Abstract: A process for killing insects by applying to said insects and to substrates susceptable to infestation by said insects and their larvae an insecticidally effective amount of a composition containing at least one compound of the formula: ##STR1## where: R is alkyl of 1 through 10 carbon atoms, substituted alkyl of 1 through 8 carbon atoms, aryl of 5 through 10 carbon atoms, substituted phenyl, aralkyl of 5 through 13 carbon atoms, substituted aralkyl of 5 through 13 carbon atoms, alkenyl of 3 through 8 carbon atoms, alkynyl of 3 through 8 carbon atoms, cycloalkyl of 3 through 12 carbon atoms, cycloalkenyl of 4 through 12 carbon atoms, cycloalkyl alkyl of 4 through 13 carbon atoms, cycloalkenyl alkyl of 5 through 13 carbon atoms, (substituted cycloalkyl)alkyl of 5 through 14 carbon atoms, (substituted cycloalkenyl)alkyl of 5 through 14 carbon atoms, and cyano;R.sub.

Abstract: An alkyl 1-hexamethyleneimine-carbothiolate in low concentration has been found insecticidally active in the treatment of substrates which contain or are susceptable to infestation by insects and their larvae, particularly Diptera, and more particularly mosquitoes. The alkyl 1-hexamethylene-carbothiolate can be formulated and applied as a solution, aerosol or admixture within which it is dispersed as an insecticidally effective ingredient.