Abstract: A method of dimethyl carbonate production includes reacting CO2 and methanol in the presence of a heteroatom-modified cerium oxide catalyst to form dimethyl carbonate. The heteroatom-modified cerium oxide catalyst includes an element selected from the group consisting of N, S and combinations thereof, in an amount ranging from 0.05 to 2 wt. % based on the total weight of the heteroatom-modified cerium oxide catalyst. The heteroatom-modified cerium oxide catalyst is in the form of nanorods with an average diameter in a range from 1 to 50 nm and an average length in a range from 10 to 700 nm. The dimethyl carbonate yield is greater than or equal to 40 mmol·gcatalyst?1.

Abstract: A catalyst system is disclosed. The catalyst system may include a pre-catalyst and a co-catalyst. The pre-catalyst includes one or more chromium compounds coordinated with a ligand. The co-catalyst includes one or more organoaluminum compounds, wherein: the ligand has a structure according to formula (I): In formula (I), R1, R2, R3, and R4 are independently chosen from (C6-C60) aryl, optionally substituted with one or more RS, wherein RS is a (C1-C50) hydrocarbyl or a (C1-C50) heterohydrocarbyl. In formula (I), R5 is a (C9-C60) aryl or a (C4-C60) heteroaryl, optionally substituted with one or more RS, wherein RS is a (C1-C50) hydrocarbyl or a (C1-C50) heterohydrocarbyl, provided that R5 is not naphthyl or triptycenyl.

Abstract: A catalyst system is disclosed. The catalyst system may include a pre-catalyst and a co-catalyst. The pre-catalyst includes one or more chromium compounds coordinated with a ligand. The co-catalyst includes one or more organoaluminum compounds, wherein: the ligand has a structure according to formula (I): In formula (I), R1, R2, R3, and R4 are independently chosen from (C6-C60) aryl, optionally substituted with one or more RS, wherein RS is a (C1-C50) hydrocarbyl or a (C1-C50) heterohydrocarbyl. In formula (I), R5 is a (C9-C60) aryl or a (C4-C60) heteroaryl, optionally substituted with one or more RS, wherein RS is a (C1-C50) hydrocarbyl or a (C1-C50) heterohydrocarbyl, provided that R5 is not naphthyl or triptycenyl.

Abstract: Catalyst systems for tetramerizing ethylene to form 1-octene may include a catalyst which may include a chromium compound coordinated with a ligand and a co-catalyst which may include an organoaluminum compound. The ligand may have a chemical structure according to Chemical Structure (I), wherein R5, R6, and R7 are each independently chosen from a (C1-C50) hydrocarbyl group or a (C1-C50) heterohydrocarbyl group, and wherein the (C1-C50) hydrocarbyl or (C1-C50) heterohydrocarbyl groups of R5, R6, and R7 have greater than 10 carbon atoms combined and RA, RB, RC, and RD and R1, R2, R3, and R4, are independently chosen from a hydrogen atom or a (C1-C50) hydrocarbyl group.

Abstract: Catalyst systems suitable for tetramerizing ethylene to form 1-octene may include a catalyst comprising a chromium compound coordinated with a ligand and a co-catalyst comprising an organoaluminum compound. The ligand may include have a chemical structure according to formula (I), wherein at least one of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 have the structure according to formula (II) wherein RA, RB, RC, and RD and the remainder of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 are independently chosen from a hydrogen or a (C1-C50) hydrocarbyl group.

Abstract: Catalyst systems suitable for tetramerizing ethylene to form 1-octene may include a catalyst including a chromium compound coordinated with a ligand and a co-catalyst including an organoaluminum compound. The ligand may have a chemical structure: (R1)(R2)A-X—C(R3)(R4). A and C may be phosphorus. X may be B(R5), Si(R5)2, N(R5), wherein R5 is an aryl group substituted with a halogen, halogenated alkyl or a silyl group, and wherein B, or N, or Si is bound to A and C. R1, R2, R3, and R4 may be independently chosen hydrocarbyl groups or heterohydrocarbyl groups.