Patents by Inventor Dieter H. Klein

Dieter H. Klein has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6245835
    Abstract: An emulsified reactive epoxy polymer composition which is readily dispersed in water particularly suited for use in a coating composition which may be cured at ambient temperatures. The emulsified composition incorporates a hydrophilic polyoxyalkylene segment.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: June 12, 2001
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Hans Juergen Wessely, Karin C. Joerg
  • Patent number: 6225376
    Abstract: An emulsified reactive epoxy polymer composition which is readily dispersed in water and is particularly suited for use in a coating composition which may be cured at ambient temperatures. The emulsifiable epoxy composition incorporates a hydrophilic polyoxyalkylene segment.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: May 1, 2001
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Karin C. Joerg
  • Patent number: 5567748
    Abstract: A water miscible or soluble amine terminated resin useful as a curing agent comprising the reaction product of: A) a polyamine component comprising one or more hydrophilic poly(oxyalkylene) amines, and optionally one or more hydrophobic polyamines; B) a polyepoxide component comprising one or more diglycidyl ethers of a polyalkylene glycol, one or more diglycidyl ethers of a cycloalkylene glycol and optionally one or more hydrophobic polyglycidyl ethers, wherein the mixture is optionally advanced by an amine extender; C) optionally, a reactive diluent which is capable of reacting with an epoxy resin, and D) optionally, a catalyst for the reaction of an amine with an epoxy resin; wherein Component A is employed in an equivalent excess with respect to Component B such that the terminal moieties of the reaction product are amine moieties capable of reacting with an epoxy resin; the composition has an amine hydrogen equivalent weight of from 140 to 240; and the composition is water soluble or water miscible.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: October 22, 1996
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Hans J. Wessely
  • Patent number: 5344856
    Abstract: The invention is a water dispersible epoxy resin composition comprising:(A) the reaction product of;(i) one or more polyepoxides;(ii) optionally, one or more poly(aromatic hydroxy) containing compounds,(iii) optionally, one or more chain terminators; and(iv) one or more nominally difunctional C.sub.12-36 fatty acids or a dimer of an unsaturated, fatty acid, andB) a sufficient amount of a surfactant to form a stable dispersion of the epoxy resin in water wherein the surfactant comprises an alkyl aryloxy poly(propyleneoxy) poly(ethyleneoxy) ethanol, a C.sub.12-36 hydrocarbyloxy poly(propyleneoxy) poly(ethyleneoxy) ethanol or a C.sub.12-36 hydrocarbylcarboxyloxy poly(propyleneoxy) poly(ethyleneoxy) ethanol. In another aspect the invention is a high solid aqueous emulsion of such epoxy resin reaction product and surfactant.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: September 6, 1994
    Assignee: The Dow Chemical Company
    Inventor: Dieter H. Klein
  • Patent number: 4698401
    Abstract: A polyfunctional reaction product having functional phenolic OH groups is made available by reacting a phenol and an alkoxylated amino-aldehyde condensation product in the presence of a solvent and of an acid catalyst. This method makes it possible to prepare a polyfunctional phenolic reaction product which is soluble in organic solvents at a low ratio of phenolic OH groups to alkoxy groups without gelling. The reaction product is particularly useful as a curing agent for epoxy resins.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: October 6, 1987
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Raymond Koenig
  • Patent number: 4661568
    Abstract: The epoxy resin composition is comprised of an epoxy resin, a solvent and a hardener which is the reaction product of a hexa-alkyl ether of a methylol melamine having the general formula (I), wherein each R, independently, is an alkyl radical having from 1 to 4 carbon atoms with a polyhydric phenol and, optionally, a monohydric phenol, with the phenol compound(s) having been employed in an amount to provide a ratio of at least one reactive phenolic hydroxy group for each alkoxy group.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: April 28, 1987
    Assignee: The Dow Chemical Company
    Inventors: Raymond Koenig, Robert Urscheler, Dieter H. Klein
  • Patent number: 3993716
    Abstract: The formation of non-aqueous polymeric dispersions, solutions, hydrosols and collodial suspensions by polymerizing vinyl monomers (A) in a hydrocarbon medium containing dissolved therein a stabilizing component (B) comprising an acrylic polymer previously formed from acrylic monomers (E). The invention comprises use, in (B), of minor proportions of (2-(1-aziridinyl)-ethyl- methacrylate to provide, by reason of its high reactivity, higher molecular weight backbones (B) and simultaneously by reason of its high functionality, to provide active sites for grafting side chains onto backbone (B). Furthermore, the reactivity thereof can make the final product self-cross-linking. The above system produces a dispersion of a vinyl polymer (C) formed from the polymerized vinyl monomers (A) in the hydrocarbon medium wherein a modified stabilizer (D) is formed either in situ from a precursor or in a preliminary separate step by grafting a portion of the vinyl monomers (A) onto the soluble polymeric stabilizer backbone (B).
    Type: Grant
    Filed: September 22, 1970
    Date of Patent: November 23, 1976
    Assignee: Dow Badische Company
    Inventors: Dieter H. Klein, Russell H. Cramm
  • Patent number: 3976614
    Abstract: Aqueous dispersions of interpolymers containing a base monomer such as styrene or methyl methacrylate, an alkylene glycol monomer such as (tripropylene glycol methyl ether) acrylate and a,b-ethylenically unsaturated carboxylic acid such as acrylic acids are useful as low viscosity coating compositions which can be cured to water resistant coatings.
    Type: Grant
    Filed: December 26, 1974
    Date of Patent: August 24, 1976
    Assignee: The Dow Chemical Company
    Inventors: W. Jay Elms, Dieter H. Klein
  • Patent number: 3950594
    Abstract: A dielectric coating for use on electroconductive papers consisting essentially of an interpolymer containing about 80 parts by weight of vinylidene chloride and at least about 1 part by weight of a vinyl acid, said interpolymer being obtained by polymerization in non-aqueous dispersion (NAD) comprising a strongly hydrogen bonded dispersing media containing from about 0.1 to 20 percent of a preformed dispersion stabilizer comprising the reaction product of (A) tripropylene glycol methylether acrylate and (B) at least one reactive comonomer capable of forming a side chain on said stabilizer which side chain is dispersible in said vinylidene chloride interpolymer and wherein the mass ratio of (A) to (B) is from about 99:1 to 80:20.
    Type: Grant
    Filed: May 31, 1973
    Date of Patent: April 13, 1976
    Assignee: The Dow Chemical Company
    Inventors: Ronald W. Hohlfeld, Dieter H. Klein