Patents by Inventor Eduard Troxler

Eduard Troxler has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5401845
    Abstract: Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: March 11, 1994
    Date of Patent: March 28, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Rita Pitteloud, Peter Hofmann, Rudolf Maul, Volker Schenk, Eduard Troxler, Horst Zinke
  • Patent number: 5322871
    Abstract: Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: April 20, 1993
    Date of Patent: June 21, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rita Pitteloud, Peter Hofmann, Rudolf Maul, Volker Schenk, Eduard Troxler, Horst Zinke
  • Patent number: 4863982
    Abstract: Compounds of the formula I ##STR1## R.sup.4 is C.sub.5 -C.sub.7 -cycloalkyl which can be substituted by C.sub.1 -C.sub.4 -alkyl, and R.sup.5 to R.sup.9 are independently of one another C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.5 -C.sub.7 -cycloalkyl, phenyl, benzyl or allyl, are suitable for stabilizing organic material against thermal, oxidative and/or actinic degradation.
    Type: Grant
    Filed: July 6, 1988
    Date of Patent: September 5, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Werner Stegmann, Eduard Troxler, Peter Hofmann, Hans-Rudolf Meier, Paul Dubs
  • Patent number: 4536593
    Abstract: If the transesterification of esters of the formula ##STR1## with alcohols of the formula III A--(OH).sub.m is catalyzed by successive treatment with catalytic amounts (a) of a tin compound of a metal of the fourth main group or the fourth sub-group of the periodic system and (b) of an acid earth, compounds of the formula I ##STR2## are obtained in virtually quantitative yield. The products thus obtained contain no troublesome by-products and do not have to be additionally purified.R is methyl or ethyl, A is a radical derived from an m-hydric aliphatic alcohol, n is 0 to 2, and m is 1 to 4.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: August 20, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Ivan Orban, Eduard Troxler
  • Patent number: 4535145
    Abstract: The invention relates to a novel process for the preparation of compounds of the formula I ##STR1## by polycondensation of a diol of the formula II ##STR2## with a dicarboxylic acid ester of the formula III ##STR3## In the above formulae, the substituents and symbols R.sub.1, R.sub.2, R.sub.3 and n are as defined in claim 1.The process comprises stirring the reaction medium which contains an excess of 2 to 50 mol. %, based on the diol of formula II, of the dicarboxylic acid ester of the formula III, in the presence of at least 0.03 mol. % of a suitable catalyst, until the bulk of the alkanol of the formula R.sub.3 OH formed during the reaction is distilled off, under a pressure of 0.7 to 1.3 bar, and thereafter stirring under a pressure of less than 5 mbar, in the temperature range from 100.degree. to 170.degree. C., and subsequently working up the resultant melt in conventional manner.
    Type: Grant
    Filed: June 29, 1984
    Date of Patent: August 13, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Eduard Troxler, Thomas Kainmuller, Rudolf Maul
  • Patent number: 4492791
    Abstract: The known reaction of dichlorotriazines of the formula II ##STR1## in which Q is an ether or amino radical, with diamines of the formula IIIPip--NH--R--NH--Pip (III)in which Pip is a radical of the formula ##STR2## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.8 -alkenyl, C.sub.7 -C.sub.11 -phenylalkyl, C.sub.2 -C.sub.8 -alkanoyl or C.sub.3 -C.sub.5 -alkenoyl and R is a divalent organic radical leads to undesirable, sparingly soluble by-products. The formation of these by-products can be suppressed if the reaction is carried out in a water-immiscible organic solvent with the addition of an aqueous base--preferably NaOH or KOH--under pressure at 140.degree.-220.degree. C.
    Type: Grant
    Filed: April 25, 1983
    Date of Patent: January 8, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Ivan Orban, Eduard Troxler
  • Patent number: 4461898
    Abstract: Mixtures of esters of polyalkylpiperidine derivatives, of the formulae I and II ##STR1## in which the proportions of I to II are 95 to 70% by weight and 5 to 30% by weight, are obtained by reacting about 2 mols of a piperidine of the formula III ##STR2## with 0.9 to 1.3 mols of a diester of the formula IV ##STR3## in the melt at between 100.degree. and 145.degree. C., in the presence of an alkali metal amide as a catalyst.The mixtures of esters thus obtained are very suitable as light stabilizers for plastics.
    Type: Grant
    Filed: November 1, 1982
    Date of Patent: July 24, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Anton Meier, Eduard Troxler
  • Patent number: 4357476
    Abstract: New nonadienylamines, nonatrienylamines and nonylamines are described, as well as a new process for their manufacture by reacting a 1,3-diolefine with a Schiff's base in the presence of certain nickel catalysts. The new compounds are suitable for combating micro-organisms, for example in the protection of materials.
    Type: Grant
    Filed: November 22, 1978
    Date of Patent: November 2, 1982
    Assignee: Ciba Geigy Corporation, N.Y.
    Inventors: Dieter Reinchr, Bernard Hugelin, Eduard Troxler
  • Patent number: 4310483
    Abstract: A process for producing a granulate of difficultly fusible additives for plastics, particularly of pigments, by thermal tumbling granulation, which process comprises mixing the additive in powder form with a granulating auxiliary which softens between 30.degree. and 200.degree. C. and which has a particle size of 0.1-2.0 mm; and subjecting this mixture to a gentle rotary motion, with heating by means of a source of heat being simultaneously applied at least until softening of the granulating auxiliary commences.
    Type: Grant
    Filed: August 3, 1979
    Date of Patent: January 12, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Werner H. Dorfel, Bernhard Medinger, Eduard Troxler
  • Patent number: 4275211
    Abstract: A process for producing piperidines of the formula (I) ##STR1## in which R.sub.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, from a ketone of the formula (II) R.sub.1 --CH.sub.2 --C(O)--CH.sub.3, wherein R.sub.1 has the meaning given above, and ammonia, in which process there is used as catalyst a strongly acid ion exchanger having a medium or large mesh size or having large macropores.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: June 23, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Ivan Orban, Eduard Troxler
  • Patent number: 4151163
    Abstract: (Pyrazolinylphenylsulfonyl)-piperazines of the formula ##STR1## wherein R.sub.1 is unsubstituted or substituted alkyl, aralkyl or alkenyl, R.sub.2 is unsubstituted or substituted alkyl, aryl or aralkyl R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are certain substituents and Y is an anion, their preparation as well as their use as optical brighteners are disclosed.
    Type: Grant
    Filed: December 5, 1977
    Date of Patent: April 24, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Eduard Troxler, Christian Luthi
  • Patent number: 4139560
    Abstract: New nonadienylamines, nonatrienylamines and nonylamines are described, as well as a new process for their manufacture by reacting a 1,3-diolefine with a Schiff's base in the presence of certain nickel catalysts. The new compounds are suitable for combating micro-organisms, for example in the protection of materials.
    Type: Grant
    Filed: March 3, 1977
    Date of Patent: February 13, 1979
    Assignee: Ciba Geigy Corporation
    Inventors: Dieter Reinehr, Bernard Hugelin, Eduard Troxler
  • Patent number: 4100111
    Abstract: The invention relates to curable mixtures which contain 1,10-substituted 1,10-diaminodecanes, as the curing agents, new 1,10-substituted 1,10-diaminodecanes and a process for the manufacture of the latter.The new 1,10-diaminodecanes are manufactured by catalytic hydrogenation of corresponding 3,12-substituted 1,2-diazo-1,5,9-cyclododecatrienes in the presence of an inert organic solvent, while raising the temperature to at least 120.degree. C.
    Type: Grant
    Filed: October 29, 1975
    Date of Patent: July 11, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Peter, Dieter Reinehr, Eduard Troxler
  • Patent number: 3939147
    Abstract: New unsaturated 1,2-diazacyclododecanes, more particularly 1,2-diazacyclododecatrienes-1,5,9 and 1,2-diazacyclododecanes-1 and a novel process for the preparation thereof are disclosed which process comprises reacting a 1,3-diolefin with an azine in the presence of certain nickel catalysts. Said process unexpectedly yields 12-membered ring compounds only, and more especially oligomerization products of 2 mols of a 1,3-diolefin and 1 mol of an azine, while deactivation of the nickel catalyst by the -N=N-bond is avoided.
    Type: Grant
    Filed: June 14, 1973
    Date of Patent: February 17, 1976
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Hugelin, Eduard Troxler