure of ?200 and ?280 MPa; ? the average reaction peak temperature may be ?220° C. and ?300° C.; ? the composition comprising one or more cyclic olefin may be fed to the reactor in one or more feed inlet of said tubular reactor; and ? said cyclic olefin may be fed to the tubular reactor in quantities of ?1.0 mol %, with regards to the total feed composition.

Abstract: The present invention relates to an ethylene polymer comprising moieties according to Formula (IB): wherein R is a moiety comprising ?1 and ?10 carbon atoms; wherein R1 and R2 are each individually hydrogen or a moiety comprising ?1 and ?5 carbon atoms, R1 and R2 may be the same or different; wherein the ethylene polymer has a molecular weight distribution of ?3.0 and ?40.0; the ethylene polymer has a melting temperature of ?115° C.; the ethylene polymer has a density ?935 and ?960 kg/m3; the ethylene polymer is essentially free from chromium, hafnium, zirconium and tetrahydrofuran; for the fraction of the ethylene polymer having a molecular weight >100 kg/mol, the intrinsic viscosity of the ethylene polymer is related to the molecular weight according to the inequality: log I.V.<0.65*log M?3.

Abstract: The invention relates to a high-pressure polymerisation process for the preparation of polyethylene. A polymer is added to the extruder via a side feed dosage unit wherein the MFIsf of the polymer added via the side feed dosage unit has a higher value than the melt flow index (MFLend) of the polyethylene end product and wherein the Mw/Mn of the end product increases at least 15% compared to the product wherein no polymer is dosed via the side feed.

Abstract: A process for increasing purity of a low density polyethylene (LDPE) composition, comprising the steps of: a) providing a melted composition comprising LDPE having Mn of at least 5.0 kg/mol according to size exclusion chromatography, Mw of at least 50 kg/mol according to size exclusion chromatography, a density of 915 to 935 kg/m3 according to ISO1183 and a melt flow rate of 0.10 g/10 min to 80 g/10 min according to ISO1133:2011 measured at 190° C. and 2.16 kg, and b) providing particles from the melted composition by: b1) mixing a supercritical fluid in the melted composition to obtain a solution saturated with the supercritical fluid and b2) expanding the solution through an opening to obtain the particles.

Abstract: A process for preparing an ethylene copolymer in the presence of free-radical polymerization initiator at pressures from 150 MPa to 350 MPa and temperatures from 100° C. to 350° C., by copolymerizing ethylene and a comonomer having a C?C bond and optionally further comonomers, wherein the comonomer having the C?C bond is represented by formula wherein R1 is hydrogen or methyl; X1 is —CO—O— or —CO—NH—; R2 is —CH2—O—, —O—CO—, —Si(CH3)2—, —Si(CH3)2—O— or —CR5R6— wherein R5 and R6 are independently selected from hydrogen, methyl, ethyl and hydroxyl; n is an integer from 1 to 32 and R2 is same or different from each other when n is 2 to 32; and R3 is —C?C— and R4 is hydrogen, C1-C10 linear or branched alkyl, C1-C10 linear or branched hydroxyalkyl or phenyl, or the unit R3-R4 stands for wherein X2 is F, Cl, Br or I.

Abstract: The invention relates to a high pressure polymerisation process for the preparation of the polyethylene wherein the polymerisation process takes place in the presence of a cobalt containing complex. The cobalt containing complex may be a complex according to Formula (I): Formula (I) wherein y1, y2, y3 and y4 may, independently of one another be the same or different, H, (C1C20) alkyl, (C5-C20) cycloalkyl, (C6-C10) aryl radical, phenyl or hydroxy-phenyl.

Abstract: The invention relates to a high pressure polymerisation process for the preparation of the polyethylene wherein the polymerisation process takes place in the presence of a cobalt containing complex. The cobalt containing complex may be a complex according to Formula (I): Formula (I) wherein y1, y2, y3 and y4 may, independently of one another be the same or different, H, (C1C20) alkyl, (C5-C20) cycloalkyl, (C6-C10) aryl radical, phenyl or hydroxy-phenyl.