Abstract: Crystallizable hot melt adhesive compositions comprising block copolyesteramides and alkali metal salts of carboxy polymers. The block copolyesteramides comprise hard or crystalline polyester blocks and soft or amorphous polyamide blocks in the weight ratio of 2:3 to 4:1. The alkali metal salts are salts of copolymers of C.sub.1 to C.sub.4 aliphatic olefins and acrylic or methacrylic acid or salts of copolymers of aromatic olefins and maleic anhydride and provide a concentration of alkali metal cation in the range of 0.1 to 15 meq per 100 parts by weight of copolyesteramide. The hot melt adhesive compositions are useful for bonding plastic parts to form plastic structures which are relatively free of bond line distortion.

Abstract: Crystallizable hot melt adhesive compositions comprising block copolyesteramides and alkali metal carboxylates. The block copolyesteramides comprise hard or crystalline polyester blocks and soft or amorphous polyamide blocks in the weight ratio of 2:3 to 4:1. The alkali metal carboxylates provide a concentration of alkali metal cation in the range of 0.1 to 6 meq per 100 parts by weight of copolyesteramide. The hot melt adhesive compositions are useful for bonding plastic parts to form plastic structures which are relatively free of bond line distortion.

Abstract: A process for bonding a reinforced plastic structure which comprises coating reinforced plastic parts of sheet molding compounds or bulk molding compound with a primer coat and bonding together with a thermoplastic block copolymer.

Abstract: A bonded reinforced plastic structure which comprises reinforced plastic parts of sheet molding compound or bulk molding compound, coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises an epoxidized novolac resin and a resinous amidopolyamine. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.

Abstract: A bonded plastic structure which comprises plastic parts of reaction injection molded polyurethane or reaction injection molded nylon coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.

Abstract: A bonded reinforced plastic structure which comprises reinforced plastic parts of sheet molding compound or bulk molding compound, coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.

Abstract: Hot melt adhesive compositions comprising a block copolymer, aluminum powder, glass fiber and hollow inorganic silicate microspheres. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to aluminum powder, glass fiber and silicate microspheres is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 2:1, the weight ratio of glass fiber to aluminum powder is at least about 1:9 and wherein the volume percent of silicate microspheres is less than about 10. The compositions are particularly useful for filling voids and cavities in substrates.

Abstract: A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition and sanding the composition to provide a surface even with the surrounding substrate. The adhesive composition comprises a block copolymer, aluminum powder and glass fiber. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to aluminum powder and glass fiber is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 2:1, and the weight ratio of glass fiber to aluminum powder is at least about 1:9.

Abstract: Hot melt adhesive compositions comprising a block copolymer, particulate mineral reinforcing agent, glass fiber and hollow inorganic silicate microspheres. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to particulate inorganic reinforcing agent, glass fiber and silicate microspheres is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 3:4, the weight ratio of particulate mineral to glass fiber is in the range of about 1:3 to about 9:1 and the volume percentage of hollow inorganic silicate microspheres is less than about 12. The compositions are particularly useful for filling voids and cavities in substrates.

Abstract: Hot melt adhesive compositions comprising a block copolymer, aluminum powder and glass fiber. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to aluminum powder and glass fiber is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 2:1, and the weight ratio of glass fiber to aluminum powder is at least about 1:9. The compositions are particularly useful for filling voids and cavities in substrates.

Abstract: Hot melt adhesive compositions comprising a block copolymer, a particulate mineral reinforcing agent and glass fiber. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to particulate mineral reinforcing agent and glass fiber is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 3:4, and the weight ratio of particulate mineral reinforcing agent to glass fiber is in the range of about 1:3 to about 9:1. The compositions are particularly useful for filling voids and cavities in substrates.

Abstract: A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition and sanding the composition to provide a surface even with the surrounding substrate. The adhesive composition comprises a block copolymer, a particulate mineral reinforcing agent, glass fiber and hollow inorganic silicate microspheres. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 percent of hard segments and from about 70 to about 30 weight percent of soft segments.

Abstract: A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition and sanding the composition to provide a surface even with the surrounding substrate. The adhesive composition comprises a block copolymer, a particulate mineral reinforcing agent and glass fiber. The block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above about 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments.

Abstract: A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition and sanding the composition to provide a surface even with the surrounding substrate. The adhesive composition comprises a block copolymer, aluminum powder, glass fiber and hollow inorganic silicate microspheres. The block copolymer is selected from the group consisting of copolyesters, coplyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above 150.degree. C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments.

Abstract: Poly(ester-amide) adhesive compositions comprising a finely divided spheroidal metal. The poly(ester-amide) comprises crystalline polyester and amorphous polyamide segments formed by reaction of a C.sub.18 to C.sub.54 polycarboxylic acid mixture and a C.sub.2 to C.sub.10 aliphatic or alicyclic primary diamine. The finely divided spheroidal metal is selected from the group consisting of aluminum, iron, mild steel, stainless steel and zinc. The weight ratio of poly(ester-amide) to metal is in the range of 70:30 to 30:70. The adhesive compositions are useful as hot melt adhesives and cavity fillings.

Abstract: A method of filling cavities with a hot melt adhesive composition. The adhesive composition comprises a block copoly(ester-amide) containing crystalline polyester and amorphous polyamide segments and a finely divided spheroidal metal. The weight ratio of poly(ester-amide) to metal is in the range of 70:30 to 30:70. The adhesive composition is applied as a hot melt to fill a cavity in a substrate and is sanded smooth to provide a surface which accepts paint.

Abstract: Acid modified vinyl acetate interpolymers containing 2-acrylamido-2-methylpropanesulfonic acid and their use as textile sizes. The interpolymers comprise from about 64.5 to about 95.8 weight percent of vinyl acetate, from about 4 to about 9.5 weight percent of acrylic acid, from about 0.2 to about 1 weight percent of 2-acrylamido-2-methylpropanesulfonic acid and from about 0 to about 25 weight percent of an ethylenically unsaturated monomer selected from the group consisting of alkyl acrylates, dialkyl maleates, and dialkyl fumarates. The interpolymers are prepared preferably by latex polymerization. The textile size solutions are formed by dissolving the interpolymers in dilute aqueous bases or in an organic solvent, and can be used advantageously in combination with polyvinyl alcohol and starches. The sizes demonstrate excellent adhesion to spun polyester and spun blends of polyester and natural fibers and are readily removed by aqueous scouring solvents.

Abstract: Acid modified vinyl acetate interpolymers containing 2-acrylamido-2-methylpropanesulfonic acid and their use as textile sizes. The interpolymers comprise from about 64.5 to about 95.8 weight percent of vinyl acetate, from about 4 to about 9.5 weight percent of acrylic acid, from about 0.2 to about 1 weight percent of 2-acrylamido-2-methylpropanesulfonic acid and from about 0 to about 25 weight percent of an ethylenically unsaturated monomer selected from the group consisting of alkyl acrylates, dialkyl maleates, and dialkyl fumarates. The interpolymers are prepared preferably by latex polymerization. The textile size solutions are formed by dissolving the interpolymers in dilute aqueous bases or in an organic solvent, and can be used advantageously in combination with polyvinyl alcohol and starches. The sizes demonstrate excellent adhesion to spun polyester and spun blends of polyester and natural fibers and are readily removed by aqueous scouring solvents.

Abstract: Adhesion of filled poly(ester-amide) adhesive compositions to metal substrates is improved by priming the metal substrate with a tie coat of an etherified methylolmelamine prior to application of the filled poly(ester-amide). The etherified methylolmelamine is the condensation product of melamine, formaldehyde and an alkanol or cycloalkanol in which the degree of methylolation is in the range of about 5 to 6, the degree of etherification is in the range of about 3 to 6 and the degree of methylation is at least about 2.

Abstract: Acid-modified poly(vinyl acetate) textile sizes and textiles sized therewith. The sizes comprise interpolymers of 90.5 to 95.5 percent by weight vinyl acetate, 4.0 to 7.5 percent by weight acrylic acid and 0.5 to 2.0 percent by weight of a monoalkyl ester of maleic, fumaric, or citraconic acids. The interpolymers are prepared preferably by latex interpolymerization. They are used for sizing spun polyester and spun blends of polyester and natural fibers.