Publication number: 20160176835
Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt; (ii) passing the feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one potassium salt, optionally propene, and optionally pane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one potassium salt, optionally propene, and optionally propane.
Type:
Application
Filed:
July 16, 2014
Publication date:
June 23, 2016
Applicants:
BASF SE, DOW Global Technologies LLC
Inventors:
Dominic RIEDEL, Joaquim Henrique TELES, Ulrike WEGERLE, Andrei-Nicolae PARVULESCU, Alexander SCHROEDER, Luise SPISKE, Daniel URBANCZYK, Ulrich MUELLER, Werner WITZL, Meinolf Weidenbach