Patents by Inventor Edward J Blok

Edward J Blok has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10059782
    Abstract: This invention relates to a process for the preparation of a silane-functionalized resin composition comprising the steps of mixing a polymer backbone, a silane, and a free radical initiator; and producing a silane-functionalized resin composition. The polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof.
    Type: Grant
    Filed: March 6, 2015
    Date of Patent: August 28, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Ian C. Stewart, David T. Harris
  • Patent number: 10059825
    Abstract: This invention relates to a process for the preparation of a silica-treated functionalized resin composition comprising the steps of reacting a polymer backbone with a hydrosilylation agent to produce a silane-functionalized resin composition, wherein the polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof; and mixing the silane-functionalized resin composition with a silica to produce a silica-treated functionalized resin composition.
    Type: Grant
    Filed: March 6, 2015
    Date of Patent: August 28, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: David T. Harris, Ian C. Stewart, Olivier J. Georjon, Edward J. Blok
  • Patent number: 9994664
    Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
    Type: Grant
    Filed: October 3, 2016
    Date of Patent: June 12, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Eugene R. Uhl, Edward J. Blok, Dennis Kumor, Randal H. Kerstetter, III, Ronald DeYoung
  • Publication number: 20180127527
    Abstract: A hydrocarbon polymer modifier (HPM) is an interpolymer of (i) a vinyl cyclohexene component (ii) a piperylene component; and (iii) a C8-C12 vinyl aromatic component; and wherein the interpolymer comprises (a) a softening point from 40° C. to 160° C., (b) Mn greater than 400, (c) Mz less than 15,000, and (d) at least 8 mole percent aromatic hydrogen, based on the total moles of hydrogen in the interpolymer.
    Type: Application
    Filed: June 1, 2016
    Publication date: May 10, 2018
    Inventors: Ranjan Tripathy, Thomas R. Barbee, Edward J. Blok
  • Publication number: 20180105631
    Abstract: An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.
    Type: Application
    Filed: December 15, 2017
    Publication date: April 19, 2018
    Inventors: Edward J. Blok, Anthony J. Dias, Robert J. Claassen, II, Eugene R. Uhl
  • Patent number: 9909004
    Abstract: A composition including at least one elastomer, and a hydrocarbon polymer additive having a dicyclopentadiene, cyclopentadiene, and methylcyclopentadiene derived content of about 40 wt % to about 80 wt % of the total weight of the hydrocarbon polymer additive, a weight average molecular weight of about 100 g/mole to about 800 g/mole, and a softening point of about 110° C. to about 150° C. as determined in accordance with ASTM D6090.
    Type: Grant
    Filed: February 19, 2013
    Date of Patent: March 6, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Anthony J. Dias, Martin E. Levine
  • Patent number: 9884924
    Abstract: This invention relates to a functionalized resin composition having the formula P-X-S-W where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, X is one or more reactive groups, and W is a silane.
    Type: Grant
    Filed: March 6, 2015
    Date of Patent: February 6, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Ian C. Stewart, Anthony J. Dias, Yong Yang, Jingwen Zhang
  • Patent number: 9868807
    Abstract: An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof. The method comprises melt processing a mixture to form the elastomeric composition in the shape of an article, wherein the mixture comprises elastomer, Si-HPM, silica, bifunctional organosilane crosslinking agent; and curing the elastomeric composition to form the article. Also disclosed are a silylated hydrocarbon polymer modifier coupled with a bifunctional organosilane crosslinking agent, and a silica-coupled hydrocarbon polymer modifier coupled to the silica via the bifunctional organosilane crosslinking agent.
    Type: Grant
    Filed: May 26, 2016
    Date of Patent: January 16, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Anthony J. Dias, Robert J. Claassen, II, Eugene R. Uhl
  • Patent number: 9840569
    Abstract: This invention relates to a functionalized resin composition having the formula P—S—X where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.
    Type: Grant
    Filed: March 6, 2015
    Date of Patent: December 12, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Ian C. Stewart, David T. Harris
  • Publication number: 20170342330
    Abstract: Systems and methods are provided for producing upgraded raffinate and extract products from lubricant boiling range feeds and/or other feeds having a boiling range of 400° F. (204° C.) to 1500° F. (816° C.) or more. The upgraded raffinate and/or extract products can have a reduced or minimized concentration of sulfur, nitrogen, metals, or a combination thereof. The reduced or minimized concentration of sulfur, nitrogen, and/or metals can be achieved by hydrotreating a suitable feed under hydrotreatment conditions corresponding to relatively low levels of feed conversion. Optionally, the feed can also dewaxed, such as by catalytic dewaxing or by solvent dewaxing. Because excessive aromatic saturation is not desired, the pressure for hydrotreatment (and optional dewaxing) can be 500 psig (˜3.4 MPa) to 1200 psig (˜8.2 MPa).
    Type: Application
    Filed: May 19, 2017
    Publication date: November 30, 2017
    Inventors: Benjamin S. Umansky, Keith K. Aldous, James W. Gleeson, Edward J. Blok, Richard A. Demmin
  • Publication number: 20170292013
    Abstract: A tire tread composition is disclosed. The tire tread composition includes components, by weight of the composition, within the range from: 5 to 75 wt % of a diene elastomer; 0 to 40 wt % of processing oil; 20 to 80 wt % of filler; a curative agent; and 5 to 30 wt % of a propylene-ethylene-diene terpolymer containing from 2 wt % to 40 wt % of ethylene and/or C4-C20 ?-olefins derived units, from 0.5 to 10 wt % of diene derived units, and having a heat of fusion, as determined by DSC, of from 0 J/g to 80 J/g.
    Type: Application
    Filed: August 31, 2015
    Publication date: October 12, 2017
    Inventors: Edward J. Blok, Anthony J. Dias, Sunny Jacob, lan C. Stewart, Yong Yang, Jingwen Zhang
  • Publication number: 20170233513
    Abstract: A propylene-ethylene-diene terpolymer and method of making such comprising from 2% to 25% wt % by weight of ethylene, from 98% to 75% wt % by weight propylene and from 1% to 21% wt % by weight of a diene, wherein the terpolymer has a crystallinity of less than 3%, a melt flow rate (MFR) of less than 10 and a Tg by DSC of from ?2° C. to ?25° C. and methods to prepare the terpolymer are depicted.
    Type: Application
    Filed: August 31, 2015
    Publication date: August 17, 2017
    Applicant: ExxonMobil Chemical Patents Inc.
    Inventors: Andy H. Tsou, Edward J. Blok, Gabor Kiss, Rhutesh K. Shah
  • Patent number: 9708435
    Abstract: A polyolefin-polybutadiene block-copolymer and a tire tread composition comprising the polyolefin-polybutadiene block-copolymer, the composition comprising, by weight of the composition, within the range from 15 to 60 wt % of a styrenic copolymer, processing oil, filler, a curative agent, and from 4 to 20 wt % of a polyolefin-polybutadiene block-copolymer, wherein the polyolefin-polybutadiene block-copolymer is a block copolymer having the general formula PO-XL-fPB; where “PO” is a polyolefin block having a weight average molecular weight within the range from 1000 to 150,000 g/mole, the “fPB” is a functionalized polar polybutadiene block having a weight average molecular weight within the range from 500 to 30,000 g/mole, and “XL” is a cross-linking moiety that covalently links the PO and fPB blocks; and wherein the maximum Energy Loss (Tangent Delta) of the immiscible polyolefin domain is a temperature within the range from ?30° C. to 10° C.
    Type: Grant
    Filed: July 15, 2014
    Date of Patent: July 18, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Andy H. Tsou, Shuji Luo, Elizabeth L. Walker, Jingwen Zhang, Yong Yang
  • Publication number: 20170066898
    Abstract: This invention relates to a process for the preparation of a silica-treated functionalized resin composition comprising the steps of reacting a polymer backbone with a hydrosilylation agent to produce a silane-functionalized resin composition, wherein the polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof; and mixing the silane-functionalized resin composition with a silica to produce a silica-treated functionalized resin composition.
    Type: Application
    Filed: March 6, 2015
    Publication date: March 9, 2017
    Inventors: David T. Harris, Ian C. Stewart, Olivier J. Georjon, Edward J. Blok
  • Publication number: 20170058058
    Abstract: This invention relates to a process for the preparation of a silane-functionalized resin composition comprising the steps of mixing a polymer backbone, a silane, and a free radical initiator; and producing a silane-functionalized resin composition. The polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof.
    Type: Application
    Filed: March 6, 2015
    Publication date: March 2, 2017
    Inventors: Edward J. Blok, Ian C. Stewart, David T. Harric
  • Publication number: 20170058057
    Abstract: This invention relates to a functionalized resin composition having the formula P-X-S-W where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, X is one or more reactive groups, and W is a silane.
    Type: Application
    Filed: March 6, 2015
    Publication date: March 2, 2017
    Inventors: Edward J. Blok, Ian C. Stewart, Anthony J. Dias, Yong Yang, Jingwen Zhang
  • Publication number: 20170051085
    Abstract: This invention relates to a functionalized resin composition having the formula P—S—X where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.
    Type: Application
    Filed: March 6, 2015
    Publication date: February 23, 2017
    Inventors: Edward J. Blok, Ian C. Stewart, David T. Harris
  • Publication number: 20170022315
    Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
    Type: Application
    Filed: October 3, 2016
    Publication date: January 26, 2017
    Inventors: Eugene R. Uhl, Edward J. Blok, Dennis Kumor, Randal H. Kerstetter, III, Ronald DeYoung
  • Patent number: 9481795
    Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: November 1, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Eugene Ronald Uhl, Edward J. Blok, Dennis Kumor, Randal Howard Kerstetter, III, Ronald DeYoung
  • Publication number: 20160289352
    Abstract: This invention relates to a dicyclopentadiene (DCPD)-based resin functionalized with groups capable of reacting with silica or carbon black for use in high performance tires and a preferred method of preparing the functionalized resin comprising ruthenium-catalyzed ring-opening cross metathesis. The functionalized resin may comprise the reaction product obtained by contacting a polymer comprising units derived from (DCPD) and a vinyl monomer or vinylene monomer in the presence of a metathesis catalyst, wherein the vinyl monomer or vinylene monomer comprises at least one of the following functional groups: a silyl group, a siloxy group, or an alkoxysilyl group. This invention further relates to a tire tread composition comprising the functionalized resin and which exhibits enhanced durability, traction, handling, and extractability properties.
    Type: Application
    Filed: August 11, 2014
    Publication date: October 6, 2016
    Inventors: Edward J. Blok, Ian C. Stewart, Anthony J. Dias, Yuan-Ju Chen