Abstract: A burner and method for oxidizing solid fuels wherein the burner has a lance having one or more nozzle feeds and one or more nozzle outlets concentrically surrounded by a primary oxidant passage which is concentrically surrounded by a secondary oxidant passage wherein the primary and secondary oxidant passages communicate at their proximal ends with a gas supply, the lance having a distal and proximal end and the one or more nozzle feeds is in communication with a gas supply.

Abstract: A method for the efficient conversion of heavy oil to distillates using sequential hydrocracking in the presence of both supported and colloidal catalyst immediately followed by a high temperature-short residence time thermal treatment. The hydrocracker reaction products or a heavy oil and hydrogen donor diluent may be advantageously heated by direct contact with high velocity combustion products.

Abstract: The present invention relates to a process for production, shipment, and treatment of a NH4F(HF)x feedstock for local production of fluorine and NF3 for semiconductor chamber cleaning without the need for storage of large quantities of dangerous feeds and intermediate products.

Abstract: Methods are disclosed for pyrolizing carbonaceous materials to carbonaceous materials having lower boiling points by heating the carbonaceous material to a desired reaction temperature and holding the carbonaceous material in contact with the heat for a sufficient time to achieve the desired reaction to a lower boiling point carbonaceous materials, then rapidly cooling the desired reaction products. The heating source is a jet which will provide hot and high velocity gas streams to the carbonaceous material to be heated.

Abstract: A method for the efficient conversion of heavy oil to distillates using sequential hydrocracking in the presence of both supported and colloidal catalyst immediately followed by a high temperature-short residence time thermal treatment. The hydrocracker reaction products or a heavy oil and hydrogen donor diluent may be advantageously heated by direct contact with high velocity combustion products.

Abstract: A process for the production of nitrogen trifluoride by reacting fluorine gas and liquid ammonia acid fluoride in a first reaction zone having a relatively low energy input followed by treatment of the resulting reaction product in a second reaction zone having a relatively high energy input. The resulting crude nitrogen trifluoride product may be further treated with fluorine gas under elevated temperatures to improve yield of the desired product.

Abstract: A process for the production of nitrogen trifluoride by reacting fluorine gas and liquid ammonia acid fluoride in a first reaction zone having a relatively low energy input followed by treatment of the resulting reaction product in a second reaction zone having a relatively high energy input. The resulting crude nitrogen trifluoride product may be further treated with fluorine gas under elevated temperatures to improve yield of the desired product.

Abstract: Method of forming a (CFX)n containing adsorbent composition by combining a fine particle (CFX)n starting material with a non-fluorinated carbonaceous material prior to the formation of a solid body and intermediate materials employed in conducting the method.

Abstract: Method and apparatus for performing a metallurgical process in which a carbonaceous material is converted to a reducing gas and a metal is melted in a main reactor, particulate coal is partially oxidized in a secondary reactor to form a particulate char and a calorific gas under conditions which minimize the formation of carbon monoxide, and at least part of the char and some of the calorific gas are introduced into the main reactor.

Abstract: Oxygen is separated from air by pressure swing adsorption in plant 2. The oxygen is passed through an ozone generator 4. The resulting ozonated oxygen is passed upwardly through a contactor 6 countercurrently to the flow of a side stream of water to be treated with ozone. The side stream containing dissolved ozone flows from the contactor 6 to a mixer 8 in which it is mixed with a main stream of water. The effluent gas from the contactor 6 contains air displaced from the water and undissolved oxygen. It is divided into two parts. One part flows to the pressure swing adsorption plant 2 and is separated therein with the air. The other part is dried by temperature swing adsorption in drier 20 and the resulting dried gas is ozonated in the ozone generator 4 with the oxygen from the plant 2.

Abstract: An improved process for the production of oxides from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, in the presence of a suitable catalyst. An alkane, e.g. propane, is converted to an alkene in a catalytic dehydrogenator. The product stream is introduced into an oxidation reactor. Product formed therein is recovered in a conventional quench tower. The pressure of the gaseous effluent from the quench tower is raised and it is introduced into an absorber/stripper unit to form a recycle stream containing unreacted alkane and alkene as well as a minor amount of oxygen, typically 1-2 percent by volume, and a waste stream comprising the remainder of the quench tower gaseous phase. The recycle stream enters a selective oxidation unit wherein oxygen is removed, and the product recycled to the dehydrogenator.

Abstract: An improved process is provided for the production of oxides from alkanes by reaction with oxygen, air or a gas enriched in oxygen relative to an air in the presence of an oxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a multistage dehydrogenator. The product stream is withdrawn from an intermediate reactor in the dehydrogenator, other than the first and the last reactor, and introduced into an oxidation reactor. The product formed in the oxidation reactor is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a pressure swing adsorption (PSA) unit to form a gaseous stream containing the unreacted alkane and alkene as well as a minor amount, i.e. less than about 2 percent by volume, of oxygen and nitrogen, if present in the feed to the oxidation reactor.

Abstract: An improved process is provided for the production of oxides from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter in the presence of an oxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a catalytic dehydrogenator. The product stream is introduced into an oxidation reactor. The product formed therein is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a separator to produce an adsorbed stream, an oxygen-enriched stream, a waste stream and, if desired, a hydrogen-enriched stream. The oxygen-enriched stream may be recycled to the oxidation reactor depending on the nitrogen content thereof. The adsorbed stream plus at least a portion of the hydrogen-enriched stream is introduced into a selective oxidation unit to remove the remaining oxygen and then recycled to the dehydrogenator. The remainder of the hydrogen-enriched stream, if any, may be taken as product or vented.

Abstract: An improved process is provided for the production of oxides from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, in the presence of an oxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a dehydrogenator. The product stream is introduced into an oxidation reactor. The product formed therein is recovered in a quench tower. The gas phase from the quench tower is treated in a PSA unit to form a gaseous stream containing the unreacted alkane, alkene, a minor amount of oxygen, i.e. less than about 2 percent by volume, and nitrogen if present in the feed to the oxidation reactor. The gaseous stream, which may or may not contain hydrogen depending on the adsorbent on the PSA unit, is introduced into a selective oxidation unit to remove the remaining oxygen and then recycled to the dehydrogenator.

Abstract: An improved process is provided for the production of nitriles and oxides from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, and ammonia where a nitrile is desired, in the presence of a suitable catalyst. An alkane, e.g. propane, is converted to an alkene in a catalytic dehydrogenator. The product stream is introduced into an ammoxidation reactor. The product formed therein is recovered in a conventional quench tower. The pressure of the gaseous effluent from the quench tower is raised and it is introduced into an absorber/stripper unit to form a recycle stream containing unreacted alkane and alkene as well as a minor amount of oxygen, typically 1-2 percent by volume, and a waste stream comprising the remainder of the quench tower gaseous phase. The recycle stream is introduced into a selective oxidation unit to remove the oxygen therefrom and then recycled to the dehydrogenator.

Abstract: An improved process is provided for the production of nitriles from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, and ammonia in the presence of an ammoxidation catalyst. An alkane, e.g., propane, is converted to an alkene in a catalytic dehydrogenator. The product stream is introduced into an ammoxidation reactor. The product formed therein is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a PSA unit comprising at least two pairs of adsorptive beds. The first bed forms a gas stream containing the unreacted alkane and alkene as well as a minor amount, typically 1-2 percent by volume, of oxygen and a vent stream containing oxygen, nitrogen if present, and hydrogen. The vent stream is introduced into the second adsorptive bed to thereby form an oxygen-containing stream which also contains, nitrogen, if present, and a hydrogen-enriched stream.

Abstract: An improved process is provided for the production of nitriles from hydrocarbons by reaction with oxygen, air or gas-enriched in relative to an air, and ammonia, in the presence of an ammoxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a multistage dehydrogenator. The product stream is withdrawn from a reactor in the dehydrogenator other than the first and the last reactor and introduced into an ammoxidation reactor. The product is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a pressure swing adsorption unit to form a gas stream containing the unreacted alkane and alkene as well as a minor amount of oxygen. The gas stream, which may or may not contain hydrogen depending on the absorbent in the pressure swing adsorption unit, is introduced into the reactor in the dehydrogenator following that from which the product stream was withdrawn.

Abstract: An improved process is provided for the production of nitriles from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, and ammonia in the presence of an ammoxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a dehydrogenator. The product stream is introduced into an ammoxidation reactor. The product formed therein is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a PSA unit to form a gas stream containing the unreacted alkane and alkene as well as a minor amount, i.e. less than about 1 percent by volume, of oxygen and nitrogen, if present in the feed to the ammoxidation reactor. The gas stream, which may or may not contain hydrogen depending on the absorbent in the PSA unit, is introduced into a selective oxidation unit to remove the remaining oxygen and then recycled to the dehydrogenator.

Abstract: In the solvent refining of a residual oil, a mixture of refined oil and refining solvent, and a mixture of pitch impurities and refining solvent are introduced into separate zones of a combination tower operated at a pressure of no greater than 100 psig to recover refining solvent from each of the mixtures. The combination tower is preferably A modified crude distillation tower from a preexisting crude unit, whereby idle crude units may be converted to solvent refining.

Abstract: Prior to upgrading a viscous feed by visbreaking, at least a portion of the feed is treated to remove a heavy phase in specified amounts, whereby the severity of the visbreaking may be increased. The Shell Hot Filtration number of the visbreaking product is reduced by at least 75%, compared to visbreaking of untreated feed at some severity.