Patents by Inventor Douglas H. Adamson

Douglas H. Adamson has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11731143
    Abstract: A machine or apparatus featuring a first processor and a second processor. The first processor is configured to receive a mixture of fluid, valuable material and unwanted material and a functionalized polymer coated member configured to attach to the valuable material in an attachment rich environment, and provide an enriched functionalized polymer coated member having the valuable material attached thereto. The second processor is configured to receive a fluid and the enriched functionalized polymer coated member in a release rich environment to release the valuable material, and provide the valuable material released from the enriched functionalized polymer coated member.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: August 22, 2023
    Assignee: CiDRA CORPORATE SERVICES INC.
    Inventors: Paul J. Rothman, Mark R. Fernald, Francis K. Didden, Christian V. O'Keefe, Douglas H. Adamson
  • Publication number: 20230257271
    Abstract: Systems and methods are provided that may utilize a glass substrate to selectively withdraw exfoliated graphene from a high-energy interface between immiscible solvents. The exfoliated graphene preferentially adheres to the surface of the glass substrate for withdrawal from the noted high energy interface, leaving behind the graphite (which is too large to be effectively adsorbed relative to the glass substrate). The disclosed systems and methods are easily implemented and offer significant advantages for graphene production relative to conventional systems and methods, e.g., the disclosed systems/methods do not require the input of heat or mechanical energy which translates to processes that are both cheaper to run and do not result in damage to the graphene. Still further, the disclosed systems/methods do not require chemical modification of the graphene, again lowering the cost considerably and not damaging the graphene structure.
    Type: Application
    Filed: February 17, 2022
    Publication date: August 17, 2023
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Richard Parnas, Prabodha Abeykoon
  • Publication number: 20230235186
    Abstract: The present disclosure provides advantageous sheet stabilized emulsion based inks, and improved methods for fabricating and using such inks. More particularly, the present disclosure provides improved methods for fabricating conductive inks derived from water-in-oil emulsions stabilized by sheets exfoliated from layered materials (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride), and related methods of use. A layered material (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride) can be exfoliated into individual sheets, and these sheets can be utilized to stabilize water-in-oil emulsions. In certain embodiments, by utilizing long chain alkanes (e.g., hexadecane), one can advantageously fabricate emulsions with high viscosity and stability. In this form, the emulsions can be used as inks, thereby advantageously providing an inexpensive route to printing electrically conducting and/or insulating lines and shapes.
    Type: Application
    Filed: January 27, 2023
    Publication date: July 27, 2023
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Feiyang Chen, Elizabeth Brown
  • Publication number: 20220194858
    Abstract: Porous, electrically conductive ceramic foams incorporating continuous self-assembled graphene networks are described. The disclosed approach uses interfacial trapping to spontaneously exfoliate and assemble pristine graphite, not graphite oxide, in a ceramic sol-gel. The composite foams display electrical conductivity and joule heating, with anticipated applications as, for example, catalyst supports, thermoelectrics, and porous electrodes.
    Type: Application
    Filed: December 15, 2021
    Publication date: June 23, 2022
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Garrett Kraft
  • Patent number: 11355259
    Abstract: The present disclosure provides advantageous graphene/graphite stabilized composites (e.g., graphene/graphite stabilized emulsion-templated foam composites), and improved methods for fabricating such graphene/graphite stabilized composites. More particularly, the present disclosure provides improved methods for fabricating pristine, graphene/graphite/polymer composite foams derived from emulsions stabilized by graphene/graphite kinetic trapping. In exemplary embodiments, the present disclosure provides that, instead of viewing the insolubility of pristine graphene/graphite as an obstacle to be overcome, it is utilized as a means to create or fabricate water/oil emulsions, with graphene/graphite stabilizing the spheres formed. These emulsions are then the frameworks used to make foam composites that have shown bulk conductivities up to about 2 S/m, as well as compressive moduli up to about 100 MPa and breaking strengths of over 1200 psi, with densities as low as about 0.25 g/cm3.
    Type: Grant
    Filed: October 8, 2020
    Date of Patent: June 7, 2022
    Assignee: University of Connecticut
    Inventors: Douglas H. Adamson, Steven Woltornist, Andrey V. Dobrynin
  • Publication number: 20210379603
    Abstract: An engineered collection medium for use in mineral separation is described. The engineered collection medium has a solid phase body configured with a three-dimensional open-cell structure like foam or sponge to provide collection surfaces. The three-dimensional surface structure is made of a hydrophobic material which is a reaction product of isocyanate and polyol promotes the attraction of mineral particles to the collection surfaces as a hydrophobic foam. The hydrophobic foam can be in the form of a cube, sphere, or sheet and can be used in a filter or conveyor belt in a processor.
    Type: Application
    Filed: February 7, 2019
    Publication date: December 9, 2021
    Inventors: Paul J. ROTHMAN, Mark R. FERNALD, Francis DIDDEN, Christian V. O'KEEFE, Douglas H. ADAMSON, Paul DOLAN, Timothy J. BAILEY, Michael Stephen RYAN, Weiguo HUANG, Kevin Rodney LASSILA, Michael D. COPPOLA, Allison K. GREENE
  • Patent number: 11135597
    Abstract: A synthetic bead for use in mineral separation is described. The synthetic bead has a surface made of a synthetic material such as polymer and the synthetic material is functionalized with molecules having a functional group for attaching mineral particles to the surface in a separation process. The synthetic beads can be placed in flotation cell containing a mixture of water, valuable material and unwanted material or in a pipeline where the mixture is transported from one location to another. The enriched synthetic beads carrying the mineral particles are separated from the unwanted materials in the mixture. The mineral particles are then released from the synthetic beads by means of low pH treatment, ultrasonic agitation, thermal or electromagnetic treatment.
    Type: Grant
    Filed: April 12, 2018
    Date of Patent: October 5, 2021
    Assignee: CIDRA CORPORATE SERVICES LLC
    Inventors: Paul J. Rothman, Mark R. Fernald, Francis K. Didden, Christian V. O'Keefe, Douglas H. Adamson
  • Patent number: 11117141
    Abstract: Apparatus for use in, or forming part of, a separation process to be implemented in separation processor technology, the apparatus comprising synthetic bubbles or beads configured with a polymer or polymer-based material functionalized to attach to a valuable material in a mixture so as to form an enriched synthetic bubbles or beads having the valuable material attached thereto, and also configured to be separated from the mixture based at least partly on a difference in a physical property between the enriched synthetic bubbles or beads having the valuable material attached thereto and the mixture.
    Type: Grant
    Filed: October 26, 2017
    Date of Patent: September 14, 2021
    Assignee: CIDRA CORPORATE SERVICES INC.
    Inventors: Paul J. Rothman, Mark R. Fernald, Francis K. Didden, Christian V. O'Keefe, Alan D. Kersey, Douglas H. Adamson
  • Patent number: 11004606
    Abstract: The present disclosure provides advantageous composite films/coatings, and improved methods for fabricating such composite films/coatings. More particularly, the present disclosure provides improved methods for fabricating composite films by trapping at least a portion of a layered material (e.g., hexagonal boron nitride sheets/layers) at an interface of a phase separated system and then introducing the layered material to a polymer film. The present disclosure provides for the use of boron nitride layers to increase the properties (e.g., dielectric constant and breakdown voltage) of polymer films. The exemplary films can be produced by an advantageous climbing technique. Exemplary boron nitride films are composed of overlapping boron nitride sheets with a total thickness of about one nanometer, with the film then transferred onto a polymer film, thereby resulting in significant increases in both dielectric and breakdown properties of the polymer film.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: May 11, 2021
    Assignee: University of Connecticut
    Inventors: Douglas H. Adamson, Zhenhua Cui, Andrey V. Dobrynin
  • Publication number: 20210027907
    Abstract: The present disclosure provides advantageous graphene/graphite stabilized composites (e.g., graphene/graphite stabilized emulsion-templated foam composites), and improved methods for fabricating such graphene/graphite stabilized composites. More particularly, the present disclosure provides improved methods for fabricating pristine, graphene/graphite/polymer composite foams derived from emulsions stabilized by graphene/graphite kinetic trapping. In exemplary embodiments, the present disclosure provides that, instead of viewing the insolubility of pristine graphene/graphite as an obstacle to be overcome, it is utilized as a means to create or fabricate water/oil emulsions, with graphene/graphite stabilizing the spheres formed. These emulsions are then the frameworks used to make foam composites that have shown bulk conductivities up to about 2 S/m, as well as compressive moduli up to about 100 MPa and breaking strengths of over 1200 psi, with densities as low as about 0.25 g/cm3.
    Type: Application
    Filed: October 8, 2020
    Publication date: January 28, 2021
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Steven Woltornist, Andrey V. Dobrynin
  • Publication number: 20200407571
    Abstract: The present disclosure provides advantageous sheet stabilized emulsion based inks, and improved methods for fabricating and using such inks. More particularly, the present disclosure provides improved methods for fabricating conductive inks derived from water-in-oil emulsions stabilized by sheets exfoliated from layered materials (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride), and related methods of use. A layered material (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride) can be exfoliated into individual sheets, and these sheets can be utilized to stabilize water-in-oil emulsions. In certain embodiments, by utilizing long chain alkanes (e.g., hexadecane), one can advantageously fabricate emulsions with high viscosity and stability. In this form, the emulsions can be used as inks, thereby advantageously providing an inexpensive route to printing electrically conducting and/or insulating lines and shapes.
    Type: Application
    Filed: October 31, 2018
    Publication date: December 31, 2020
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Feiyang Chen, Elizabeth Brown
  • Patent number: 10835905
    Abstract: An engineered collection medium for use in mineral separation is described. The engineered collection medium has a solid phase body configured with a three-dimensional open-cell structure like foam or sponge to provide collection surfaces. The surfaces are functionalized with a hydrophobic chemical having molecules with a functional group for attaching mineral particles to the collection surfaces. The engineered collection medium can be a foam block, a filter or conveyor belt to be placed in a slurry to collect mineral particles in the slurry. The engineered collection medium carrying the mineral particles is provided to a release apparatus where the mineral particles can be released by using mechanical agitation, sonic agitation and so forth.
    Type: Grant
    Filed: January 9, 2017
    Date of Patent: November 17, 2020
    Assignee: CIDRA CORPORATE SERVICES INC.
    Inventors: Paul J. Rothman, Mark R. Fernald, Francis Didden, Christian V. O'Keefe, Douglas H. Adamson, Paul Dolan, Timothy J. Bailey, Michael Ryan
  • Patent number: 10832828
    Abstract: The present disclosure provides advantageous graphene/graphite stabilized composites (e.g., graphene/graphite stabilized emulsion-templated foam composites), and improved methods for fabricating such graphene/graphite stabilized composites. More particularly, the present disclosure provides improved methods for fabricating pristine, graphene/graphite/polymer composite foams derived from emulsions stabilized by graphene/graphite kinetic trapping. In exemplary embodiments, the present disclosure provides that, instead of viewing the insolubility of pristine graphene/graphite as an obstacle to be overcome, it is utilized as a means to create or fabricate water/oil emulsions, with graphene/graphite stabilizing the spheres formed. These emulsions are then the frameworks used to make foam composites that have shown bulk conductivities up to about 2 S/m, as well as compressive moduli up to about 100 MPa and breaking strengths of over 1200 psi, with densities as low as about 0.25 g/cm3.
    Type: Grant
    Filed: March 2, 2017
    Date of Patent: November 10, 2020
    Assignee: University of Connecticut
    Inventors: Douglas H. Adamson, Steven Woltornist, Andrey V. Dobrynin
  • Patent number: 10751693
    Abstract: Apparatus or recovering a mineral particle of interest from a slurry in a mineral extraction process, featuring a core or substrate; and multiple layers arranged on the core or substrate, each layer of the multiple layers configured with a respective outer surface having a plurality of molecules attached thereto, the molecules comprising a functional group selected for attracting and attaching one or more mineral particles of interest to the molecules. Each layer is made from a polymer having a thickness of less than or equal to about 125 microns. The polymer is selected from a group consisting of polydimethylsiloxane or dimethyl siloxane.
    Type: Grant
    Filed: June 1, 2015
    Date of Patent: August 25, 2020
    Assignee: CiDRA Corporate Service Inc.
    Inventors: Paul J. Rothman, Mark R. Fernald, Christian V. O'Keefe, Douglas H. Adamson
  • Patent number: 10357782
    Abstract: Apparatus, such as a flotation separation device, features a flotation cell or column configured to receive a mixture of water, valuable material and unwanted material; receive polymer-based materials, including polymer bubbles or beads, configured to attach to the valuable material in the mixture; and provide enriched polymer-based materials, including enriched polymer bubbles or beads, having the valuable material attached thereon.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: July 23, 2019
    Assignee: CiDRA Corporate Services LLC
    Inventors: Paul J. Rothman, Mark R. Fernald, Francis K. Didden, Christian V. O'Keefe, Alan D. Kersey, Douglas H. Adamson
  • Publication number: 20190201914
    Abstract: A synthetic bead for use in mineral separation is described. The synthetic bead has a surface made of a synthetic material such as polymer and the synthetic material is functionalized with molecules having a functional group for attaching mineral particles to the surface in a separation process. The synthetic beads can be placed in flotation cell containing a mixture of water, valuable material and unwanted material or in a pipeline where the mixture is transported from one location to another. The enriched synthetic beads carrying the mineral particles are separated from the unwanted materials in the mixture. The mineral particles are then released from the synthetic beads by means of low pH treatment, ultrasonic agitation, thermal or electromagnetic treatment.
    Type: Application
    Filed: April 12, 2018
    Publication date: July 4, 2019
    Inventors: Paul J. ROTHMAN, Mark R. FERNALD, Francis K. DIDDEN, Christian V. O'KEEFE, Douglas H. ADAMSON
  • Patent number: 10266413
    Abstract: A method to fractionate and isolate components of oxidized graphene material is provided that includes fractionating a system that includes graphene oxide, a solvent and water, wherein the fractionation creates two phases or fractions: (i) a water phase or fraction that contains highly oxidized graphene oxide, and (ii) a solvent-in-water emulsion phase or fraction that contains a graphene-based material. The graphene-based material is recovered from the solvent-in-water phase or fraction. Fractionation of the solvent-in-water emulsion phase or fraction may be repeated. The graphene-based material (uGO) may be used in a range of applications, e.g., a medical device, a nanoelectronic, an electromechanical system, a sensor, a composite, a catalysis, and energy storage device, and an optics application.
    Type: Grant
    Filed: November 3, 2017
    Date of Patent: April 23, 2019
    Assignee: University of Connecticut
    Inventors: Douglas H. Adamson, Harish Kumar
  • Patent number: 10245597
    Abstract: Apparatus is provided featuring a first and second cells. The first cell receives an ore slurry having mineral particles of interest, receives unexpanded polymer microspheres comprising a surface having mineral collector chemistry attached thereto with molecules for attaching the mineral particles of interest, causes the unexpanded polymer microspheres to expand substantially in volume into expanded polymer microspheres having a substantially increased sphere surface area, and provides an expanded polymer microsphere foam layer comprising the expanded polymer microspheres with attached mineral particles of interest. The second cell receives the expanded polymer microsphere foam layer, and causes the expanded polymer microspheres to collapse substantially in volume into collapsed polymer microspheres having a substantially reduced sphere surface area that results in a mechanical shearing off of the attached mineral particles of interest.
    Type: Grant
    Filed: April 1, 2013
    Date of Patent: April 2, 2019
    Assignee: CiDRA Corporate Services Inc.
    Inventors: Francis K. Didden, Alan D. Kersey, Michael A. Davis, Paul J. Rothman, Mark R. Fernald, Christian V. O'Keefe, Douglas H. Adamson
  • Publication number: 20180323009
    Abstract: The present disclosure provides advantageous composite films/coatings, and improved methods for fabricating such composite films/coatings. More particularly, the present disclosure provides improved methods for fabricating composite films by trapping at least a portion of a layered material (e.g., hexagonal boron nitride sheets/layers) at an interface of a phase separated system and then introducing the layered material to a polymer film. The present disclosure provides for the use of boron nitride layers to increase the properties (e.g., dielectric constant and breakdown voltage) of polymer films. The exemplary films can be produced by an advantageous climbing technique. Exemplary boron nitride films are composed of overlapping boron nitride sheets with a total thickness of about one nanometer, with the film then transferred onto a polymer film, thereby resulting in significant increases in both dielectric and breakdown properties of the polymer film.
    Type: Application
    Filed: July 17, 2018
    Publication date: November 8, 2018
    Applicant: University of Connecticut
    Inventors: Douglas H. Adamson, Zhenhua Cui, Andrey V. Dobrynin
  • Patent number: 10060570
    Abstract: Apparatus, including a pipeline, featuring at least one pipe liner or coating configured to line or coat a pipe for receiving a process fluid flow, configured with at least one chemical taggant or tracer, and also configured to respond to the process fluid flow, and provide an indication about a degree of liner or coating wear or a location of wear in the pipe. The apparatus may also include the pipe having the at least one pipe liner or coating configured therein.
    Type: Grant
    Filed: January 9, 2014
    Date of Patent: August 28, 2018
    Assignee: CiDRA CORPORATE SERVICES, INC.
    Inventors: Alan D. Kersey, Michael Puig, Francis K. Didden, Douglas H. Adamson