Abstract: A cement mix for preparation of a magnesium silico-phosphate cement (MSPC) with an altered hardening rate is provided. The cement mix comprises on the order of 1% of an [MF6]n? salt or acid. Upon addition of water, the mix produces a final set cement that has similar physical properties to those of a cement prepared from a mix lacking the additive, but with a significantly altered setting time. In some embodiments of the invention, the additive is provided in the form of a coating for the MgO component of the mix. In preferred embodiments, H2TiF6, Na2TiF6 and/or K2TiF6 are used as retarders, while K3AlF6 is used as an accelerant. Other embodiments use M?nMF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: A method is provided for advantageously altering the rate of hardening of a magnesium silico-phosphate cement (MSPC). Addition of on the order of 1% of an [MF6]n? salt or acid to an MSPC, obtained by adding the salt or acid either directly to the dry mix or to the water used to effect hydraulic hardening of the cement, significantly alters the hardening rate without adversely affecting the physical properties of the final set cement. In preferred embodiments, Na2TiF6 and/or K2TiF6 are used as retardants, while K3AlF6 is used as an accelerant. Other embodiments use M?n-MF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), Si (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: A method is provided for advantageously altering the rate of hardening of a magnesium silico-phosphate cement (MSPC). Addition of on the order of 1% of an [MF6]n? salt or acid to an MSPC, obtained by adding the salt or acid either directly to the dry mix or to the water used to effect hydraulic hardening of the cement, significantly alters the hardening rate without adversely affecting the physical properties of the final set cement. In preferred embodiments, Na2TiF6 and/or K2TiF6 are used as retardants, while K3AlF6 is used as an accelerant. Other embodiments use M?n-MF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), Si (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: Compositions are provided for alleviating or preventing discoloration, known as “scorching”, in flame-retarded flexible polyurethane foams. The anti-scorch compositions contain combinations of antioxidant agents, epoxy compounds, organic phosphites—alone or in combination with metal salts of carboxylic acids. The compositions are useful, for example, for polyurethane foams retarded with aliphatic or aromatic phosphorus-based flame retardants, or with halogen-containing flame retardants.

Abstract: Compositions and methods for alleviating or preventing discoloration in flame-retarded flexible polyurethane foams, known as “scorching”, are provided. The anti-scorch compositions contain antioxidant agents combined with at least one, and preferably with two, additional compounds selected from ?-diketone compounds, epoxy compounds, organic phosphites or phosphonites, and metal salts of carboxylic acids.

Abstract: An anti-scorch composition for flame-retarded flexible polyurethane foams, comprising, in combination, one or more antioxidant agents, together with one or more salt(s) of an organic acid.