Abstract: This invention relates to a method of pretreating cellulosic webs with dry vapors of a lower alkylhalogeno silane, which react with hydroxyl groups in said cellulosic web, and subsequently coating said web. Said invention also relates to the article of manufacture prepared by said method.

Abstract: Modified reactive siloxanes are chemically bonded directly to the surface of a cellulosic substrate to form an oleophilic layer of siloxane on the cellulosic substrate and a conventional ink impregnates the oleophilic siloxane to effect printing thereon.

Abstract: A process for rendering cellulosic material water repellent that requires no subsequent neutralization step while retaining the desired water repellent and strength characteristics thus provided by selecting a cellulosic material having a water content of up to about 10%, preferably below about 2% and contacting the material with vapors of a lower alkyl silicon halide during which contacting the concentration and temperature of the halide vapor, the pressure within the treating chamber and the contact time are all maintained so as to provide a water repellent cellulosic material having a pH greater than 2.5. In one aspect of the invention, the cellulosic material subjecting to contacting is substantially frozen and in another aspect contacting is conducted under vacuum.