Patents by Inventor Eldon D. Dalrymple
Eldon D. Dalrymple has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8703659Abstract: A sealant composition for servicing a wellbore comprising at least one gel system, a leak off prevention material and water.Type: GrantFiled: January 19, 2006Date of Patent: April 22, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, Diederik W. van Batenburg, Jip van Eijden
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Patent number: 8631869Abstract: Provided are methods of using fluid loss control additives that comprise a water-soluble polymer with hydrophobic or hydrophilic modification. In one embodiment, a method of providing at least some degree of fluid loss control during a subterranean treatment is provided. In an example of such a method, the method may comprise providing a treatment fluid comprising an aqueous liquid and a fluid loss control additive, the fluid loss control additive comprising a water-soluble polymer with hydrophobic or hydrophilic modification; and introducing the treatment fluid into a well bore that penetrates a subterranean formation, wherein there is at least a partial reduction in fluid loss into at least a portion of the subterranean formation from the treatment fluid and/or another aqueous fluid introduced into well bore subsequent to the treatment fluid.Type: GrantFiled: April 8, 2005Date of Patent: January 21, 2014Inventors: Leopoldo Sierra, Eldon D. Dalrymple, Larry S. Eoff, Barireddy R. Reddy, Matthew E. Blauch, Mark A. Parker
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Patent number: 8623793Abstract: Methods comprising providing a relative permeability modifier that comprises a hydrophilic polymer backbone with a hydrophobic modification and incorporating at least one cationic compound onto the hydrophilic polymer backbone. The hydrophilic polymer is one or more of: a polyacrylamide; a polyvinylamine; a poly(vinylamine/vinyl alcohol); an alkyl acrylate polymer; cellulose; chitosan; a polyamide; a polyetheramine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; or a starch. The hydrophobic modification is achieved either by reacting the hydrophilic polymer with a hydrophobic compound or by a polymerization reaction product of a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobic compound has an alkyl chain length from 4 to 22 carbons and is one or more of: an alkyl acrylate; an alkyl methacrylate; an alkyl acrylamide; an alkyl methacrylamide; or an alkyl dimethylammoniumethyl methacrylate halide.Type: GrantFiled: June 27, 2012Date of Patent: January 7, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, B. Raghava Reddy, Eldon D. Dalrymple
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Patent number: 8592353Abstract: Method of diverting fluids in a subterranean formation including the steps of providing a first fluid comprising an aqueous fluid and a hydrophobically modified water-soluble relative permeability modifier; introducing the first fluid into a well bore such that the first treatment fluid penetrates into a portion of the subterranean formation in a sufficient amount so as to substantially divert a second treatment fluid to another portion of the subterranean formation. Then, a second aqueous fluid is introduced into the well bore and substantially diverted from the portion of the subterranean formation penetrated with the first treatment fluid. In some cases, a well treatment operation, such as acid stimulation operation, a clay stabilization operation, or a scale inhibition operation, is performed using the second fluid.Type: GrantFiled: March 16, 2012Date of Patent: November 26, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Patent number: 8459352Abstract: Selective placement of conformance treatments in multi-zone well completions. A method includes injecting a relative permeability modifier into a zone and optimizing a ratio of desired fluid to undesired fluid produced from the zone, including adjusting at least one flow control device between fully open and fully closed configurations. Another method includes injecting a relative permeability modifier into multiple zones, one at a time, via respective flow control devices, and then producing fluid from each of the zones. Another method includes identifying which of the zones to treat by, for each of the zones: a) closing flow control devices corresponding to the other zones, and b) evaluating fluid produced from the zone; and injecting a conformance treatment into the zones identified as the zones to treat.Type: GrantFiled: December 10, 2012Date of Patent: June 11, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Mark D. Kalman, Eldon D. Dalrymple, Larry Eoff
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Patent number: 8420576Abstract: Methods comprising introducing a hydrophobically and cationically modified relative permeability modifier into a portion of a subterranean formation. The hydrophobically and cationically modified relative permeability modifier comprises a hydrophilic polymer backbone with a hydrophobic modification and a cationic modification. The cationic modification may comprise at least one cationic compound comprising an alkyl chain length of from 1 to 3 carbons.Type: GrantFiled: August 10, 2009Date of Patent: April 16, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, B. Raghava Reddy, Eldon D. Dalrymple
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Patent number: 8387694Abstract: Methods comprising identifying an interval of a subterranean formation to be treated, the interval comprising multiple portions, each portion having a different effective permeability; introducing a relative-permeability modifier into the interval; and, introducing a sealant into the interval. The relative-permeability modifier modifies the interval to have a more uniform effective permeability to water-based fluids. The relative-permeability modifier comprises a water-soluble polymer. The more uniform effective permeability of the interval allows for a more uniform treatment of the interval by the sealant than would be allowed without treatment of the interval with the relative-permeability modifier.Type: GrantFiled: August 10, 2012Date of Patent: March 5, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Julio E. Vasquez, Larry S. Eoff
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Patent number: 8360145Abstract: Selective placement of conformance treatments in multi-zone well completions. A method includes injecting a relative permeability modifier into a zone and optimizing a ratio of desired fluid to undesired fluid produced from the zone, including adjusting at least one flow control device between fully open and fully closed configurations. Another method includes injecting a relative permeability modifier into multiple zones, one at a time, via respective flow control devices, and then producing fluid from each of the zones. Another method includes identifying which of the zones to treat by, for each of the zones: a) closing flow control devices corresponding to the other zones, and b) evaluating fluid produced from the zone; and injecting a conformance treatment into the zones identified as the zones to treat.Type: GrantFiled: April 6, 2012Date of Patent: January 29, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Mark D. Kalman, Eldon D. Dalrymple, Larry Eoff
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Publication number: 20120298360Abstract: Methods comprising identifying an interval of a subterranean formation to be treated, the interval comprising multiple portions, each portion having a different effective permeability; introducing a relative-permeability modifier into the interval; and, introducing a sealant into the interval. The relative-permeability modifier modifies the interval to have a more uniform effective permeability to water-based fluids. The relative-permeability modifier comprises a water-soluble polymer. The more uniform effective permeability of the interval allows for a more uniform treatment of the interval by the sealant than would be allowed without treatment of the interval with the relative-permeability modifier.Type: ApplicationFiled: August 10, 2012Publication date: November 29, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Julio E. Vasquez, Larry S. Eoff
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Patent number: 8302691Abstract: Exemplary embodiments provide methods of treating a subterranean formation to improve gas production therefrom. Exemplary embodiments of the methods comprise introducing a cationic polyorganosiloxane into the subterranean formation, wherein the cationic polyorganosiloxane comprises at least two quaternary ammonium groups.Type: GrantFiled: January 19, 2007Date of Patent: November 6, 2012Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Danhua Leslie Zhang, Eldon D. Dalrymple, Paul S. Brown
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Publication number: 20120264885Abstract: Methods comprising providing a relative permeability modifier that comprises a hydrophilic polymer backbone with a hydrophobic modification and incorporating at least one cationic compound onto the hydrophilic polymer backbone. The hydrophilic polymer is one or more of: a polyacrylamide; a polyvinylamine; a poly(vinylamine/vinyl alcohol); an alkyl acrylate polymer; cellulose; chitosan; a polyamide; a polyetheramine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; or a starch. The hydrophobic modification is achieved either by reacting the hydrophilic polymer with a hydrophobic compound or by a polymerization reaction product of a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobic compound has an alkyl chain length from 4 to 22 carbons and is one or more of: an alkyl acrylate; an alkyl methacrylate; an alkyl acrylamide; an alkyl methacrylamide; or an alkyl dimethylammoniumethyl methacrylate halide.Type: ApplicationFiled: June 27, 2012Publication date: October 18, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, B. Raghava Reddy, Eldon D. Dalrymple
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Patent number: 8278250Abstract: Methods of using relative permeability modifiers for the diversion of aqueous fluids during subterranean operations are provided. An embodiment of the present invention provides a method of diverting fluids in a subterranean formation that may comprise providing a treatment fluid comprising an aqueous fluid and a relative permeability modifier that comprises water-soluble polymer with hydrophobic or hydrophilic modification; introducing the treatment fluid into a well bore that penetrates the subterranean formation; and at least a first portion of the treatment fluid to penetrate into a portion of the subterranean formation so as to substantially divert a second portion of the treatment fluid or another aqueous treatment fluid to another portion of the subterranean.Type: GrantFiled: May 5, 2005Date of Patent: October 2, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Patent number: 8272440Abstract: Methods for treating an interval of a subterranean formation having a permeability that varies include identifying the interval to be treated; introducing a relative-permeability modifier into the interval, wherein the relative-permeability modifier modifies the interval to have a more uniform effective permeability to water, and wherein the relative-permeability modifier comprises a water-soluble polymer; and introducing a sealant into the interval, wherein the more uniform effective permeability of the interval allows for a more uniform treatment of the interval by the sealant than would be allowed without treatment of the interval with the relative-permeability modifier.Type: GrantFiled: December 17, 2009Date of Patent: September 25, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Julio E. Vasquez, Larry S. Eoff
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Patent number: 8273692Abstract: Methods of reducing the permeability of a subterranean formation to aqueous-based fluids using a water-soluble relative permeability modifier that comprises a hydrophobically modified polymer, wherein the hydrophobically modified polymer is a reaction product of: a hydrophilic polymer that comprises a polymer selected from the group consisting of a polyvinylamine, a poly(vinylamine/vinyl alcohol), and an alkyl acrylate polymer; and, a hydrophobic compound comprising at least one alkyl chain having a carbon chain length between about 4 and about 22 carbons. The water-soluble relative permeability modifier may be placed within a subterranean drilling operation such that the water-soluble relative permeability modifier attaches onto surfaces within the subterranean formation to effect permeability of aqueous fluids.Type: GrantFiled: August 10, 2011Date of Patent: September 25, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Eldon D. Dalrymple, B. Raghava Reddy
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Publication number: 20120231978Abstract: Drilling fluids comprising a base fluid and a hydrophobically modified polymer. The hydrophobically modified polymer consisting of alkyl chains having a carbon chain length between about 4 and about 22 carbons bound to a hydrophilic polymer. The hydrophilic polymer (1) consists of a polymer backbone that contains polar heteroatoms, at least one of which is not a nitrogen atom, and at least a portion of the polar heteroatoms are functionalized with the alkyl chains; and, (2) comprises at least one hydrophilic polymer selected from the group consisting of a cellulose, a chitosan, a polyetheramine, a polyhydroxyetheramine, a polylysine, and a polysulfone.Type: ApplicationFiled: May 22, 2012Publication date: September 13, 2012Inventors: Larry S. Eoff, Eldon D. Dalrymple, B. Raghava Reddy
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Publication number: 20120222860Abstract: Selective placement of conformance treatments in multi-zone well completions. A method includes injecting a relative permeability modifier into a zone and optimizing a ratio of desired fluid to undesired fluid produced from the zone, including adjusting at least one flow control device between fully open and fully closed configurations. Another method includes injecting a relative permeability modifier into multiple zones, one at a time, via respective flow control devices, and then producing fluid from each of the zones. Another method includes identifying which of the zones to treat by, for each of the zones: a) closing flow control devices corresponding to the other zones, and b) evaluating fluid produced from the zone; and injecting a conformance treatment into the zones identified as the zones to treat.Type: ApplicationFiled: April 6, 2012Publication date: September 6, 2012Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Mark D. KALMAN, Eldon D. DALRYMPLE, Larry EOFF
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Patent number: 8251141Abstract: Methods comprising providing a carrier fluid comprising an aqueous-based component, a water-soluble relative permeability modifier, and gravel particulates wherein the water-soluble relative permeability modifier suspends at least a portion of the gravel particulates; and introducing the carrier fluid into a well bore penetrating a subterranean formation, such that the gravel particulates form a gravel pack near the well bore. In some embodiments, the carrier fluid is substantially free of a viscosifying agent.Type: GrantFiled: August 9, 2006Date of Patent: August 28, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, David L. Brown, Eldon D. Dalrymple, Paul S. Brown
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Publication number: 20120168166Abstract: Method of diverting fluids in a subterranean formation including the steps of providing a first fluid comprising an aqueous fluid and a hydrophobically modified water-soluble relative permeability modifier; introducing the first fluid into a well bore such that the first treatment fluid penetrates into a portion of the subterranean formation in a sufficient amount so as to substantially divert a second treatment fluid to another portion of the subterranean formation. Then, a second aqueous fluid is introduced into the well bore and substantially diverted from the portion of the subterranean formation penetrated with the first treatment fluid. In some cases, a well treatment operation, such as acid stimulation operation, a clay stabilization operation, or a scale inhibition operation, is performed using the second fluid.Type: ApplicationFiled: March 16, 2012Publication date: July 5, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Patent number: 8196655Abstract: Selective placement of conformance treatments in multi-zone well completions. A method includes injecting a relative permeability modifier into a zone and optimizing a ratio of desired fluid to undesired fluid produced from the zone, including adjusting at least one flow control device between fully open and fully closed configurations. Another method includes injecting a relative permeability modifier into multiple zones, one at a time, via respective flow control devices, and then producing fluid from each of the zones. Another method includes identifying which of the zones to treat by, for each of the zones: a) closing flow control devices corresponding to the other zones, and b) evaluating fluid produced from the zone; and injecting a conformance treatment into the zones identified as the zones to treat.Type: GrantFiled: August 31, 2009Date of Patent: June 12, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Mark D. Kalman, Eldon D. Dalrymple, Larry Eoff
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Patent number: 8158720Abstract: Crosslinkable polymer compositions are provided that may be useful for, among other things, reducing, stopping, or diverting the flow of fluids in subterranean formations. The crosslinkable polymer compositions may comprise an aqueous fluid, a chitosan-reacting polymer, chitosan, and a gelation-retarding additive comprising an acid derivative. Various methods of use are also provided.Type: GrantFiled: June 28, 2005Date of Patent: April 17, 2012Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Eldon D. Dalrymple, Julio Vasquez