Abstract: The present disclosure relates to electrolysis systems and methods. The teachings thereof may be embodied in methods and systems for the utilization of carbon dioxide and production of carbon monoxide. For example, a method may include: passing an electrolyte and carbon dioxide in front of a cathode through a cathode chamber; and removing electrolysis byproducts from an electrolyte/electrolysis product mixture using a catalytic filter system. The cathode may include material to reduce carbon dioxide. The process may generate a hydrocarbon compound or carbon monoxide as the electrolysis product and a formate as an electrolysis byproduct. The filter system may include a functionalized complex or a functionalized support material which catalyzes a cleavage reaction of formates (a) to hydrogen and carbon dioxide, or (b) to water and carbon monoxide.

Abstract: The present disclosure relates to electrolysis. The teachings thereof may be embodied in a reduction process and/or an electrolysis system for electrochemical carbon dioxide utilization wherein carbon dioxide is introduced into an electrolysis cell and reduced at a cathode. For example, an electrolysis system for carbon dioxide utilization may comprise: an electrolyzer including an anode in an anode space and a cathode in a cathode space. The cathode space has an entrance for carbon dioxide. The cathode space comprises a catholyte including alkali metal cations. The anode space has an entrance for an anolyte. The anode space comprises an anolyte comprising chlorine anions.

Abstract: The present disclosure relates to electrolysis. Teachings thereof may be embodied in a reduction method and/or an electrolysis system for electrochemical carbon dioxide utilization. For example, an electrolysis system for carbon dioxide utilization may include: an electrolysis cell with an anode in an anode space, a cathode in a cathode space, and a membrane; a first feed for carbon dioxide into the cathode space, configured to bring the carbon dioxide into contact with the cathode; a proton donor unit; and a second feed for protons configured to bring the protons into the cathode space from the proton donor unit into contact with the cathode.

Abstract: The present disclosure relates to electrolysis systems and methods. The teachings thereof may be embodied in methods and systems for the utilization of carbon dioxide and production of carbon monoxide. For example, a method may include: passing an electrolyte and carbon dioxide in front of a cathode through a cathode chamber; and removing electrolysis byproducts from an electrolyte/electrolysis product mixture using a catalytic filter system. The cathode may include material to reduce carbon dioxide. The process may generate a hydrocarbon compound or carbon monoxide as the electrolysis product and a formate as an electrolysis byproduct. The filter system may include a functionalized complex or a functionalized support material which catalyzes a cleavage reaction of formates (a) to hydrogen and carbon dioxide, or (b) to water and carbon monoxide.