Abstract: An adjustable ring is constructed from a first material to form at least a portion of a substantially circular shape. The first material includes two first C-shaped distal halves, and two second C-shaped proximate halves, and each of the halves arranged together to form a vertically bisected O-shape with a top portion removed defining a first arcuate void portion and a bottom portion removed defining a second arcuate void portion. The ring also includes a second material created to fit inside each of the two first and two second C-shaped halves of the first material to form a substantially circular shape defining an inner diameter for a given ring size. The second material includes at least one stress relief point and at least one size bar formed therewith. The second material is created to fit inside the first material using one or more of casting, co-casting, machining, forging, and stamping.

Abstract: Silica polyamine composites (SPC) made from silanized amorphous nano-porous silica gel and poly(allylamine) (BP-1) were functionalized with phosphorus acid using the Mannich reaction, resulting in a phosphonic acid modified composite (BPAP). Zirconium (IV) was immobilized on BPAP. Arsenate anions strongly adsorbed on the ZrBPAP composite in the pH range 2 to 8, while arsenite only adsorbed well at pH 10. Regeneration of the resin was carried out successfully for As(V) and As(III) using 2M-H2SO4. Four adsorption/desorption cycles were performed for As(V) at pH 4 without significant decrease in the uptake performance. ZrBPAP capture capacity and kinetics for arsenate were tested for longevity over 1000 cycles with only a marginal loss of performance.

Abstract: An adjustable ring is constructed from a first material to form at least a portion of a substantially circular shape. The first material includes two first C-shaped distal halves, and two second C-shaped proximate halves, and each of the halves arranged together to form a vertically bisected O-shape with a top portion removed defining a first arcuate void portion and a bottom portion removed defining a second arcuate void portion. The ring also includes a second material created to fit inside each of the two first and two second C-shaped halves of the first material to form a substantially circular shape defining an inner diameter for a given ring size. The second material includes at least one stress relief point and at least one size bar formed therewith. The second material is created to fit inside the first material using one or more of casting, co-casting, machining, forging, and stamping.

Abstract: A Co-Casting technique is described herein using Pins, Undercuts, Grooves, Rails that permit the attachment of a secondary precious metal to a primary alternative meta. The process of making a mold creating a model and casting a final worked piece uses wax filling of the recessed areas and the subsequent molding of the precious metal within the recessed areas in order to fill the aforementioned.

Abstract: Oxine ligands placed on styrene base ion exchange resins selectively remove iron and gallium from acidic solutions. After loading, the oxine resin is stripped of the loaded metals and used again for further metal removal. The resins can be used for process streams, acid rock drainages, or any other iron or gallium containing solution.

Abstract: The present application discloses new decorative articles. The decorative articles may have a base having a reflective upper surface. The decorative articles may include at least one an aesthetic item located at least proximal the reflective upper surface of the base. The decorative articles may include an affixing material disposed on the reflective upper surface of the base, wherein the affixing material fixes the aesthetic item in a predetermined orientation relative to the reflective upper surface.

Abstract: An article of manufacture having an alternative material and a precious material making this unique in bonding materials that are significantly dissimilar having an alternative material having an integral securing area and a laminate of precious material connected at the securing area of the alternative material having a contoured shape substantially matching a shape of the first alternative material.

Abstract: A Co-Casting technique is described herein using Pins, Undercuts, Grooves, Rails that permit the attachment of a secondary precious metal to a primary alternative meta. The process of making a mold creating a model and casting a final worked piece uses wax filling of the recessed areas and the subsequent molding of the precious metal within the recessed areas in order to fill the aforementioned.

Abstract: Silica polyamine composites (SPC) made from silanized amorphous nano-porous silica gel and poly(allylamine) (BP-1) were functionalized with phosphorus acid using the Mannich reaction, resulting in a phosphonic acid modified composite (BPAP). Zirconium (IV) was immobilized on BPAP. Arsenate anions strongly adsorbed on the ZrBPAP composite in the pH range 2 to 8, while arsenite only adsorbed well at pH 10. Regeneration of the resin was carried out successfully for As(V) and As(III) using 2M-H2SO4. Four adsorption/desorption cycles were performed for As(V) at pH 4 without significant decrease in the uptake performance. ZrBPAP capture capacity and kinetics for arsenate were tested for longevity over 1000 cycles with only a marginal loss of performance.

Abstract: Oxine ligands placed on styrene base ion exchange resins selectively remove iron and gallium from acidic solutions. After loading, the oxine resin is stripped of the loaded metals and used again for further metal removal. The resins can be used for process streams, acid rock drainages, or any other iron or gallium containing solution.

Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.

Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.

Abstract: Silica polyamine composites (SPC) made from silanized amorphous nano-porous silica gel and poly(allylamine) (BP-1) were functionalized with phosphorus acid using the Mannich reaction, resulting in a phosphonic acid modified composite (BPAP). Zirconium (IV) was immobilized on BPAP. Arsenate anions strongly adsorbed on the ZrBPAP composite in the pH range 2 to 8, while arsenite only adsorbed well at pH 10. Regeneration of the resin was carried out successfully for As(V) and As(III) using 2M-H2SO4. Four adsorption/desorption cycles were performed for As(V) at pH 4 without significant decrease in the uptake performance. ZrBPAP capture capacity and kinetics for arsenate were tested for longevity over 1000 cycles with only a marginal loss of performance.

Abstract: An article of jewelry and method of producing an article of jewelry, comprising providing a substrate made of a biocompatible medical grade cobalt-based alloy that includes cobalt, chromium and molybdenum. The cobalt-based alloy substrate is formed into a desired shape of the article of jewelry.

Abstract: The osmium (Os) cluster-functionalized CNT of the present invention formed from a triosmium derivative having one or more amine groups and a functionalized carbon nanotube having a plurality of COOH groups through zwitterionic interactions between the COOH and amine groups has high solubilities in water and various organic solvents.

Abstract: The osmium (Os) cluster-functionalized CNT of the present invention formed from a triosmium derivative having one or more amine groups and a functionalized carbon nanotube having a plurality of COOH groups through zwitterionic interactions between the COOH and amine groups has high solubilities in water and various organic solvents.

Abstract: A silica-polyamine based extraction material removes selected transition metal ions from solution in the presence of iron ions. The silica-polyamine base is a reaction product of a polyamine and a covalently anchored trifunctional hydrocarbylsilyl that yields non-crosslinked amino groups to which pyridine function group is attached. The extraction material is particularly useful in selectively removing copper from low concentration, low pH leach solutions separating copper from ferric iron or chloride ions. The product is a durable, high capacity extraction material that selectively captures copper at high flow rates and releases that copper into highly concentrated solutions.

Abstract: A process for forming a metallic article having a black ornamental surface includes the steps of metallurgically providing an alloy containing between about 51 and 70 about percent by weight of titanium, between about 3 and about 17 percent by weight of niobium, and the balance of a metal selected from the group consisting of zirconium, tantalum, molybdenum, hafnium zirconium, chromium, and mixtures thereof. The alloy is then casted and/or metal worked into a workpiece having a desired geometry and surface texture. The workpiece thereof is then baked in a kiln or oven in a substantially air atmosphere of between about 450 and about 850 degrees C. for a period of between about one and about 29 minutes. Resultant of such baking, there is produced a durable black surface layer consisting substantially of an oxide of niobium which is adhered to the substrate of the workpiece which remains unoxidized.