Abstract: An article, such as a polymeric film, sachet, purge control pad, or label, includes a sulfur scavenger. In some embodiments, an oxygen scavenger is also included. A method includes providing an article, including a sulfur scavenger and an oxygen scavenger; and subjecting the article to a dosage of actinic radiation effective to trigger the oxygen scavenger. A method of reducing the sulfur content of a package containing a food product includes either (1) providing a film including a layer including a zinc ionomer, and a layer including an oxygen scavenger; packaging the food product in the film; and storing the package for at least 24 hours; or (2) providing the food product at a temperature of ?40° F.; providing a film including a layer including a sulfur scavenger; packaging the food product in the film; and storing the package for at least 24 hours.

Abstract: A method comprises subjecting ant oxygen scavenger to actinic radiation; and then optionally storing the oxygen scavenger in a container, the container configured such that the oxygen scavenger exhibits no substantial oxygen scavenging activity while inside the container. The dosed oxygen scavenger can later be removed from the container, if stored therein, subjected to a second dose of actinic radiation to trigger the oxygen scavenger, and used in packaging oxygen sensitive products. A stored oxygen scavenger, untriggered, is also disclosed.

Abstract: A package includes a thermoformed web or support member, an optical data storage medium disposed in a cavity of the thermoformed web, or on the support member; and a covering web disposed on the optical data storage medium, and on the thermoformed web or support member, and in sealing relationship to the thermoformed web or support member; where each of the thermoformed web or support member, and the covering web, includes an oxygen barrier; and where at least one of the thermoformed web or support member, and the covering web, includes an oxygen scavenger. Methods of making the package are also disclosed. In addition to, or alternatively to including the oxygen scavenger in at least one of the thermoformed or support member, and the covering web, the oxygen scavenger can be disposed on the optical medium, e.g. in the form of a disc, coating, label, pellet, wafer, or flattened sachet.

Abstract: An oxygen scavenger composition includes an organic oxygen scavenger, a transition metal catalyst, and a blend of at least two photoinitiators selected from 1,3,5-tris(4-benzoylphenyl)benzene, thioxanthone derivative, acyl phenylphosphineoxide derivative, and diphenyl sulfide derivative. A film includes at least one layer including an organic oxygen scavenger, a transition metal catalyst, and a blend of at least two photoinitiators selected from 1,3,5-tris(4-benzoylphenyl)benzene, thioxanthone derivative, acyl phenylphosphineoxide derivative, and diphenyl sulfide derivative.

Abstract: A method includes triggering an oxygen scavenger; and storing the scavenger in a container configured such that the oxygen scavenger exhibits no substantial oxygen scavenging activity while inside the container. The triggered oxygen scavenger can later be removed from the container, and used in packaging oxygen sensitive products. A stored oxygen scavenger, triggered, is also disclosed. A method of distributing an oxygen scavenger film includes providing a tubular film at a first location, the film having oxygen barrier and oxygen scavenger layers; triggering the oxygen scavenger; collapsing the film; rolling up the film; transporting the film to a second location; and triggering the oxygen scavenger. Another method of distributing an oxygen scavenger film includes providing an oxygen scavenger film at a first location; transporting the film to a second location; triggering the oxygen scavenger; storing the oxygen scavenger film in a container; and transporting the film to a third location.

Abstract: A method for triggering an oxygen scavenging composition for use in packaging an oxygen sensitive article includes the steps of providing an oxygen scavenging composition comprising an oxidizable organic compound and, optionally, a transition metal catalyst, and exposing the composition to a source of pulsed light wherein each pulse has a duration of between 1 microsecond and 1 millisecond, a frequency of between 0.1 to 100 Hertz, and a total intensity of at least 350 mW/cm2 so that each pulse provides the composition with a dose of UV light of at least 0.1 J/cm2 so as to provide a triggered composition. The triggered composition can be applied to an article so as to provide an oxygen scavenging package. An apparatus and packaging system are also disclosed.

Abstract: An article of manufacture includes an oxygen scavenger and poly(lactic acid). The article can be in the form of a film, coating, gasket, liner, insert, sealant, or fibrous matte. A film includes at least one layer including an oxygen scavenger, and at least one layer including poly(lactic acid). A package can be made from the film for enclosing an oxygen-sensitive artice such as food. The poly(lactic acid) blocks the migration of odor causing byproducts of the oxygen scavenging process. A method includes providing a film including at least one layer including an oxygen scavenger; and at least one layer including the poly(lactic acid); and exposing the film to actinic radiation. A method for reducing migration of organoleptically significant compounds is also disclosed.

Abstract: A method includes providing an article including an oxygen scavenger; forming the article into a container; placing an oxygen sensitive product into the container; and exposing the container to actinic radiation at a dosage effective to sterilize the container, and trigger the oxygen scavenger in the article. Alternative methods are also disclosed. A package includes a container, the container including an activated oxygen scavenger; wherein the container is sterilized; and wherein an oxygen sensitive product is disposed in the container.

Abstract: A multilayer film includes a first and second outer layer each including a polymer; and an internal layer including an oxygen scavenger; wherein at least one of the first and second outer layers includes a blend of a polymer, a siloxane having a viscosity of from 1×107 centistokes to 5×107 centistokes, and an antiblock agent. A laminate is also disclosed, including a multilayer film having an oxygen scavenger layer, and a layer including a blend of a polymer, a siloxane having a viscosity of from 1×107 centistokes to 5×107 centistokes, and an antiblock agent.

Abstract: The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in a rigid container, especially a bottle, a tray, a carton, a lidstock associated with a tray, a stand up pouch, or a paperboard container. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of bottled products, and modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package.

Abstract: A method comprises subjecting ant oxygen scavenger to actinic radiation; and then optionally storing the oxygen scavenger in a container, the container configured such that the oxygen scavenger exhibits no substantial oxygen scavenging activity while inside the container. The dosed oxygen scavenger can later be removed from the container, if stored therein, subjected to a second dose of actinic radiation to trigger the oxygen scavenger, and used in packaging oxygen sensitive products. A stored oxygen scavenger, untriggered, is also disclosed.

Abstract: The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in solids, particularly polymeric materials present in multi-layered packaging materials. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package. Novel articles, methods, and packages are also disclosed.

Abstract: A method includes triggering an oxygen scavenger; and storing the scavenger in a container configured such that the oxygen scavenger exhibits no substantial oxygen scavenging activity while inside the container. The triggered oxygen scavenger can later be removed from the container, and used in packaging oxygen sensitive products. A stored oxygen scavenger, triggered, is also disclosed. A method of distributing an oxygen scavenger film includes providing a tubular film at a first location, the film having oxygen barrier and oxygen scavenger layers; triggering the oxygen scavenger; collapsing the film; rolling up the film; transporting the film to a second location; and triggering the oxygen scavenger. Another method of distributing an oxygen scavenger film includes providing an oxygen scavenger film at a first location; transporting the film to a second location; triggering the oxygen scavenger; storing the oxygen scavenger film in a container; and transporting the film to a third location.

Abstract: An article of manufacture includes an oxygen scavenger and an amorphous silica. The article can be in the form of e.g. a film or sealing compound. A package can be made from the article for containing an oxygen-sensitive article such as food. The amorphous silica reduces migration of odor causing by-products of the oxygen scavenging process. A method of making an article of manufacture having reduced migration of by-products of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and an amorphous silica; and exposing the article to actinic radiation.

Abstract: Novel articles and packages are disclosed. Disclosed is the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in solids, particularly polymeric materials present in multi-layered packaging materials. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of modified atmosphere and vacuum packages. A solid article includes a film including an oxygen barrier layer; and a layer including an oxygen scavenger; and a patch including an oxygen barrier; and an oxygen indicator including a luminescent compound; wherein the patch is adhered to the film; and wherein the oxygen indicator is disposed between the oxygen barrier of the patch, and the oxygen barrier of the film. A package, and a bottle, each having the oxygen indicator, are also disclosed.

Abstract: An article of manufacture includes an oxygen scavenger and an amorphous silica. The article can be in the form of e.g. a film or sealing compound. A package can be made from the article for containing an oxygen-sensitive article such as food. The amorphous silica reduces migration of odor causing by-products of the oxygen scavenging process. A method of making an article of manufacture having reduced migration of by-products of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and an amorphous silica; and exposing the article to actinic radiation.

Abstract: A package includes a thermoformed web or support member, an optical data storage medium disposed in a cavity of the thermoformed web, or on the support member; and a covering web disposed on the optical data storage medium, and on the thermoformed web or support member, and in sealing relationship to the thermoformed web or support member; where each of the thermoformed web or support member, and the covering web, includes an oxygen barrier; and where at least one of the thermoformed web or support member, and the covering web, includes an oxygen scavenger. Methods of making the package are also disclosed. In addition to, or alternatively to including the oxygen scavenger in at least one of the thermoformed or support member, and the covering web, the oxygen scavenger can be disposed on the optical medium, e.g. in the form of a disc, coating, label, pellet, wafer, or flattened sachet.

Abstract: A system for triggering an oxygen scavenging film includes the means for emitting UV-C light, means associated with said light defining a film path, means for feeding an oxygen scavenging film into the system to trigger the oxygen scavenging film, means for feeding the triggered film to packaging means. The film may comprise an oxidizable organic compound and a transition metal catalyst.

Abstract: A system for triggering an oxygen scavenging film includes the means for emitting UV-C light, means associated with said light defining a film path, means for feeding an oxygen scavenging film into the system to trigger the oxygen scavenging film. The film may comprise an oxidizable organic compound and a transition metal catalyst.

Abstract: The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in solids, particularly polymeric materials present in multi-layered packaging materials. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package. Novel articles, methods, and packages are also disclosed.