Abstract: A process for the production of a coating layer on a three-dimensional shaped substrate, comprising the steps: (1) providing a three-dimensional shaped substrate, (2) initial application of a coating layer on the surface of the substrate from a coating composition curable by free-radical polymerization of olefinic double bonds on UV irradiation and (3) irradiating the coated substrate with UV radiation; wherein the coating composition contains the following constituents: A) at least one free-radically polymerizable binder containing olefinically unsaturated groups, B) optionally, at least one free-radically polymerizable monomeric reactive diluent containing one or more olefinically unsaturated groups, C) at least one photoinitiator for free-radical polymerization, and D) at least one metal compound.

Abstract: A process for the preparation of a coating layer comprising the steps: (a) applying a coating layer to a substrate from a coating agent of which the resin solids comprise a binder system curable by free-radical polymerization of olefinic double bonds; and (b) thermal curing of the applied coating layer, wherein the coating agent contains at least one HALS compound and at least one metal compound selected from the group consisting of metal salt compounds containing the metal in the cation and/or anion of the compound, organometallic compounds, metal coordination compounds and combinations thereof, wherein said metal or metals is/are selected from the group consisting of metals of groups 13 and 14 of the periodic system of elements and transition metals, which metals or transition metals are able to occur in at least 2 oxidation states other than zero.