Abstract: The invention relates to production of alloys based on aluminum. A method is proposed for producing aluminum-based alloys by electrolysis, according to which low-consumable anode of aluminum pot is used as a source of alloying elements. At the same time, in order to optimize master alloy consumption, one of the following options is chosen: dissolution of alloying elements from slightly soluble anodes; adding oxides and/or fluorides and/or carbonates of alloying elements to electrolyte melt of aluminum pot; simultaneous dissolution of alloying elements from slightly soluble anodes with addition of oxides and/or fluorides and/or carbonates of alloying elements to electrolyte melt of aluminum pot.

Abstract: The invention relates to vertical or inclined electrodes of an electrolyzer for electrolytically producing aluminum from aluminum oxide. An electrode contains an electrode base and a surface coating based on refractory ceramics. According to a first variant of the invention, the electrode base is made of a composite material containing between 5% and 90% by mass of refractory ceramics, and of at least one metal having a melting temperature exceeding 1000° C., which forms refractory intermetallic compounds upon interaction with aluminum, and/or containing at least one alloy of such a metal. According to a second variant of the invention, the electrode base is made of a metal alloy, for example structural steel or another alloy, and the surface of the electrode base has applied thereto an intermediary layer consisting of a composite material having the composition described above.

Abstract: The invention concerns non-ferrous metallurgy, particularly an anode for electrolytically obtaining aluminum by the electrolysis of fluoride melts. The anode for obtaining aluminum by means of the electrolysis of melts at a temperature of less than 930° C. consists of a base executed of an alloy containing 65-96%wt of iron, less than 35%wt of copper, less than 20%wt of nickel, and one or several additives from molybdenum, manganese, titanium, tantalum, tungsten, vanadium, zirconium, niobium, chromium, aluminum (less than 1%wt) cobalt, cerium, yttrium, silicon, and carbon totaling less than 5%, and a protective oxide layer comprising iron oxides and complex oxides of iron, copper, and nickel. The protective oxide layer on the anode surface is obtained by preliminary oxidation in air at a temperature of 850-1050° C. or subsequently in the electrolysis process by oxidation with oxygen evolving at the anode.

Abstract: The invention relates to production of alloys based on aluminum. A method is proposed for producing aluminum-based alloys by electrolysis, according to which low-consumable anode of aluminum pot is used as a source of alloying elements. At the same time, in order to optimize master alloy consumption, one of the following options is chosen: dissolution of alloying elements from slightly soluble anodes; adding oxides and/or fluorides and/or carbonates of alloying elements to electrolyte melt of aluminum pot; simultaneous dissolution of alloying elements from slightly soluble anodes with addition of oxides and/or fluorides and/or carbonates of alloying elements to electrolyte melt of aluminum pot.

Abstract: The invention relates to nonferrous metallurgy and may be suitable for controlling the feed of alumina to electrolytic cells for producing aluminum to maintain the alumina concentration in the electrolytic melt equal or close to the saturation value. To maintain the alumina concentration within the set range, reduced voltage U or pseudo-resistance R is measured and recorded at fixed time intervals. Underfeeding or overfeeding phases occur compared to a theoretical alumina feeding rate during electrolysis, wherein the duration of underfeeding phases is based on the alumina concentration in the electrolytic melt, and the duration of overfeeding phases is based on the change of one or more electrolytic cell parameters being recorded: reduced voltage, U, pseudo-resistance, R, rates of reduced voltage, dU/dt, pseudo-resistance, dR/dt, change. Adjustments to the anode-cathode distance to maintain the electrolytic cell energy balance may be performed during any of the feeding phases.

Abstract: The invention relates to electrowinning of aluminum from cryolite-alumina melts, and can be used in the shunt design of a cathode assembly. In an aluminum electrolysis cell, cathode vertical metal shunts, are designed such that their top part is melted aluminum, and the bottom part is solid aluminum. Shunts are located in conduits made in a hearth slab lining which has a widening in the middle part which is wider than both parts of the shunts. The widening in the shunt conduit can be filled with a composite material, i.e. titanium diboride-carbon. The shunts can be designed as a tube, and the widening in the conduit and the space inside the tube can be filled with the composite material titanium diboride-carbon. The invention makes it possible to increase the electrical efficiency due to the absence of contact assemblies, reduced current loss, and achieving an effective current distribution and current shunting.

Abstract: This invention relates to producing aluminum by electrolysis of a melt and can be used in the process control of an electrolyte composition by quantitative X-ray phase analysis (XRD) of potassium-containing electrolyte with calcium or calcium and magnesium additives. A quantitative XRD method is employed for analyzing doped samples of crystallized bath samples taken from baths. A weighted ground bath sample is mixed with a weighted quantity of sodium fluoride at a ratio, for example, 1:2 by weight. The weighted quantities are mixed and placed in a furnace (650-750° C. for 20-40 minutes) to dissolve sodium fluoride in the sample and recrystallize the sample with the desired phase composition. The doped sample is placed in a furnace (420-450° C) and held for 15-30 minutes. The doped sample is removed from the furnace and allowed to air cool. The phase composition of the doped sample is analyzed by any quantitative X-ray phase method.

Abstract: The invention relates to vertical or inclined electrodes of an electrolyzer for electrolytically producing aluminum from aluminum oxide. An electrode contains an electrode base and a surface coating based on refractory ceramics. According to a first variant of the invention, the electrode base is made of a composite material containing between 5% and 90% by mass of refractory ceramics, and of at least one metal having a melting temperature exceeding 1000° C., which forms refractory intermetallic compounds upon interaction with aluminum, and/or containing at least one alloy of such a metal. According to a second variant of the invention, the electrode base is made of a metal alloy, for example structural steel or another alloy, and the surface of the electrode base has applied thereto an intermediary layer consisting of a composite material having the composition described above.

Abstract: The invention relates to the preparation of synthetic melted mica materials, and specifically relates to a stone casting process and to the composition of an initial feedstock, and may be used in the creation of novel types of stone casting in the metallurgical, mining/enrichment, refractory and construction industries.

Abstract: The invention relates to non-ferrous metallurgy, more particularly to producing aluminium by electrolysis, and even more particularly to a structural element for covering the space above a melt in an electrolysis cell for producing aluminium by the electrolysis of cryolite-alumina melts. In a cover for an electrolysis cell for producing aluminium, which is in contact with a vapour-gas phase when the electrolysis cell is in operation and which is in the form of central and peripheral sections which are movably arranged relative to each other, the central and peripheral sections are made from a corrosion-resistant and erosion-resistant material which comprises 80.0-99.0 wt % of fluorophlogopite and 20.0-1.0 wt % of a refractory filler. The central sections of the cover may be permanently fixed on each anode rod, and the peripheral sections may be configured as convex panels rigidly and removably fixed on the top surface of a cathode and supported by the central section of the cover.

Abstract: The invention relates to nonferrous metallurgy and may be suitable for controlling the feed of alumina to electrolytic cells for producing aluminum to maintain the alumina concentration in the electrolytic melt equal or close to the saturation value. To maintain the alumina concentration within the set range, reduced voltage U or pseudo-resistance R is measured. The measured values are recorded at fixed time intervals, underfeeding or overfeeding phases compared to a theoretical alumina feeding rate during electrolysis are formed, whereas the duration of underfeeding phases is selected depending on the alumina concentration in the electrolytic melt, and the duration of overfeeding phases is determined according to the change of one or more electrolytic cell parameters being recorded: reduced voltage, U, pseudo-resistance. R, rates of reduced voltage, dU/dt, pseudo-resistance, dR/dt, change.

Abstract: This invention relates to the field of nonferrous metallurgy, and in particular, to producing aluminum by the electrolysis of a melt and can be used in the process control of an electrolyte composition by quantitative X-ray phase analysis (XRD) of potassium-containing electrolyte with calcium or calcium and magnesium additives. The method is as follows. A quantitative XRD method is employed for analyzing doped samples of crystallized bath samples taken from baths. For this purpose, a weighted ground bath sample is mixed with a weighted quantity of sodium fluoride at a ratio, for example, 1:2 by weight of the sample. The weighted quantities are mixed and placed in a furnace heated to 650-750° C. for 20-40 minutes to dissolve sodium fluoride in the sample and recrystallize the sample with the desired phase composition. Then the doped sample is placed in a furnace heated to a temperature of 420-450° C. and held there for 15-30 minutes. The doped sample is then removed from the furnace and allowed to air cool.

Abstract: The invention concerns non-ferrous metallurgy, particularly an anode for the electrolytically obtaining aluminum by the electrolysis of fluoride melts. The anode for obtaining aluminum by means of the electrolysis of melts at a temperature of less than 930° C. consists of a base executed of a alloy containing 65-96%wt of iron, up to 35%wt of copper, up to 20%wt of nickel, and one or several additives from molybdenum, manganese, titanium, tantalum, tungsten, vanadium, zirconium, niobium, chromium, aluminum (up to 1%wt), cobalt, cerium, yttrium, silicon, and carbon totaling up to 5%wt, and a protective oxide layer consisting mainly of iron oxides and complex oxides of iron, copper, and nickel. The base is made by casting in a metal or sand mold. The protective oxide layer on the anode surface is obtaining by preliminary oxidation in air at a temperature of 850-1050° C. or subsequently in the electrolysis process by oxidation with oxygen evolving at the anode.

Abstract: The invention relates to electrowinning of aluminium from cryolite-alumina melts, and can be used in the shunt design of a cathode assembly. In an aluminium electrolysis cell, cathode vertical metal shunts, are designed such that their top part is melted aluminium, and the bottom part is solid aluminium. Shunts are located in conduits made in a hearth slab lining which has a widening in the middle part which is wider than both parts of the shunts. The widening in the shunt conduit can be filled with a composite material, i.e. titanium diboride-carbon. The shunts can be designed as a tube, and the widening in the conduit and the space inside the tube can be filled with the composite material titanium diboride-carbon. The invention makes it possible to increase the electrical efficiency due to the absence of contact assemblies, reduced current loss, and achieving an effective current distribution and current shunting.