Abstract: A process derived hydrogen donor solvent is used to increase the maximum resid conversion and conversion rate in an ebullated bed resid hydrocracker. The hydrogen donor solvent precursor is produced by hydroreforming reactions within the resid hydrocracker, recovered as the resin fraction from a solvent deasphalting unit, regenerated in a separate hydrotreater reactor, and recycled to the ebullated bed resid hydrocracker. The major advantage of this invention relative to earlier processes is that hydrogen is more efficiently transferred to the resin residual oil in the separate hydrotreater and the hydrogen donor solvent effectively retards the formation of coke precursors at higher ebullated bed resid hydrocracker operating temperatures and resid cracking rates.

Abstract: The invention provides a method and apparatus for producing nitrogen trifluoride. The invention involves passing a working fluid through a heat engine cycle and using the mechanical energy generated by the working fluid to produce sufficient mixing intensity within a nitrogen trifluoride reactor. The method utilizes a working fluid vapor jet, such as a hydrogen fluoride vapor jet, to impart sufficient energy to the mixing zone of a reactor in order to disperse gaseous fluorine within a liquid ammonium acid fluoride melt. A gaseous reaction product stream is removed from the reactor, the reaction product stream comprising nitrogen trifluoride and a working fluid vapor. The working fluid is then separated from the nitrogen trifluoride and recycled for reuse in the process, thereby completing a heat engine cycle.

Abstract: A method of heating a surface susceptible to oxidation or reduction includes generating a central, generally cylindrical, fuel-rich particulate jet, and a coaxial, annular, supersonic velocity, oxidant-rich jet having an auto-thermal ignition temperature greater than the temperature of the fuel-rich particulate jet, directed toward the surface to be heated, the velocity of the fuel-rich particulate jet being less than the velocity of the oxidant-rich jet; allowing the supersonic oxidant-rich jet and the fuel-rich particulate jet to coact to form a coherent particulate fuel-rich and fuel-lean jet having a central particulate fuel-rich region and a coaxial annular fuel-lean region; impinging the coherent particulate fuel-rich and fuel-lean jet upon the surface to be heated for forming a turbulent reaction zone at the surface; and controlling oxidation and reduction reactions at the turbulent reaction zone by adjusting properties of the supersonic oxidant-rich jet and/or the fuel-rich particulate jet.

Abstract: The invention provides a method and apparatus for producing nitrogen trifluoride. The invention involves passing a working fluid through a heat engine cycle and using the mechanical energy generated by the working fluid to produce sufficient mixing intensity within a nitrogen trifluoride reactor. The method utilizes a working fluid vapor jet, such as a hydrogen fluoride vapor jet, to impart sufficient energy to the mixing zone of a reactor in order to disperse gaseous fluorine within a liquid ammonium acid fluoride melt. A gaseous reaction product stream is removed from the reactor, the reaction product stream comprising nitrogen trifluoride and a working fluid vapor. The working fluid is then separated from the nitrogen trifluoride and recycled for reuse in the process, thereby completing a heat engine cycle.

Abstract: The present invention provides a method and apparatus for producing nitrogen trifluoride. The method comprises contacting a fluorine-containing feed stream with liquid ammonium acid fluoride in a reaction zone for time and under conditions sufficient to produce nitrogen trifluoride. During the contacting step, the effective melt acidity value of the liquid ammonium acid fluoride is decreased and a reaction product stream is removed. In one embodiment, a gaseous mixture of elemental fluorine and hydrogen fluoride is contacted with a bulk liquid ammonium acid fluoride, such that the initial effective melt acidity value is greater than the melt acidity value of the bulk liquid ammonium acid fluoride in the reaction zone.

Abstract: A method of heating a surface provides for a central fuel rich jet having a peripheral shroud of substantially stoichiometric combustion products and one or more fuel lean jets each having a peripheral shroud of substantially stoichiometric combustion products. The fuel lean jets are placed around the periphery of the central fuel rich jet. The fuel lean jet or jets each having shrouds of substantially stoichiometric combustion products and a careful choice of relative velocities for each results in minimizing the mixing of the fuel rich and fuel lean jets until they are at or near the surface of the material to be melted. The placement of the fuel lean jet and fuel rich jets may be reversed in applications where an oxidizing atmosphere is required at the surface to be heated.