Abstract: A reflective film includes a first optical stack that provides a first reflective characteristic and a second optical stack that provides a second reflective characteristic. The optical stacks also have first and second absorptive characteristics that are suitable to absorptively heat the respective stacks upon exposure to light including a write wavelength while maintaining the structural integrity of the stacks. The absorptive heating can change the first and second reflective characteristics to third and fourth reflective characteristics, respectively. A blocking layer that at least partially blocks light of the write wavelength may also be provided between the optical stacks to permit absorptive heating of any selected one of the optical stacks. The reflective characteristics of the optical stacks can thus be independently modified in any desired patterns by appropriate delivery of light beams that include the write wavelength.

Abstract: A reflective film includes interior layers that selectively reflect light by constructive or destructive interference, the layers extending from a first to a second zone of the film. In the first zone, the layers operate substantially as a reflective polarizer; in the second zone they operate substantially as a mirror. The layers may thus provide a first reflective characteristic in the first zone wherein normally incident light of one polarization state is substantially reflected and normally incident light of an orthogonal polarization state is substantially transmitted, and a second reflective characteristic in the second zone wherein normally incident light of any polarization state is substantially reflected. The film may have a first thickness in the first zone that is substantially the same as a second thickness in the second zone. Alternatively, the second thickness may be substantially less than the first thickness. Related methods, articles, and systems are also disclosed.

Abstract: A reflective film includes a first optical stack that provides a first reflective characteristic and a second optical stack that provides a second reflective characteristic. The optical stacks also have first and second absorptive characteristics that are suitable to absorptively heat the respective stacks upon exposure to light including a write wavelength while maintaining the structural integrity of the stacks. The absorptive heating can change the first and second reflective characteristics to third and fourth reflective characteristics, respectively. A blocking layer that at least partially blocks light of the write wavelength may also be provided between the optical stacks to permit absorptive heating of any selected one of the optical stacks. The reflective characteristics of the optical stacks can thus be independently modified in any desired patterns by appropriate delivery of light beams that include the write wavelength.

Abstract: A reflective film includes interior layers that selectively reflect light by constructive or destructive interference, the layers extending from a first to a second zone of the film. In the first zone, the layers operate substantially as a reflective polarizer; in the second zone they operate substantially as a mirror. The layers may thus provide a first reflective characteristic in the first zone wherein normally incident light of one polarization state is substantially reflected and normally incident light of an orthogonal polarization state is substantially transmitted, and a second reflective characteristic in the second zone wherein normally incident light of any polarization state is substantially reflected. The film may have a first thickness in the first zone that is substantially the same as a second thickness in the second zone. Alternatively, the second thickness may be substantially less than the first thickness.

Abstract: Multi-layer articles are described that are capable of forming color images. The articles may contain at least two layers, a thermally activatable layer and a blocking layer, or at least three layers with two thermally activatable layers and a blocking layer between. The thermally activatable layers absorb light of a write wavelength and have an absorption threshold for activation. The blocking layer blocks light of the write wavelength at certain incident angles or polarization states and permits light of the write wavelength and certain incident angles or polarization states to pass through. The thermally activatable layers may be layers with a light to heat convertor composition and a color changing compound or they may be a group of layers arranged to change its reflective characteristic upon exposure to light while maintaining the structural integrity of the group of layers.

Abstract: Multi-layer articles are described that are capable of forming color images. The articles include at least six layers, four thermally activatable layers (layers 1-4) and two blocking layers (layer 5 and 6). The layers are arranged such that layer 5 is disposed between layers 1 and 2 and layer 6 is disposed between layers 3 and 4. Thermally activatable layers 1 and 2 are activatable upon exposure to light of a first write wavelength, and blocking layer 5 is adapted to at least partially block light of the first write wavelength. Thermally activatable layers 3 and 4 are activatable upon exposure to light of a second write wavelength, and blocking layer 6 is adapted to at least partially block light of the second write wavelength. At least one, and possibly all of the thermally activatable layers include a light to heat convertor composition and a color changing compound.

Abstract: A reflective film includes interior layers arranged to selectively reflect light by constructive or destructive interference, the layers extending from a first zone to a second zone of the film. The film has a first thickness and the interior layers provide a first reflective characteristic in the first zone; the film has a second thickness and the interior layers provide a second reflective characteristic in the second zone. The difference between the first and second reflective characteristics is not substantially attributable to any difference between the first and second thicknesses, which difference may be zero. Rather, the difference in the reflective characteristics is substantially attributable to reduced birefringence of at least some of the interior layers in one zone relative to the other zone. The film may also incorporate absorbing agents to assist in the manufacture or processing of the film. Related methods and articles are also disclosed.

Abstract: A reflective film includes interior layers arranged to selectively reflect light by constructive or destructive interference, the layers extending from a first zone to a second zone of the film. The film has a first thickness and the interior layers provide a first reflective characteristic in the first zone; the film has a second thickness and the interior layers provide a second reflective characteristic in the second zone. The difference between the first and second reflective characteristics is not substantially attributable to any difference between the first and second thicknesses, which difference may be zero. Rather, the difference in the reflective characteristics is substantially attributable to reduced birefringence of at least some of the interior layers in one zone relative to the other zone. The film may also incorporate absorbing agents to assist in the manufacture or processing of the film. Related methods and articles are also disclosed.

Abstract: A method for building three-dimensional articles using a thermal polymerization process in provided. The articles are built by using a composition that includes a thermally polymerizable composition, a thermal initiator, and a nonlinear light-to-heat conversion material such as a reverse saturable dye. The article is built by the sequential exposure of adjacent voxels with a laser beam. Microlens arrays can be used to expose more than one voxel at a time.

Abstract: A reflective film includes interior layers that selectively reflect light by constructive or destructive interference, the layers extending from a first to a second zone of the film. The interior layers include a first set of layers composed of a first material and a second set of layers composed of a different second material. The first and second sets of layers are both birefringent in the first zone, but at least some of the layers have reduced birefringence in the second zone. The reduced birefringence produces a second reflective characteristic in the second zone that differs from a first reflective characteristic in the first zone, this difference not being substantially attributable to any thickness difference between the first and second zones. The film may also incorporate absorbing agents to assist in the manufacture or processing of the film.

Abstract: Laser-personalizable security articles include multi-layer security documents. The multi-layer security document includes an optically transparent cover layer, a composite image and an imagable layer adjacent to the cover layer. The first surface of the cover layer is at least partially a microstructured surface, where the microstructured surface forms microlenses or a lenticular surface. The composite image is made by a collection of complete or partial images viewed through the microstructured surface of the cover layer. The composite image is located on or within the second surface of the cover layer. The imagable layer is a laser imagable layer. When imaged, a personalized second composite three dimensional image is created on or in the imagable layer.

Abstract: Material comprising sub-micrometer particles dispersed in a polymeric matrix. The materials are useful in article, for example, for numerous applications including display applications (e.g., liquid crystal displays (LCD), light emitting diode (LED) displays, or plasma displays); light extraction; electromagnetic interference (EMI) shielding, ophthalmic lenses; face shielding lenses or films; window films; antireflection for construction applications; and construction applications or traffic signs.

Abstract: A method including: a. coating at least a portion of at least one major surface of a substrate with a polymerizable composition to obtain a coated surface; b. initiating polymerization of the polymerizable composition by scanning a first electron-beam focused on the coated surface across at least a portion of the coated surface, thereby irradiating the coated surface at a frequency selected to achieve an exposure duration of greater than 0 and no greater than 10 microseconds, and a dark time between each exposure duration of at least one millisecond, thereby producing an at least partially polymerized composition. A pressure sensitive adhesive article and a cross-linked silicone release liner made according to the method are also disclosed.

Abstract: A retarder film provides a first light retardation and can be heat processed in one or more selected areas to provide a second light retardation in the selected area(s). The retarder film may have an absorption characteristic such that the heat processing can be carried out by selectively exposing the film to a suitable radiant beam. The retarder film is composed of a stack of contiguous ultrathin layers configured to provide an effective optical medium for visible light. Visible light propagates through the stack as an effective medium having effective refractive indices along principal x-, y-, and z-axes. At least some of the ultrathin layers possess intrinsic birefringence, and the effective indices of the stack are functions of the intrinsic refractive indices of the constituent ultrathin layers. The heat processing is carried out so that the ultrathin layer stack structural integrity is not substantially altered in the processed area(s).

Abstract: Techniques are described for forming microlens sheeting having composite images that appear to float with respect to the plane of the sheeting. As one example, a method comprises forming one or more images within a sheeting having a surface of microlenses, wherein at least one of the images is a partially complete image, and wherein each of the images is associated with a different one of the microlenses, wherein the microlenses have refractive surfaces that transmit light to positions within the sheeting to produce a plurality of composite images from the images formed within the sheeting so that each of the composite images appears to float with respect to the plane of the sheeting, and wherein forming the one or more images comprises forming the one or more images such that each of the composite images is associated with a different viewing angle range.

Abstract: Multi-layer articles are described that are capable of forming color images. The articles may contain at least two layers, a thermally activatable layer and a blocking layer, or at least three layers with two thermally activatable layers and a blocking layer between. The thermally activatable layers absorb light of a write wavelength and have an absorption threshold for activation. The blocking layer blocks light of the write wavelength at certain incident angles or polarization states and permits light of the write wavelength and certain incident angles or polarization states to pass through.

Abstract: Multi-layer articles are described that are capable of forming color images. The articles include at least six layers, four thermally activatable layers (layers 1-4) and two blocking layers (layer 5 and 6). The layers are arranged such that layer 5 is disposed between layers 1 and 2 and layer 6 is disposed between layers 3 and 4. Thermally activatable layers 1 and 2 are activatable upon exposure to light of a first write wavelength, and blocking layer 5 is adapted to at least partially block light of the first write wavelength. Thermally activatable layers 3 and 4 are activatable upon exposure to light of a second write wavelength, and blocking layer 6 is adapted to at least partially block light of the second write wavelength. At least one, and possibly all of the thermally activatable layers include a light to heat convertor composition and a color changing compound.

Abstract: Certain patternable reflective films are used as masks to make other patterned articles, and one or more initial masks can be used to pattern the patternable reflective films. An exemplary patternable reflective film has an absorption characteristic suitable to, upon exposure to a radiant beam, absorptively heat a portion of the film by an amount sufficient to change a first reflective characteristic to a different second reflective characteristic. The change from the first to the second reflective characteristic is attributable to a change in birefringence of one or more layers or materials of the patternable film. In a related article, a mask is attached to such a patternable reflective film. The mask may have opaque portions and light-transmissive portions. Further, the mask may have light-transmissive portions with structures such as focusing elements and/or prismatic elements.

Abstract: Methods for generating a color image are provided which include a multi-layer construction in which at least one of the layers is a thermally activatable layer that includes a thermally activatable composition. The thermally activatable composition includes a non-linear light to heat converter composition and a color forming compound. Upon activation with a light source an image forms.

Abstract: Translucent, transparent, or semi-translucent microlens sheetings with composite images are disclosed, in which a composite image floats above or below the sheeting, or both. The composite image may be two-dimensional or three-dimensional. The sheeting may have at least one layer of material having a surface of microlenses that form one or more images at positions internal to the layer of material, at least one of the images being a partially complete image. Additional layers, such as retroreflective, translucent, transparent, or optical structure layers may also be incorporated into the sheeting.