Patents by Inventor Drake M. Michno
Drake M. Michno has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20110236838Abstract: Color silver halide photographic elements having a yellow dye image-forming unit comprises at least one blue-sensitive silver iodobromide emulsion layer that has silver iodobromide grains. The silver iodobromide grains have initially associated therewith at least two blue spectral sensitizing dye layers comprising: (a) an inner dye layer adjacent the silver iodobromide grains comprising at least one anionic blue spectral sensitizing Dye 1, and (b) an outer dye layer adjacent to the inner dye layer comprising at least one cationic blue spectral sensitizing Dye 2. Dye 2 absorbs light at equal or higher energy than Dye 1. The maximum energy emission wavelength of Dye 2 overlaps but is not exactly corresponding to the maximum energy absorption wavelength of Dye 1. The silver iodobromide grains also have initially associated therewith an amine borane compound and a thiosulfonate compound.Type: ApplicationFiled: March 26, 2010Publication date: September 29, 2011Inventors: David R. Foster, Drake M. Michno
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Publication number: 20090325108Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.Type: ApplicationFiled: June 27, 2008Publication date: December 31, 2009Inventors: Paul L. Zengerle, John W. Harder, Drake M. Michno, James H. Reynolds, Steven P. Szatynski
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Patent number: 7632632Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.Type: GrantFiled: June 27, 2008Date of Patent: December 15, 2009Assignee: Eastman Kodak CompanyInventors: Paul L. Zengerle, John W. Harder, Drake M. Michno, James H. Reynolds, Steven P. Szatynski
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Patent number: 7629112Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.Type: GrantFiled: May 30, 2008Date of Patent: December 8, 2009Assignee: Eastman Kodak CompanyInventors: Paul L. Zengerle, Drake M. Michno, James H. Reynolds, Steven P. Szatynski, John W. Harder
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Publication number: 20090297992Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.Type: ApplicationFiled: May 30, 2008Publication date: December 3, 2009Inventors: Paul L. Zengerle, Drake M. Michno, James H. Reynolds, Steven P. Szatynski, John W. Harder
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Patent number: 6811963Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver haType: GrantFiled: January 17, 2003Date of Patent: November 2, 2004Assignee: Eastman Kodak CompanyInventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
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Publication number: 20040146815Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver haType: ApplicationFiled: January 17, 2003Publication date: July 29, 2004Inventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
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Patent number: 6699652Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver haType: GrantFiled: January 17, 2003Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
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Patent number: 6680165Abstract: The invention provides a color negative photographic element comprising a light sensitive silver halide emulsion imaging layer having associated therewith a cyan dye-forming coupler dispersion comprising a first 2-ureido-5-acylamino substituted phenolic cyan dye-forming coupler [P], a second phenolic cyan dye-forming coupler [AP] where the 2-substituent is other than an ureido group, a substantially non-color-developable phenolic activator compound [ACT], and a non-phenolic organic coupler solvent having a boiling point of at least 150C; wherein compounds represented by [P], [AP], and [ACT] are present in the coupler dispersion in relative weight fractions of from 0.30 to 0.65 for [P], from 0.15 to 0.35 for [AP], and from 0.15 to 0.Type: GrantFiled: October 24, 2002Date of Patent: January 20, 2004Assignee: Eastman Kodak CompanyInventors: Jerrold N. Poslusny, Paul B. Merkel, David A. Steele, Drake M. Michno, David S. Ross, Richard K. Rothrock, Paul L. Zengerle
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Patent number: 6620580Abstract: Disclosed is a photographic element comprising a support bearing a blue light sensitive record containing at least three layers having different levels of light sensitivity arranged in the order slowest to fastest with the slowest layer closest to the support and the fastest layer closest to the light exposure source, wherein (a) all of the blue-sensitive layers are closer to the light exposure source than the layers sensitive to any other color; (b) the slowest blue light sensitive layer is at least 1.0 log E slower than the next fastest blue light sensitive layer when measured at a density of 0.15 above Dmin, and contains a particular type of cyan dye-forming development inhibitor releasing (DIR) coupler; and (c) all of the blue light sensitive layers other than the slowest blue light sensitive layer independently contain a certain type of yellow dye-forming DIR coupler. Embodiments of the invention provide improved color rendition without sacrificing blue density.Type: GrantFiled: November 14, 2001Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: Norma B. Platt, Drake M. Michno
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Publication number: 20030143498Abstract: Disclosed is a photographic element comprising a support bearing a blue light sensitive record containing at least three layers having different levels of light sensitivity arranged in the order slowest to fastest with the slowest layer closest to the support and the fastest layer closest to the light exposure source, wherein (a) all of the blue-sensitive layers are closer to the light exposure source than the layers sensitive to any other color; (b) the slowest blue light sensitive layer is at least 1.0 logE slower than the next fastest blue light sensitive layer when measured at a density of 0.15 above Dmin, and contains a particular type of cyan dye-forming development inhibitor releasing (DIR) coupler; and (c) all of the blue light sensitive layers other than the slowest blue light sensitive layer independently contain a certain type of yellow dye-forming DIR coupler. Embodiments of the invention provide improved color rendition without sacrificing blue density.Type: ApplicationFiled: November 14, 2001Publication date: July 31, 2003Applicant: Eastman Kodak CompanyInventors: Norma B. Platt, Drake M. Michno
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Patent number: 6043016Abstract: This invention comprises a photographic element, comprising a support bearing at least one silver halide emulsion and at least one malonanilide yellow dye-forming DIR coupler of structure I, below: ##STR1## wherein: R.sup.1 and R.sub.2 are individually selected from the group consisting of halogen atoms and alkoxycarbonyl, aryloxycarbonyl, carbamoyl, carbonamido, sulfonamido, sulfamoyl, alkylsulfonyl, arylsulfonyl, sulfonyloxy, acyloxy and cyano groups and each is in the para position or in either meta position relative to the NH group of the anilide;m and n are individually 0 or 1;R.sub.3 and R.sub.4 are individually a halogen atom or an alkyl group and may be in the para position or either meta position relative to the NH group of the anilide;X and Y are individually a halogen atom or an alkyl or alkoxy group; andR.sub.5 is an alkyl group with 3 to 10 carbon atoms or a phenyl group.Type: GrantFiled: December 11, 1998Date of Patent: March 28, 2000Assignee: Eastman Kodak CompanyInventors: Paul B. Merkel, Jerrold N. Poslusny, Drake M. Michno, Robert C. Stewart
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Patent number: 5599656Abstract: Photographic elements are disclosed having a first coupler represented by the formula:COUP.sub.1 -T-INHwhereinCOUP.sub.1 is a coupler moiety,T is a timing group bonded to INH through a substituted or unsubstituted methylene group contained in T and bonded to COUP.sub.1 through an O, S, or N atom contained in T,and INH is a development Inhibitor moiety, andwherein the T-INH group is able to undergo electron transfer along a conjugated system therein to cleave INH after T-INH is cleaved from COUP.sub.1, anda second coupler represented by the formula:COUP.sub.2 -(TIME).sub.n -S-R.sub.1 -R.sub.2wherein COUP.sub.2 is a coupler moiety, TIME is a timing group, n is 0 or 1, R.sub.1 is a divalent linking group that does not include a heterocyclic ring attached directly to S, and R.sub.2 is a water solubilizing group.Type: GrantFiled: August 6, 1990Date of Patent: February 4, 1997Assignee: Eastman Kodak CompanyInventors: Drake M. Michno, Richard P. Szajewski, Stephen P. Singer
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Patent number: 5460928Abstract: A color photographic element has a blue sensitive tabular grain silver halide emulsion layer the halide content of which is less than 80% chloride and which has a tabularity of at least 8. The foregoing emulsion is sensitized such that the wavelength of maximum sensitivity of the emulsion between 400-500 nm (".lambda..sub.Bmax "), the sensitivity at 485 nm ("S.sub.485 "), the sensitivity at 410 nm ("S.sub.410 "), and the sensitivity at .lambda..sub.Bmax (".lambda..sub.Bmax "), are defined by:430 nm.gtoreq..lambda..sub.Bmax .gtoreq.440 nm or 450 nm.gtoreq..lambda..sub.Bmax .gtoreq.480 nmandS.sub.485 .gtoreq.50% (S.sub.Bmax)S.sub.410 .gtoreq.60% (S.sub.Bmax)and the maximum sensitivity of the emulsion between 430-440 nm ("S.sub.(430-440)max "), and the maximum sensitivity between 450-480 nm ("S.sub.(450-480)max "), have the following relationship:90% (S.sub.(450-480)max).gtoreq.S.sub.(430-440)max .gtoreq.110%(S.sub.(450-480)max).Type: GrantFiled: April 15, 1994Date of Patent: October 24, 1995Assignee: Eastman Kodak CompanyInventors: Mamie Kam-Ng, Drake M. Michno, John D. Buhr
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Patent number: 5389504Abstract: A photographic element including a support and first and second green-sensitive silver halide emulsion layers of different sensitivity, wherein the layer of higher sensitivity includes a two-equivalent magenta dye-forming coupler selected from the group consisting of a pyrazolone coupler having a structure according to formula I and a pyrazoloazole coupler having a structure according to formula II as set forth in the disclosure, and the layer of lower sensitivity includes a two-equivalent magenta dye-forming coupler selected from the group consisting of couplers defined by formulas I and II. The activity of the magenta dye-forming coupler present in the layer of lower sensitivity is less than the activity of the coupler present in the layer of higher sensitivity. The layers of higher and lower sensitivity do not comprise magenta couplers which are defined by the same formula.Type: GrantFiled: June 24, 1993Date of Patent: February 14, 1995Assignee: Eastman Kodak CompanyInventors: Hans G. Ling, Drake M. Michno, Stephen Singer
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Patent number: 5387500Abstract: A photographic element including a support and at least two green-sensitive silver halide emulsion layers of different sensitivity, each emulsion layer including a two-equivalent pyrazoloazole magenta dye-forming coupler having a structure according to formula I of the disclosure. The activity of the dye-forming coupler present in the layer of lower sensitivity is less than the activity of the dye-forming coupler present in the layer of higher sensitivity.Type: GrantFiled: May 27, 1994Date of Patent: February 7, 1995Assignee: Eastman Kodak CompanyInventors: Hans G. Ling, Drake M. Michno
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Patent number: 5288593Abstract: A photographic element comprises a support bearing at least one photographic silver halide emulsion layer and at least one coupler (A) having a water solubilizing group wherein coupler (A) forms a compound that is washed out of the photographic element during photographic processing and forms a coupling-off group represented by the formula:--X--Rel.sup.2 --T.sup.2 --INHwherein;X is selected from oxygen, nitrogen or sulfur;X--Rel.sup.2 contains a photographic ballast and is a releasing group for releasing T.sup.2 --INH from X--Rel.sup.2 by elimination electron transfer reaction during photographic processing without substantial delay of releasing;T.sup.2 is a timing group that releases INH by elimination electron transfer reaction with timing delay during photographic processing;INH is a development inhibitor group.The photographic coupler (A) enables formation of easily removable dyes in photographic elements and processes that provide images having improved acutance, stability and interimage effects.Type: GrantFiled: June 24, 1992Date of Patent: February 22, 1994Assignee: Eastman Kodak CompanyInventors: William J. Begley, Drake M. Michno, Hans G. Ling, Teh H. Chen
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Patent number: 5286613Abstract: A color photographic element comprising a support bearing at least one photographic silver halide emulsion layer and a combination of at least two couplers (A) and (B), coupler (A) capable upon reaction with oxidized developer of forming a compound that is washed out of the photographic element during photographic processing and capable of releasing a photographic development inhibitor or a timing group having a photographic development inhibitor, the timing group capable of providing timed release of said photographic development inhibitor and coupler (B) capable upon reaction with oxidized developer of forming a compound that is not washed out of the photographic element during photographic processing and capable of releasing a photographic development inhibitor with or without time delay. Such a color photographic material enables formation of improved color images.Type: GrantFiled: June 24, 1992Date of Patent: February 15, 1994Assignee: Eastman Kodak CompanyInventors: William J. Begley, Hans G. Ling, Drake M. Michno
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Patent number: 5279929Abstract: A photographic element comprises a support bearing at least one photographic silver halide emulsion layer and at least one coupler (A) having a water solubilizing group wherein coupler (A) forms a compound that is washed out of the photographic element during photographic processing and forms a coupling-off group represented by the formula:--X--Rel.sup.3 --T.sup.3 --INHwherein;X is selected from oxygen, nitrogen or sulfurX--Rel.sup.3 contains a photographic ballast and is a releasing group for releasing T.sup.3 --INH from X--Rel.sup.3 by intramolecular displacement reaction during photographic processing without substantial delay of releasing;T.sup.3 is a timing group that releases INH by intramolecular displacement reaction with timing delay during photographic processing;INH is a development inhibitor group;The photographic coupler (A) enables formation of easily removable dyes in photographic elements and processes that provide images having improved acutance, stability and interimage effects.Type: GrantFiled: June 24, 1992Date of Patent: January 18, 1994Assignee: Eastman Kodak CompanyInventors: William J. Begley, Drake M. Michno, Hans G. Ling, Teh H. Chen
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Patent number: 5093239Abstract: Compounds and reagents containing the compounds are disclosed for detecting oxidase positive organisms. The compounds have the structureCOUP--LINK).sub.n RwhereinCOUP-- represents a radical that couples with an oxidized primary aromatic amine and releases --LINK--R;--LINK-- represents a divalent radical that undergoes intramolecular cyclization and release of --R upon release by COUP--;n represents zero or one;--R represents a monovalent radical that forms a detectable species in the form of a colorimetric dye or fluorescent compound upon release from --LINK--; wherein --R is selected from the group consisting of: ##STR1## wherein W represents hydrogen; halogen; hydroxy; substituted or unsubstituted carbonamido; sulfonamido; sulfonyl; ureido or amino;R.sup.1 and R.sup.2 each independently represent hydrogen, halogen, alkyl, alkoxy, carboxy, sulfo, cyano, nitro, carboxylic acid ester, carbonyl, sulfonyl, carbonamido, sulfonamido, alkylsulfonyl, arylsulfonyl; andR.sup.3 and R.sup.Type: GrantFiled: May 2, 1988Date of Patent: March 3, 1992Assignee: Eastman Kodak CompanyInventors: Robert T. Belly, Lee J. Fleckenstein, Drake M. Michno, William N. Washburn