Abstract: The invention provides an In situ polymerization process which does not require the use of polymerization initiators or solvents for obtaining an electro-optical apparatus wherein a compound having a polymerizable group, preferably an acrylate or methacrylate, is introduced into a cell formed of 1 to 100 microns thick, wherein said compound having a polymerizable group is maintained at a temperature which is above its melting temperature, and a direct current electric field is applied of at least 2.5 V/?m and for a time ranging between 5 minutes and 24 hours until the polymerization of the compound with the polymerizable group is achieved, an then cooled down to room temperature and removing the applied field.

Abstract: The invention provides an In situ polymerization process which does not require the use of polymerization initiators or solvents for obtaining an electro-optical apparatus wherein a compound having a polymerizable group, preferably an acrylate or methacrylate, is introduced into a cell formed of 1 to 100 microns thick, wherein said compound having a polymerizable group is maintained at a temperature which is above its melting temperature, and a direct current electric field is applied of at least 2.5 V/?m and for a time ranging between 5 minutes and 24 hours until the polymerization of the compound with the polymerizable group is achieved, an then cooled down to room temperature and removing the applied field.