Abstract: A process whereby an optical fiber is hermetically coated with a layer of aluminum oxide. The fiber is reacted pyrolytically with organo aluminum derivatives or other aluminum compounds, either in the form of vapor or atomized spray, to produce the desired coating. The thickness can be varied by changing reaction parameters. A buffer is also applied to the coated fiber. The end product is a glass fiber impervious to gases and fluids in the environment, especially H.sub.2 O, and one of improved abrasion resistance, hardness and strength.

Abstract: An optical fiber which has just been drawn from an optical preform is provided with an external hermetic coating by using a heterogeneous nucleation thermochemical deposition technique. This technique involves passing the fiber through a reaction zone which contains a gaseous medium that includes a reactant which decomposes, or a mixture of reactants which chemically react, at a predetermined temperature to form the material of the coating. Only the fiber but not the gaseous medium surrounding the same is heated to the predetermined temperature, especially by directing radiation onto the exposed circumferential surface of the fiber, so that the decomposition or the chemical reaction takes place directly on the exposed surface of the fiber rather than in the gaseous medium, accompanied by simultaneous deposition of the coating material on the exposed surface of the fiber. The resulting fiber with hermetic coating can then be provided with an additional polymer coating layer.

Abstract: A metallic material coating is applied to the external surface of a freshly drawn optical fiber while such surface is still pristine by passing the optical fiber through a body of liquid metal-organic material which forms a layer on the fiber, and by subsequently removing all non-metallic components from the layer of metal-organic material by volatilizing the same. The optical fiber with the layer metal-organic material is passed through a baking oven in which at least the layer is heated to a baking temperature at which organic materials present in the metal-organic material are volatilized and the remainder is baked to the fiber. Then, at least the layer is fired in a firing chamber at a higher temperature at which the metal-organic material is decomposed into its volatile non-metallic and non-volatile metallic components, the latter remaining in the layer and the former becoming volatile and leaving the layer.

Abstract: A tubular formation of particulate optical material is formed by a layer slurry deposition process which involves spraying layer after layer of slurry containing particles of the optical material onto a rotating rod-shaped bait. The composition of the slurry and particularly the index of refraction of the optical material may be varied from one layer to another or from one group of layers to another to obtain a graded or stepped refraction index profile in the formation, in an optical preform formed therefrom, and ultimately in the fiber drawn from the optical preform. The particles of the slurry are suspended in a liquid vehicle which evaporates in the spray stream or shortly after deposition, and are coated with an organic binder which holds them together in the layer and in the formation, so that the formation is self-supporting. Then, the organic binder is removed and the formation is sintered, followed by a collapse of the sintered tubular formation into the optical preform in the form of a solid rod.

Abstract: Hydroxyl free deposition with high efficiency and at a high deposition rate may be achieved, even with use of relatively inexpensive raw materials, by utilizing a ring-shaped plasma activated axial chemical vapor deposition obtaining 100% chemical conversion and fractional volatilization of impurities. The plasma is induced in an annular stream of a plasma-forming gaseous medium, and the reactant or reactants used in the axial chemical vapor deposition are introduced into the center of the ring-shaped plasma to be converted by the heat of the plasma flame into soot which is deposited on a bait. An annular stream of a cooling medium flows outwardly past the plasma flame and is circumferentially centered by an extension of the outer tubular element of a plasma torch in which the plasma is generated. An RF generator which induces the plasma is operated at a frequency exceeding 20 MHz to give the plasma flame the desired ring-sloped configuration.

Abstract: In order to provide a high power heat source having a very clean and invariable heat flux, a ring plasma is induced in a heating zone of a plasma torch including a plurality of coaxial tubular elements and the optical fiber is drawn through a channel passing axially through the center of the plasma torch and of the ring-shaped plasma. In this manner the preform from which the fiber is drawn can be placed in close proximity to the induced plasma without exposure to non-symmetrical temperature variations. Cooling gas passes through the heating zone either in an annular stream surrounding the plasma or in an annular stream passing through the center of the plasma around the preform and the fiber being drawn, or both. The heating zone is protected from environmental disturbances by an extension of the outer tubular element of the plasma torch which surrounds the heating zone.