Abstract: The present invention relates to a process for treating, in a reactor containing a catalytic bed, a solid catalyst, said process comprising the steps of: a) implementing, in said reactor, a gas-phase catalytic reaction at a catalytic bed temperature T1 in the presence of a hydrogen halide or giving rise to the formation of a hydrogen halide, b) causing an inert gas to flow through the catalytic bed at a catalytic bed temperature T2 that is lower than T1, the temperature T2 being greater than 30° C.

Abstract: The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.

Abstract: The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst, said process being performed in a reactor made of a material comprising a base layer made of a material M1 and an inner layer made of a material M2, said base layer and said inner layer being laid against each other by bonding.

Abstract: The invention relates to a process for preparing bis(fluorosulfonyl) imide, comprising the steps of: i) providing a stream A1 containing hydrofluoric acid; providing a reactor containing a liquid phase A2 that contains bis(halosulfonyl) imide; providing at least one mixing device that is connected to the inlet of said reactor; ii) supplying liquid phase A2 and stream A1 to the at least one mixing device; iii) bringing liquid phase A2 into contact with stream A1 in the mixing device to form a reaction mixture B in liquid form containing bis(fluorosulfonyl) imide; iv) introducing the reaction mixture B produced in step iii) into the liquid phase A2 in the reactor.

Abstract: The invention relates to a method for producing and purifying 2,3,3,3-tetrafluoro-1-propene using a first composition comprising 2,3,3,3-tetrafluoro-1-propene, 3,3,3-trifluoropropene (1243zf), and trans-1,3,3,3-tetrafluoro-1-propene (1234ze-E), said method comprising the steps of: (a) bringing said first composition into contact with at least one organic extraction agent in order to form a second composition; (b) extractive distilaation of said second composition in order to form (i) a third composition comprising said organic extraction agent, 3,3,3-trifluoropropene (1243zf), and trans-1,3,3,3-tetrafluoro-1-propene (1234ze-E), and (ii) a stream comprising the 2,3,3,3-tetrafluoro-1-propene; and (c) recovery and separation of said third composition in order to form a stream comprising said organic extraction agent and a stream comprising 3,3,3-trifluoropropene (1243zf) and trans-1,3,3,3-tetrafluoro-1-propene (1234ze-E).

Abstract: The present invention relates to a catalyst comprising a) from 90% to 99.99% by weight of alumina in which said alumina is at least 90% by weight ?-alumina and b) from 0.01% to 10% by weight of at least one metal of valency 0 selected from the group consisting of Pd, Ru, Pt, Rh and Ir, characterized in that the chloride content of said catalyst is less than 500 ppm, based on the total weight of the catalyst.

Abstract: The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.

Abstract: A method for preparing Cl—SO2NHSO2Cl including a step of chlorinating sulphamic acid with at least one chlorinating agent and at least one sulphur-containing agent, the method resulting in a flow F1, preferably liquid, including Cl—SO2NHSO2Cl and a gas stream F2 including HCl and SO2, the method including a step a) of treating the gas stream F2. Also, a method for preparing LiFSl including the abovementioned method for preparing Cl—SO2NHSO2Cl.

Abstract: The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.

Abstract: A process for producing 2,3,3,3-tetrafluoropropene comprises the steps: i) in a first adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the gas phase in the presence of a catalyst to produce a stream A comprising 2,3,3,3-tetrafluoropropene, HF and unreacted 2-chloro-3,3,3-trifluoropropene; and ii) in a second adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing hydrofluoric acid into contact in the gas phase, optionally in the presence of a catalyst, with at least one chlorinated compound to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene. The stream A obtained in step i) feeds said second reactor. The inlet temperature of the fixed bed of one of said first or second reactors is between 300° C. and 400° C. The longitudinal temperature difference between the inlet and the outlet of the fixed bed in question is less than 20° C.

Abstract: The invention relates to a process for preparing bis(fluorosulfonyl) imide, comprising the steps of: i) providing a stream A1 containing HF and a reactor containing a liquid phase A2 that contains bis(chlorosulfonyl) imide; ii) in said reactor, bringing said liquid phase A2 into contact with said stream A1 to produce bis(fluorosulfonyl) imide, said process being characterized in that said stream A1 is injected into said liquid phase A2.

Abstract: The present invention relates to a method for storing, in a closed container, a composition comprising 1,1,1,2,3,3-hexafluoropropane in a liquid/gas state composed of a liquid phase and of a gas phase, characterized in that i) a stream comprising 1,1,1,2,3,3-hexafluoropropane is injected into said container, said stream comprising an oxygen concentration of at most 5000 ppm by volume at a temperature of 25° C., and ii) the container is closed after injection of said stream. The present invention also relates to a container for storing 1,1,1,2,3,3-hexafluoropropane.

Abstract: A process for producing 2,3,3,3-tetrafluoropropene comprises i) in a first adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing hydrofluoric acid into contact, in the gas phase with at least one chlorinated compound in order to produce a stream A comprising 2-chloro-3,3,3-trifluoropropene, ii) in a second adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing the stream A into contact, in the gas phase in the presence of a catalyst, with hydrofluoric acid, to produce a stream B comprising 2,3,3,3-tetrafluoropropene. The temperature at the inlet of the fixed bed of one of said first or second reactors is between 300° C. and 400° C. The longitudinal temperature difference between the inlet and the outlet of the fixed bed of the reactor is less than 20° C.

Abstract: The present invention relates to a process for producing 2-chloro-3,3,3-trifluoropropene, comprising the steps: i) providing a stream A comprising at least one chlorinated compound selected from the group consisting of 2,3-dichloro-1,1,1-trifluoropropane, 1,1,1,2,3-pentachloropropane, 1,1,2,3-tetrachloropropene and 2,3,3,3-tetrachloropropene; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.

Abstract: The present invention relates to a process for producing 2,3,3,3-tetrafluoropropene, comprising the steps: i) providing a stream A comprising at least one starting compound selected from the group consisting of 2-chloro-3,3,3-trifluoropropene and 2,3-dichloro-1,1,1-trifluoropropane; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2,3,3,3-tetrafluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.

Abstract: The present invention relates to a process for producing 2-chloro-3,3,3-trifluoropropene, comprising the steps: i) providing a stream A comprising at least one chlorinated compound selected from the group consisting of 2,3-dichloro-1,1,1-trifluoropropane, 1,1,1,2,3-pentachloropropane, 1,1,2,3-tetrachloropropene and 2,3,3,3-tetrachloropropene; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.

Abstract: A process for producing 2,3,3,3-tetrafluoropropene comprises i) in a first adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing hydrofluoric acid into contact, in the gas phase with at least one chlorinated compound in order to produce a stream A comprising 2-chloro-3,3,3-trifluoropropene, ii) in a second adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing the stream A into contact, in the gas phase in the presence of a catalyst, with hydrofluoric acid, to produce a stream B comprising 2,3,3,3-tetrafluoropropene. The temperature at the inlet of the fixed bed of one of said first or second reactors is between 300° C. and 400° C. The longitudinal temperature difference between the inlet and the outlet of the fixed bed of the reactor is less than 20° C.

Abstract: The present invention relates to a process for producing 2,3,3,3-tetrafluoropropene, comprising the steps: i) providing a stream A comprising at least one starting compound selected from the group consisting of 2-chloro-3,3,3-trifluoropropene and 2,3-dichloro-1,1,1-trifluoropropane; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2,3,3,3-tetrafluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.

Abstract: A process for producing 2,3,3,3-tetrafluoropropene comprises the steps: i) in a first adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the gas phase in the presence of a catalyst to produce a stream A comprising 2,3,3,3-tetrafluoropropene, HF and unreacted 2-chloro-3,3,3-trifluoropropene; and ii) in a second adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing hydrofluoric acid into contact in the gas phase, optionally in the presence of a catalyst, with at least one chlorinated compound to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene. The stream A obtained in step i) feeds said second reactor. The inlet temperature of the fixed bed of one of said first or second reactors is between 300° C. and 400° C. The longitudinal temperature difference between the inlet and the outlet of the fixed bed in question is less than 20° C.

Abstract: A process for the production of 2,3,3,3-tetrafluoropropene including the stages: i) in a first reactor, bringing a stream A including 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the gas phase in the presence of a catalyst in order to produce a stream B including 2,3,3,3-tetrafluoropropene, HCl, HF and unreacted 2-chloro-3,3,3-trifluoropropene; and ii) in a second reactor, bringing hydrofluoric acid into contact, in the gas phase in the presence or not of a catalyst, with a stream including at least one chlorinated compound selected from the group of 1,1,1,2,3-pentachloropropane, 2,3-dichloro-1,1,1-trifluoropropane, 2,3,3,3-tetrachloropropene and 1,1,2,3-tetrachloropropene, in order to produce a stream C including 2-chloro-3,3,3-trifluoropropene, wherein the stream B obtained in stage i) feeds the second reactor used for stage ii); and wherein the electrical conductivity of the stream A provided in stage i) is less than 15 mS/cm.