Abstract: This invention provides a separating agent for optical isomers, which has high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of the optical isomers, and a separation column for optical isomers having the same. This invention provides: a separating agent for optical isomers which is used for separation of optical isomers in a sample comprising the optical isomers, which is comprising a monolithic inorganic type carrier having a meso pore formed on an inner wall surface of a specific macropore, and a polysaccharide or a polysaccharide derivative supported on the monolithic inorganic type carrier, wherein the meso pore has a pore size of 6 to 100 nm; and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube.

Abstract: This invention provides a separating agent for optical isomers, which has high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of the optical isomers, and a separation column for optical isomers having the same. This invention provides: a separating agent for optical isomers which is used for separation of optical isomers in a sample comprising the optical isomers, which is comprising a monolithic inorganic type carrier having a meso pore formed on an inner wall surface of a specific macropore, and a polysaccharide or a polysaccharide derivative supported on the monolithic inorganic type carrier, wherein the meso pore has a pore size of 6 to 100 nm; and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube.

Abstract: The present invention relates to a process for the production of monolithic separating columns using monolithic moldings whose diameter is reduced by grinding, and to separating columns having improved separation efficiency produced in this way, and to the use thereof.

Abstract: This invention provides a separating agent for optical isomers, which has high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of the optical isomers, and a separation column for optical isomers having the same. This invention provides: a separating agent for optical isomers which is used for separation of optical isomers in a sample comprising the optical isomers, which is comprising a monolithic inorganic type carrier having a meso pore formed on an inner wall surface of a specific macropore, and a polysaccharide or a polysaccharide derivative supported on the monolithic inorganic type carrier, wherein the meso pore has a pore size of 6 to 100 nm; and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube.

Abstract: This invention provides a separating agent for optical isomers, which has high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of the optical isomers, and a separation column for optical isomers having the same. This invention provides: a separating agent for optical isomers which is used for separation of optical isomers in a sample comprising the optical isomers, which is comprising a monolithic inorganic type carrier having a meso pore formed on an inner wall surface of a specific macropore, and a polysaccharide or a polysaccharide derivative supported on the monolithic inorganic type carrier, wherein the meso pore has a pore size of 6 to 100 nm; and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube.

Abstract: The present invention relates to inorganic monolithic mouldings whose surface is coated with physi- or chemisorbed organic polymers, and to processes for the production of materials of this type. The materials according to the invention are highly suitable as sorbents for chromatography, in particular for high pressure liquid chromatography of biological materials.

Abstract: The present invention relates to a process for the production of monolithic separating columns using monolithic moldings whose diameter is reduced by grinding, and to separating columns having improved separation efficiency produced in this way, and to the use thereof.

Abstract: The present invention relates to capillaries which are at least partially sheathed with metal foil and to the use thereof in the coupling of methods such as HPLC, CE (capillary electrophoresis), CEC (capillary electrochromatography) or pCEC (pressurised CEC) to MS (mass spectrometry). The sheathing according to the invention with metal foil enables direct coupling of the capillaries to a mass spectrometer without using further adapters, such as spray needles or empty capillary parts.

Abstract: The present invention relates to a process for the surface modification of solid support materials, in particular chromatography materials, using silanes, in which the surface modification is carried out in the presence of ionic liquids.

Abstract: The invention relates to a device (1) for processing samples (2), comprising a body (3) with a collecting chamber (4), which can be connected with a pump (5) for aspirating, or dispensing fluids and that acts on this collecting chamber, a separating chamber (6) adjoining the collecting chamber (4) for the solid phase extraction and elution of organic, or inorganic particles (7) separated from these samples (2), and an opening (8) for releasing these particles (7). The device in accordance with the invention relates to individual pipette tips, as well as to SPE microplates, and is distinguished in that the device (1) comprises a capillary (9), which is connected with the collecting chamber (4), or with the body (8), and has a packing (10) for the solid phase extraction of organic, or inorganic particles (7) separated from these samples (2) and is used as a separating chamber (6).

Abstract: The invention relates to a method for producing open tubular capillaries containing monolithic sorbents and to said capillaries. The inventive capillaries are characterised by a connection layer between the capillary wall and the sorbent, said layer ensuring a particularly good adhesion of the sorbent to the capillary wall.

Abstract: This invention provides a separating agent for optical isomers, which has high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of the optical isomers, and a separation column for optical isomers having the same. This invention provides: a separating agent for optical isomers which is used for separation of optical isomers in a sample comprising the optical isomers, which is comprising a monolithic inorganic type carrier having a meso pore formed on an inner wall surface of a specific macropore, and a polysaccharide or a polysaccharide derivative supported on the monolithic inorganic type carrier, wherein the meso pore has a pore size of 6 to 100 nm; and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube.

Abstract: The invention relates to the use of gelation moulds made from hydrophobicized glass tubes for the production of monolithic mouldings as sorbents for chromatography.

Abstract: The invention relates to a process for the production of chromatography columns or capillaries containing sorbents of monolithic mouldings which can remain directly in their gelation mould after production. This is achieved by the process according to the invention, in which the gelation mould is repeatedly filled with the monomer sol.

Abstract: The invention relates to the process for the preparation of N,N-disubstituted imidazolium salts, N-heterocyclic carbene ligands and ruthenium catalysts containing N-heterocyclic carbene ligands, i.e. compounds of the general formulae (I) and, (II), compounds of the general formulae (III) and (IV) and compounds of the general formulae (V) and (VI), immobilised on inorganic oxide supports. The invention furthermore relates to the use of the immobilised compounds of the general formulae (I-IV) in organic, organometallic or transition metal-catalysed synthesis and to the use of the compounds of the general formulae (V) and (VI) as catalysts in organic and organometallic synthesis, in particular for C—C coupling reactions, such as olefin metathesis.

Abstract: The present invention relates to inorganic monolithic mouldings whose surface is coated with physi- or chemisorbed organic polymers, and to processes for the production of materials of this type. The materials according to the invention are highly suitable as sorbents for chromatography, in particular for high pressure liquid chromatography of biological materials.

Abstract: The use of a support material for capillary electrochromatography is disclosed, wherein the support material, which is based on a base material containing hydroxy groups, has reversed phases which are limited to the inner surfaces of porous particles, said reversed phases consisting of fatty acid residues. Further, separating capillaries suitable for such a use are disclosed.

Abstract: The invention relates to monolithic sorbents with a casing of fiber-reinforced plastic. Through the use of fiber-reinforced plastic having a viscosity of between 40 and 100 ml/10 min by the MVI method, the casing can be applied to the moulding leaving just a small dead space and has adequate mechanical stability.

Abstract: This invention relates to a stationary phase for solid phase microextraction (SPME) comprising a surface built up by a RAM (restricted access material) phase, a device for SPME comprising said stationary phase and a method for SPME using said stationary phase. The RAM SPME stationary phases according to the invention are robust, providing many direct extractions and subsequent determinations, while overcoming the present disadvantages of direct sampling of biological matrices by SPME.

Abstract: The present invention relates to a support for catalysts which has a content of physisorbed water of at least 2.5% by weight. Further subject-matters of the application are a process for preparing heterogeneous catalysts containing these supports and the use of these catalysts for olefin polymerization and also a polymerization process using the catalysts.