Patents by Inventor Dwyann Dalrymple
Dwyann Dalrymple has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10253609Abstract: Methods for acid diversion in a hydrocarbon-containing subterranean formation are disclosed. The methods include injecting an acid diversion agent comprising a water-soluble or dispersible branched polyhydroxyetheramine and injecting an acidic solution into a well which is in contact with the hydrocarbon-containing subterranean formation. Preferably, the acid solution is diverted toward a zone of the formation that has a lower permeability to fluid than an adjacent zone. This process improves the permeability of the hydrocarbon-containing subterranean formation to hydrocarbons, while decreasing the permeability of the formation to water or brine.Type: GrantFiled: April 29, 2014Date of Patent: April 9, 2019Assignee: Ecolab USA Inc.Inventors: Kin-Tai Chang, Eldon Dwyann Dalrymple
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Patent number: 9284478Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: GrantFiled: March 3, 2010Date of Patent: March 15, 2016Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20150307769Abstract: Methods for acid diversion in a hydrocarbon-containing subterranean formation are disclosed. The methods include injecting an acid diversion agent comprising a water-soluble or dispersible branched polyhydroxyetheramine and injecting an acidic solution into a well which is in contact with the hydrocarbon-containing subterranean formation. Preferably, the acid solution is diverted toward a zone of the formation that has a lower permeability to fluid than an adjacent zone. This process improves the permeability of the hydrocarbon-containing subterranean formation to hydrocarbons, while decreasing the permeability of the formation to water or brine.Type: ApplicationFiled: April 29, 2014Publication date: October 29, 2015Applicant: Ecolab USA Inc.Inventors: Kin-Tai Chang, Eldon Dwyann Dalrymple
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Patent number: 9127193Abstract: A treatment fluid for a well including: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to an embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming the treatment fluid; and (d) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.Type: GrantFiled: October 31, 2012Date of Patent: September 8, 2015Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20140116691Abstract: Methods for reducing fines migration in a porous subterranean reservoir are disclosed. In certain aspects, the methods include introducing a composition comprising a water-soluble or dispersible branched polyhydroxyetheramine into the porous subterranean reservoir, maintaining a sufficient temperature in the porous subterranean reservoir for a period of time, adsorbing the composition onto a surface of the porous subterranean reservoir, and stabilizing at least a portion of the fines present in the porous subterranean reservoir. Methods for enhancing an effective permeability of a porous subterranean reservoir are also disclosed. In connection with the disclosed methods, a treatment composition can be used and in certain aspects, the treatment composition can be a reaction product of bisphenol A, an ethanol amine, diethanol amine, and a monofunctionalized polyoxyalkyleneamine.Type: ApplicationFiled: October 30, 2012Publication date: May 1, 2014Inventors: Eldon Dwyann Dalrymple, Kin-Tai Chang
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Patent number: 8522874Abstract: A treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a weak organic acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: GrantFiled: March 3, 2010Date of Patent: September 3, 2013Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20130056199Abstract: A treatment fluid for a well including: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to an embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming the treatment fluid; and (d) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.Type: ApplicationFiled: October 31, 2012Publication date: March 7, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Patent number: 8322421Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: GrantFiled: March 3, 2010Date of Patent: December 4, 2012Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20120279708Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: ApplicationFiled: March 3, 2010Publication date: November 8, 2012Applicant: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Edtuardo Vasquez, Eldon Dwyann Dalrymple
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Patent number: 8273690Abstract: Crosslinkable-polymer compositions that comprise a chitosan-based compound and a phenol source, and associated methods, are provided. Various methods of use are also provided. In one embodiment, the methods comprise providing a crosslinkable-polymer composition comprising an aqueous fluid, a chitosan-based compound, a chitosan-reacting polymer, and a phenol source; introducing the crosslinkable-polymer composition into the portion of the subterranean formation; and allowing the crosslinkable-polymer composition to form a crosslinked gel in the portion of the subterranean formation.Type: GrantFiled: November 3, 2006Date of Patent: September 25, 2012Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Julio E. Vasquez, Larry S. Eoff, Eldon Dwyann Dalrymple
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Publication number: 20110214866Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: ApplicationFiled: March 3, 2010Publication date: September 8, 2011Applicant: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Edtuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20110214865Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a weak organic acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: ApplicationFiled: March 3, 2010Publication date: September 8, 2011Applicant: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Edtuardo Vasquez, Eldon Dwyann Dalrymple
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Publication number: 20110214867Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: ApplicationFiled: March 3, 2010Publication date: September 8, 2011Applicant: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Patent number: 7866394Abstract: Methods of cementing in subterranean formations, cement compositions, and methods for making the compositions are provided. A cement slurry is passed into a subterranean formation, and a swelling agent is passed into the subterranean formation to reduce an amount of water flowing into the cement slurry. The swelling agent may be combined with a carrier fluid before being displaced into the subterranean formation. Alternatively, the swelling agent may be pre-mixed with the cement slurry to form a new cement composition, followed by displacing the cement composition into the subterranean formation. The swelling agent is present in an amount effective to, upon absorption of water and swelling to form a gel mass, substantially block the flow path of the water into the cement composition or reduce losses to low pore pressure intervals, thereby preventing the integrity of the cement composition from being compromised or lost to voidage, fractures, fissures, etc.Type: GrantFiled: February 27, 2003Date of Patent: January 11, 2011Assignee: Halliburton Energy Services Inc.Inventors: Prentice G. Creel, Charles L. Boatman, Richard H. Tate, Eldon Dwyann Dalrymple, Stephen P. Luscombe, John L. Eubank
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Patent number: 7563750Abstract: An exemplary method of the present invention for performing an injection operation includes providing a water-soluble relative permeability modifier, introducing the water-soluble relative permeability modifier into a subterranean formation; and injecting an aqueous injection fluid into the subterranean formation after introducing the water-soluble relative permeability modifier. An exemplary permeability-modifying injection fluid of the present invention contains water-soluble relative permeability modifier. The water-soluble relative permeability modifiers of the present invention include hydrophobically modified water-soluble polymers, hydrophilically modified water-soluble polymers, and water-soluble polymers without hydrophobic or hydrophilic modification.Type: GrantFiled: January 24, 2004Date of Patent: July 21, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Eldon Dwyann Dalrymple, B. Raghava Reddy
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Patent number: 7325613Abstract: Crosslinkable-polymer compositions that comprise a chitosan-based compound and a phenol source, and associated methods, are provided. Various methods of use are also provided. In one embodiment, the methods comprise providing a crosslinkable-polymer composition comprising an aqueous fluid, a chitosan-based compound, a chitosan-reacting polymer, and a phenol source; introducing the crosslinkable-polymer composition into the portion of the subterranean formation; and allowing the crosslinkable-polymer composition to form a crosslinked gel in the portion of the subterranean formation.Type: GrantFiled: November 3, 2006Date of Patent: February 5, 2008Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Julio E. Vasquez, Larry S. Eoff, Eldon Dwyann Dalrymple
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Patent number: 7220708Abstract: A method and composition is provided for a relative permeability modifying polymer for use with drilling fluids that comprises a water soluble polymer formed from a hydrophobic or hydrophobically modified hydrophilic monomer and a hydrophilic monomer. In an alternative embodiment, a method is provided for producing a water soluble polymer formed from a hydrophilic monomer for use as a relative permeability modifying polymer.Type: GrantFiled: February 27, 2003Date of Patent: May 22, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Frank Zamora, Larry S. Eoff, Eldon Dwyann Dalrymple, B. Raghava Reddy
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Patent number: 6981552Abstract: The present invention provides a well treatment fluid containing water, a amine-based polymer, and an oxidized polysaccharide-based polymer. The oxidized polysaccharide-based polymer is able to crosslink with the amine-based polymer and produce a gel having a viscosity of greater than about 20 cp, measured at a pH of about 4 to about 7 and at STP. The present invention also provides a method of treating a subterranean formation penetrated by a wellbore comprising the steps of: (a) forming the well treatment fluid, and (b) contacting the subterranean formation with the fluid.Type: GrantFiled: March 21, 2003Date of Patent: January 3, 2006Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Eldon Dwyann Dalrymple
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Patent number: 6889766Abstract: A method for recovering oil from a reservoir is provided. This method comprises passing a swelling agent into a permeable zone of the reservoir that allows fluid to flow between an injection well and a producing well. An aqueous solution is passed into the reservoir to contact the swelling agent, thereby causing the swelling agent to swell and substantially block the permeable zone. One or more injectants are passed into the reservoir to remove oil therefrom. The swelling agent inhibits the injectants from passing through the permeable zone, ensuring that the injectants pass through the areas of the reservoir containing oil.Type: GrantFiled: February 27, 2003Date of Patent: May 10, 2005Assignee: Halliburton Energy Services, Inc.Inventors: Prentice G. Creel, Charles L. Boatman, Sam W. McDonald, Richard H. Tate, Eldon Dwyann Dalrymple
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Publication number: 20040182575Abstract: The present invention provides a well treatment fluid containing water, a amine-based polymer, and an oxidized polysaccharide-based polymer. The oxidized polysaccharide-based polymer is able to crosslink with the amine-based polymer and produce a gel having a viscosity of greater than about 20 cp, measured at a pH of about 4 to about 7 and at STP. The present invention also provides a method of treating a subterranean formation penetrated by a wellbore comprising the steps of: (a) forming the well treatment fluid, and (b) contacting the subterranean formation with the fluid.Type: ApplicationFiled: March 21, 2003Publication date: September 23, 2004Inventors: B. Raghava Reddy, Larry S. Eoff, Eldon Dwyann Dalrymple