Abstract: A preparation method of perovskite film based on semicarbazide hydrochloride (SEM-HCl) additive and a preparation method of photovoltaic device are provided, a perovskite optimized crystallization strategy is provided, a tin-based perovskite thin film is prepared based on a solution method, and a purpose of regulating and controlling perovskite crystallization is achieved by means of a cross-linking effect of special groups in SEM-HCl and perovskite components. Defects of crystals of the prepared perovskite film are reduced, the non-radiative recombination in a transmission process of carriers is suppressed, and a photoelectric conversion efficiency and a photovoltaic device stability are remarkably improved.

Abstract: A preparation method of perovskite film based on semicarbazide hydrochloride (SEM-HCl) additive and a preparation method of photovoltaic device are provided, a perovskite optimized crystallization strategy is provided, a tin-based perovskite thin film is prepared based on a solution method, and a purpose of regulating and controlling perovskite crystallization is achieved by means of a cross-linking effect of special groups in SEM-HCl and perovskite components. Defects of crystals of the prepared perovskite film are reduced, the non-radiative recombination in a transmission process of carriers is suppressed, and a photoelectric conversion efficiency and a photovoltaic device stability are remarkably improved.

Abstract: The invention provides long-persistent phosphors, methods for their manufacture and phosphorescent articles. The invention also provides a method for generating a long-persistent phosphorescence at a selected color. The phosphors of the invention may be alkaline earth aluminates, alkaline earth silicates, and alkaline earth aluminosilicates. The phosphors include those activated by cerium. The phosphors also include those in which persistent energy transfer occurs from a donor ion to an acceptor ion, producing persistent emission largely characteristic of the acceptor ion.

Abstract: The invention provides long-persistent phosphors, methods for their manufacture and phosphorescent articles. The invention also provides a method for generating a long-persistent phosphorescence at a selected color. The phosphors of the invention may be alkaline earth aluminates, alkaline earth silicates, and alkaline earth aluminosilicates. The phosphors include those activated by cerium. The phosphors also include those in which persistent energy transfer occurs from a donor ion to an acceptor ion, producing persistent emission largely characteristic of the acceptor ion.