Abstract: A device for the chemical analysis of solid or molten material samples, based on laser-induced emission spectroscopy, including a laser source generating a laser beam, a deflection device deflecting the laser beam, a focusing device focusing the laser beam, a device that guides the reflections of a plasma ignited by the laser beam on the material sample to an evaluation device. To arrange the laser source and the evaluation device remotely from the material sample, an arm having at least one movable joint and a cavity for the laser beam is provided between the laser source and the material sample for guiding the laser beam. The deflection device is shaped as a mirror or a prism and is provided at the articulation of the arm, whereby the laser source and the evaluation device are arranged to be independent of the material sample in terms of their movements.

Abstract: For producing a superconducting circuit, a film (12) consisting of a cuprate superconductor material is generated on a substrate (13), wherein the superconductor material is in the superconducting state at an operating temperature of the superconducting circuit to be produced, and then the film is irradiated by projecting an energetic ion radiation onto the film through a mask (11) positioned at a distance from the film and protecting selected areas of the film from being irradiated, the mask comprising a structure pattern transparent to the ion radiation but otherwise opaque to the ion radiation. Areas (14) not protected by the mask are irradiated with an ion dose being sufficiently low to avoid degradation of the crystal structure of the first film but being sufficient to inhibit superconductivity of the film with respect to the operating temperature; ion doses are preferably in the range of 0.8·1015 and 2·1015 ions/cm2 or below.

Abstract: A device for the chemical analysis of solid or molten material samples (8), based on the laser-induced emission spectroscopy, is provided with a laser source (10) generating a laser beam (11), a deflection device deflecting the laser beam, a focusing device focusing the laser beam (11) as well as a device (14) that guides the reflections (26) of a plasma (25) ignited by the laser beam (11) on the material sample (8) to an evaluation device (28) such as a spectrometer.

Abstract: The invention relates to a process for producing supported shell catalysts comprising noble metals by UV photoreduction of noble metal salt precursors fixed to a support. For this purpose, the shaped supported body is impregnated with suitable noble metal salts which are then reduced to the metals in a zone close to the surface by means of UV radiation, preferably in the absence of a chemical reducing agent. The metal salts in the interior of the pellets which have not been irradiated and therefore have not been reduced are extracted using a solvent. The noble metal shell catalysts produced in this way can be used for many heterogeneously catalyzed reactions such as hydrogenations and oxidations. According to the invention, Pd/Au shell catalysts on porous ceramic supports, e.g. SiO2 shaped bodies, produced by this process can be used in the synthesis of vinyl acetate.

Abstract: The invention relates to a process for producing supported shell catalysts comprising noble metals by UV photoreduction of noble metal salt precursors fixed to a support. For this purpose, the shaped supported body is impregnated with suitable noble metal salts which are then reduced to the metals in a zone close to the surface by means of UV radiation, preferably in the absence of a chemical reducing agent. The metal salts in the interior of the pellets which have not been irradiated and therefore have not been reduced are extracted using a solvent.The noble metal shell catalysts produced in this way can be used for many heterogeneously catalyzed reactions such as hydrogenations and oxidations.According to the invention, Pd/Au shell catalysts on porous ceramic supports, e.g. SiO.sub.2 shaped bodies, produced by this process can be used in the synthesis of vinyl acetate.