Patents by Inventor Druce K. Crump

Druce K. Crump has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5488130
    Abstract: A novel intermediate useful in the synthesis of 2-hydroxypropyl iminodiacetic acid is disclosed. The intermediate can be formed by contacting 2-hydroxypropyl amine with glycolonitrile to form an aminonitrile which can be hydrolyzed and contacted with additional glycolonitrile to form the nitrile intermediate which can be converted to 2-hydroxylpropyl iminodiacetic acid via hydrolysis.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: January 30, 1996
    Assignee: The Dow Chemical Company
    Inventors: Phillip S. Athey, Druce K. Crump, David A. Wilson
  • Patent number: 5481018
    Abstract: A novel intermediate useful in the synthesis of alpha-alanine diacetic acid or its salts is disclosed. The intermediate can be formed by contacting alanine with glycolonitrile under alkaline conditions or glycine with lactonitrile to form an aminonitrile which can be hydrolyzed and then contacted with additional glycolonitrile to form the nitrile intermediate which can be converted to alpha-alanine diacetic acid via hydrolysis.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: January 2, 1996
    Assignee: The Dow Chemical Company
    Inventors: Phillip S. Athey, David A. Wilson, Druce K. Crump
  • Patent number: 5447575
    Abstract: New compounds are represented by Formula I: ##STR1## and salts and complexes thereof; wherein R is an alkyl group having at least one --SO.sub.3 H and at least one --OH; each R' is independently selected from hydrogen, an unsubstituted or inertly substituted alkyl group, an alkyl group substituted with a carbonyl group, with a carboxylic acid, salt or complexed carboxyl group, or an alkoxy group; R" is hydroxyalkyl and x+y+z=3 and are good chelants. The compounds are also biodegradable and are particularly useful in hard surface cleaners.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: September 5, 1995
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 5389594
    Abstract: New compounds are represented by Formula I: ##STR1## and salts and complexes thereof; wherein R is an alkyl group having at least one --SO.sub.3 H and at least one --OH; each R' is independently selected from hydrogen, an unsubstituted or inertly substituted alkyl group, an alkyl group substituted with a carbonyl group, with a carboxylic acid, salt or complexed carboxyl group, or an alkoxy group; R" is hydroxyalkyl and x+y+z=3 and are good chelants. The compounds are also biodegradable and are particularly useful in washing compositions, preferably containing detergents and in gas conditioning.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: February 14, 1995
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 5258141
    Abstract: New compounds are represented by Formula I: ##STR1## and salts and complexes thereof; wherein R is an alkyl group having at least one --SO.sub.3 H and at least one --OH; each R' is independently selected from hydrogen, an unsubstituted or inertly substituted alkyl group, an alkyl group substituted with a carbonyl group, with a carboxylic acid, salt or complexed carboxyl group, or an alkoxy group; R" is hydroxyalkyl and x+y+z=3 and are good chelants. The compounds are also biodegradable and are particularly useful in washing compositions, preferably containing detergents and in gas conditioning.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: November 2, 1993
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 5208369
    Abstract: New compounds are represented by Formula I: ##STR1## and salts and complexes thereof; wherein R is an alkyl group having at least one --SO.sub.3 H and at least one --OH; each R' is independently selected from hydrogen, an unsubstituted or inertly substituted alkyl group, an alkyl group substituted with a carbonyl group, with a carboxylic acid, salt or complexed carboxyl group, or an alkoxy group; R" is hydroxyalkyl and x+y+z=3 and are good chelants. The compounds are also biodegradable and are particularly useful in washing compositions, preferably containing detergents and in gas conditioning.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: May 4, 1993
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 5208363
    Abstract: The present invention is a process for preparing aminoacetonitriles or ethylenediamine tetraacetonitrile comprising the steps of (a) admixing glycolonitrile with an amine having at least one primary amine group or ethylenediamine to form an intermediate amine acetonitrile reaction product, (b) admixing the reaction product of Step (a) with formaldehyde and hydrocyanic acid such that each hydrogen on an amine nitrogen is replaced by an acetonitrile group. The resulting aminoacetonitrile advantageously has all amino groups fully substituted with acetonitrile groups.
    Type: Grant
    Filed: May 5, 1992
    Date of Patent: May 4, 1993
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 5098681
    Abstract: Sulfur dioxide is removed from a fluid containing SO.sub.2 by employing as an absorbent therefor an aqueous solution of compounds represented by Formulas I and II: ##STR1## wherein each R.sup.1 or R.sup.2 is independently hydrogen; an alkyl group; a hydroxyalkyl group; an aldehyde group; a carboxylic acid or salt group; an alkyl group containing at least one carboxylic ester, carboxylic acid or salt, ether, aldehyde, ketone or sulfoxide; and wherein at least one R.sup.1 or R.sup.2 is a carbonyl-containing group, such as an aldehyde group, a carboxylic acid containing group, a carboxyl ester group, or a ketone-containing group; ##STR2## wherein each R.sup.3 is independently hydrogen; an alkyl group; a hydroxyalkyl group; an aldehyde group; a carboxylic acid or salt group; or an alkyl, aryl, or aralkyl group containing at least one carboxylic ester, a carboxylic acid or salt, ether, aldehyde, ketones or sulfoxide group. The absorbent solution preferably can be thermally regenerated by heating to remove SO.sub.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: March 24, 1992
    Assignee: The Dow Chemical Company
    Inventors: Steven H. Christiansen, Dane Chang, Druce K. Crump
  • Patent number: 4895600
    Abstract: Asphalt compositions are improved by incorporating therein the reaction produce of (a) a phosphorus-containing compound, (b) an amine or polyamine and (c) a carbonyl-containing compound as an anti-stripping agent. These asphalt compositions are useful as a pavement material by blending with an aggregate.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: January 23, 1990
    Assignee: The Dow Chemical Company
    Inventors: Dane Chang, Druce K. Crump
  • Patent number: 4872996
    Abstract: A process for inhibiting the deposition of manganese in water systems by adding to the water a sufficient amount of an organic aminophosphonic acid to inhibit corrosion and scale resulting from undesirable manganese deposition.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: October 10, 1989
    Assignee: The Dow Chemical Company
    Inventors: Jeffrey G. Grierson, David A. Wilson, Druce K. Crump
  • Patent number: 4799995
    Abstract: Inhibition of calcium scale under the extreme temperature conditions found in pulp digesters has been accomplished by employing certain mixtures of polaminopoly(alkylenephosphonic acids) together with nonionic surfactants. Diethylenetriaminepenta(methylenephosphonic acid) together with a polyethoxynonylphenol has been found especially effective for the purpose.
    Type: Grant
    Filed: July 29, 1987
    Date of Patent: January 24, 1989
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, Lance A. Cooper, Thomas M. Hopkins
  • Patent number: 4786329
    Abstract: Asphalt compositions are improved by incorporating therein the reaction product of (a) a phosphorus-containing compound, (b) an amine or polyamine and (c) a carbonyl-containing compound as an anti-stripping agent. These asphalt compositions are useful as a pavement material by blending with an aggregate.
    Type: Grant
    Filed: September 9, 1987
    Date of Patent: November 22, 1988
    Assignee: The Dow Chemical Company
    Inventors: Dane Chang, Druce K. Crump
  • Patent number: 4770791
    Abstract: It has now been found that certain phosphonate derivatives of bis(aminoalkyl) piperazines are good threshold agents to prevent metal ion precipitation in aqueous solutions. They also function as sequestering and/or chelating agents as do those which do not contain the phosphonate group.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: September 13, 1988
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, Jaime Simon, David A. Wilson
  • Patent number: 4758635
    Abstract: New derivatives of polyamidoamines which contain at least one phosphonic, alkylphosphonic, hydroxyalkyl, carboxyalkly, alkylsulfonic or salts of the acid groups as substituents on a nitrogen are useful as chelating and/or threshold agents for preventing precipitation of metal ions. The preferred agents contain phosphonic acid groups or their salts.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: July 19, 1988
    Assignee: The Dow Chemical Company
    Inventors: David A. Wilson, Druce K. Crump, Jaime Simon
  • Patent number: 4680396
    Abstract: It has now been found that certain phosphonate derivatives of bis(aminoalkyl) piperazines are good threshold agents to prevent metal ion precipitation in aqueous solutions. They also function as sequestering and/or chelating agents as do those which do not contain the phosphonate group.
    Type: Grant
    Filed: February 24, 1984
    Date of Patent: July 14, 1987
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, Jaime Simon, David A. Wilson
  • Patent number: 4568469
    Abstract: Certain methylene phosphonic acid derivatives of aminohydrocarbyl piperazine-urea adducts are good threshold agents to prevent metal ion precipitation in aqueous solutions.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: February 4, 1986
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 4568468
    Abstract: A process of preventing precipitation of scale producing metal ions, e.g. calcium, from their aqueous solutions by adding an effective amount of a methylenephosphonic acid derivative of bis(methylamine)-norbornane. These compounds are effective in threshold amounts.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: February 4, 1986
    Assignee: The Dow Chemical Company
    Inventors: Jaime Simon, Druce K. Crump, David A. Wilson
  • Patent number: 4560548
    Abstract: Radionuclide complexes of phosphonate derivatives of bis(aminoalkyl)piperazine have been found which are useful for imaging and/or treating therapeutically the skeletal system to detect and treat bone tumors. These complexes clear readily through the kidneys and the ratio of uptake in bone to that in surrounding soft tissue is high.
    Type: Grant
    Filed: April 10, 1984
    Date of Patent: December 24, 1985
    Assignee: The Dow Chemical Company
    Inventors: Jaime Simon, David A. Wilson, Wynn A. Volkert, Druce K. Crump
  • Patent number: 4540508
    Abstract: Compositions comprising methylene phosphonic acid derivatives of piperazine or aminoethylpiperazine (AEP) in combination with certain phosphonic acid derivatives of aliphatic acids or, methylene phosphonic acid derivatives of ammonia, amines and polyamines. These provide a synergistic effect with respect to the threshold activity in preventing metal ion precipitation.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: September 10, 1985
    Assignee: The Dow Chemical Company
    Inventors: David A. Wilson, Druce K. Crump
  • Patent number: 4518777
    Abstract: Certain methylene phosphonic acid derivatives of aminohydrocarbyl piperazine-urea adducts are good threshold agents to prevent metal ion precipitation in aqueous solutions.
    Type: Grant
    Filed: September 2, 1983
    Date of Patent: May 21, 1985
    Assignee: The Dow Chemical Company
    Inventors: Druce K. Crump, David A. Wilson