Abstract: Cathode cans for use in air depolarized cells, and cells made with such cans. The side wall is stronger than the bottom wall, and has a smoother outwardly-disposed surface than the respective bottom wall surface. Strength, and thus hardness, of the side wall relates to strength, and thus hardness, of the bottom wall, as hardness of 130-185 relates, to hardness of 93-117, on the Vickers scale. Preferred hardness of the side wall is about 130 to 185; and of the bottom wall is about 93 to 117. The side wall is drawn, and an outwardly-disposed surface of the side wall is ironed. As ironed, the surface finish is related to surface finish of the bottom wall, at the same stage, as surface finish RA of less than 2, preferably about 0.5 to about 1.5, microinches, is related to surface finish RA of about 2 to about 5, preferably about 2.5 to about 4.5, microinches. Thickness of the side wall is generally up to about 85 percent as great as thickness of the bottom wall.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) walls of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) wars of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: Cathode assembly precursor cathode assembly (26) and elongate air depolarized electrochemical cells (10) made therewith. Cathode assembly precursor comprises a closed-loop elongate cathode current collector (32), and perforations (56) from outer to inner surfaces, and catalystically active carbon extending into the perforations (56). The current collector (32) can be cylindrical and can be free from longitudinal jointing, or can have a longitudinal joint (54), preferably free from overlap of the side wall. The current collector (32) can comprise an imperforate edge region at the top (42) and/or bottom (44), left (48) and/or right (46) edge. The perforations (56) define an open traction of the wall, of about 45 to about 70 percent. Typical cathode assemblies (26) have air diffusion member (36) on the outer surface of the cathode assembly (26). Such air diffusion member (36) typically has thickness of about 0.0025 to 0.005 inch (about 0.06 to about 0.13 mm.

Abstract: This invention pertains to metal-air electrochemical cells wherein one or more air entry ports is located in the bottom of the cathode can, to provide for entry of oxygen-rich air into the cathode can, where the oxygen participates in the electrochemical reaction whereby the cell produces electrical energy. In this invention, extremely small air ports are provided, along with methods of reliably fabricating such small air ports, where a tool impression extends around the port. Generally, the use of an increased number of small air ports distributed over the bottom of the cathode can, opposite the reaction surface of the cathode assembly, wherein the overall open area of the ports is not increased, results in less moisture traversing the air ports, into or out of the cell. Accordingly, moisture loss, or gain, as a function of electrical energy produced, is thereby reduced.

Abstract: This invention pertains to metal-air electrochemical cells wherein one or more air entry ports is located in the bottom of the cathode can, to provide for entry of oxygen-rich air into the cathode can, where the oxygen partcicpates in the chemical reaction whereby the cell produces electrical energy. In this invention, multiple small air entry ports are provided. Generally, the use of multiple ports distributed over the bottom of the cathode can, opposite the reaction surface of the cathode assembly, while not increasing the overall open area of the ports, results in an increase in the ratio of the cell limiting current to the rate at which moisture is lost from the cell. Accordingly, moisture loss as a function of electrical energy produced, is less.

Abstract: This invention pertains to electrochemical cells, typically to air depolarized cells of the button-type. Non-reactive elements of cells of the invention are thinner than corresponding non-reactive elements of prior art cells. Such elements can be made thinner because of improved structures of such elements. The anode can is made from a metal strip structure having a higher steel content. The cathode can preferably has improved stiffness and rigidity while retaining sufficient ductility to tolerate forming the cathode can. By so reducing the thicknesses of non-reactive elements of the cell, and thus the volume occupied by such non-reactive elements, the fraction of the cell devoted to holding electrochemically reactive anode material therein is increased, with corresponding increase in the milliampere hour capacity of the cell.

Abstract: Cathode cans for use in air depolarized cells, and cells made with such cans. The side wall is stronger than the bottom wall, and has a smoother outwardly-disposed surface than the respective bottom wall surface. Strength, and thus hardness, of the side wall relates to strength, and thus hardness, of the bottom wall, as hardness of 130-185 relates, to hardness of 93-117, on the Vickers scale. Preferred hardness of the side wall is about 130 to 185; and of the bottom wall is about 93 to 117. The side wall is drawn, and an outwardly-disposed surface of the side wall is ironed. As ironed, the surface finish is related to surface finish of the bottom wall, at the same stage, as surface finish RA of less than 2, preferably about 0.5 to about 1.5, microinches, is related to surface finish RA of about 2 to about 5, preferably about 2.5 to about 4.5, microinches. Thickness of the side wall is generally up to about 85 percent as great as thickness of the bottom wall.

Abstract: An elongate air depolarized electrochemical cell (10). A grommet (18) closes the top of the cell (10). A seal (36) can extend upwardly into a slot (174) between the grommet (18) and a top closure member (177) such as at the top of a cathode can (28), or a separate top closure member (200). Cathode assembly (26) and separator (16) can extend into the slot (174). The seal is between the grommet (18) and cathode assembly (26), or between grommet (18) and separator (16). or both. The seal can extend upwardly into the slot (174) from an outer surface of the cathode assembly (26), can extend about respective upper edges of the cathode current collector (57), catalyst, and separator (16), and downwardly toward, preferably against or along the inner surface of, the separator (16).

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) walls of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: Cathode cans for use in air depolarized cells, and cells made with such cans. The side wall is stronger than the bottom wall, and has a smoother outwardly-disposed surface than the respective bottom wall surface. Strength, and thus hardness, of the side wall relates to strength, and thus hardness, of the bottom wall, as hardness of 130-185 relates to hardness of 93-117, on the Vickers scale. Preferred hardness of the side wall is about 130 to 185; and of the bottom wall is about 93 to 117. The side wall is drawn, and an outwardly-disposed surface of the side wall is ironed. As ironed, the surface finish is related to surface finish of the bottom wall, at the same stage, as surface finish RA of less than 2, preferably about 0.5 to about 1.5, microinches, is related to surface finish RA of about 2 to about 5, preferably about 2.5 to about 4.5, microinches. Thickness of the side wall is generally up to about 85 percent as great as thickness of the bottom wall.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12). a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) walls of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) walls of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: A method for attenuating x-rays which is insensitive to the x-ray energy employs forward scattering through a filter element to minimize energy shifts due to Compton scattering. Efficiency can be enhanced by employing a material with a large small angle scattering cross section. Since attenuation in the filter increases rapidly with decreasing x-ray energy, the filter provides larger, thinner scattering areas for low energy x-rays and smaller, thicker scattering areas for higher energy x-rays. By adjusting the relative fractions of the scattering areas and their thicknesses, the total scattering yield through the filter can be made to be essentially independent of x-ray energy over a broad band of x-ray energies.

Abstract: This invention pertains to novel alkaline electrochemical cells having high drain capacities, especially cells having high drain rate capabilities at voltages of at least 1.1 volts for use in small appliances such as hearing aids. The anode includes anode material in the cells including potassium hydroxide, zinc powder, 0.02% to 0.5% of a reaction rate enabling compound selected from a compound of indium, cadmium, gallium, thallium, germanium, tin, or lead, with indium compounds being preferred. The anode material optionally further includes a low level of mercury, and preferably a surfactant comprising hydroxyethylcellulose. The cathode provides sufficient oxidative capability to oxidize the zinc at a sufficient rate to support the electrical drain demands on the cell. A cathode, in a preferred zinc air cell for a hearing aid, includes at least 5 air ports, evenly distributed over the surface of the bottom of the cathode can.

Abstract: This invention pertains to alkaline electrochemical cells, typically to metal-air cells of the button-type. Non-reactive elements of cells of the invention are thinner than corresponding non-reactive elements of prior art cells. Such elements can be made thinner because of improved structures of such elements. The anode can is made from a metal strip structure having a higher steel content. The cathode can has a modified temper, which improves relative stiffness and rigidity while retaining sufficient ductility. By so reducing the thicknesses of non-reactive elements of the cell, and thus the volume occupied by such non-reactive elements, the fraction of the cell devoted to holding electrochemically reactive anode material therein is increased, with corresponding increase in the milliampere hour capacity of the cell.

Abstract: This invention pertains to metal-air electrochemical cells wherein one or more air entry ports is located in the bottom of the cathode can, to provide for entry of oxygen-rich air into the cathode can, where the oxygen participates in the electrochemical reaction whereby the cell produces electrical energy. In this invention, extremely small air ports are provided, along with methods of reliably fabricating such small air ports Generally, the use of an increased number of small air ports distributed over the bottom of the cathode can, opposite the reaction surface of the cathode assembly, wherein the overall open area of the ports is not increased, results in less moisture traversing the air ports, into or out of the cell. Accordingly, moisture loss, or gain, as a function of electrical energy produced, is thereby reduced.

Abstract: This invention pertains to electrochemical cells, and anode cans used therein, wherein edge regions of respective anode cans are toed-in. The anode can includes a top wall, and a first side wall depending downwardly from the top wall. The first side wall has an edge region remote from the top wall. The cathode can has a bottom wall, and a second side wall extending upwardly from the bottom wall. The edge region of the first side wall is displaced inwardly of the outer surface of the first side wall as defined at locations away from the edge region. Thus, the edge region is toed-in. Generally, the first side wall follows a path from an intermediate element of the first side wall to a distal edge of the first side wall, wherein no element of the path is directed toward the top wall. The invention further comprehends methods of making the above metal anode cans, and cells.

Abstract: This invention pertains to novel electrochemical metal air cells having improved closed circuit voltage characteristics. The improved voltage characteristics are illustrated at a constant load of 51 ohms. The closed circuit voltage during an initial placement into use of the cell of the invention has a decreased voltage drop relative to prior art cells, and recovers to a higher voltage. For example, the closed circuit voltage of the metal air cell drops to a minimum voltage during the first 20 seconds of initial placement into use. The minimum voltage is no more than 22% less than the initial open circuit voltage. This voltage drop is less than the voltage drop of other known metal air cells at 51 ohms. Metal air cells of the invention recover, during the first minute of use, to a closed circuit voltage of at least 79% of the initial open circuit voltage. The value of the open circuit voltage of the metal air cell of the invention is preferably about 1.43 volt.

Abstract: This invention pertains to electrochemical cells, and anode cans used therein, wherein edge regions of respective anode cans are toed-in. The anode can includes a top wall, and a first side wall depending downwardly from the top wall. The first side wall has an edge region remote from the top wall. The first side wall comprises a curl at the edge region. The edge region comprises a first portion of the first outer surface on the curl. The first portion of the first outer surface is displaced from a first downward projection of the first outer surface of the first side wall as defined at a maximum perimeter element of the intermediate region. Thus, the edge region is toed-in. Generally, the first side wall follows a path from an intermediate element of the first side wall to a bottom edge of the first side wall, and a reverse curl extending from the bottom edge toward the top wall. The cathode can has a bottom wall, and a second side wall extending upwardly from the bottom wall.