Abstract: The present invention relates to methods for the layered construction of molds and cores that include refractory molding base material, a hydrophobized metal oxide as solids and a binder containing at least water glass in the form of an aqueous alkali silicate solution. The methods involve applying a refractory molding base material in layers and selectively print the molds and cores using the binder. The present invention further relates to molds or cores produced in accordance with these methods.

Abstract: The present invention relates to a method for the layer-by-layer production of a cured three- dimensional shaped body, wherein the method comprises at least: (i) providing a binder comprising at least the following components: a) monomeric furfuryl alcohol and optionally a resin component comprising at least a furan resin, wherein about 60% by weight to 100% by weight of monomeric furfuryl alcohol, based on the sum of monomeric furfuryl alcohol and resin component are present in the binder, and b) a hardener component selected from methanesulfonic acid, benzenesulfonic acid, and mixtures thereof, (ii) providing a layer of a refractory molding material to provide a molding material layer, (iii) selectively applying a component a) or b) of the binder separately from the refractory molding material to at least a part of the molding material layer, (iv) applying the other component of the binder separately from the component mentioned in step (iii), wherein step (iv) can be carried out before or after step (iii),