Abstract: The present invention relates to a method for preparing photoluminescent silicon nanoparticles having uniformly hydrogen-terminated surfaces that are essentially free of residual oxygen. The present invention also relates to a method of preparing a blue-emitting photoluminescent silicon nanoparticle. The present invention further relates to a composition that includes a photoluminescent silicon nanoparticle having a surface that is uniformly hydrogen-terminated and essentially free of residual oxygen. The present invention also relates to a composition including a photoluminescent silicon nanoparticle having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen. The present invention additionally relates to a composition including a photoluminescent silicon nanoparticle stably dispersed in an organic solvent and having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen.

Abstract: The present invention relates to a method for preparing photoluminescent silicon nanoparticles having uniformly hydrogen-terminated surfaces that are essentially free of residual oxygen. The present invention also relates to a method of preparing a blue-emitting photoluminescent silicon nanoparticle. The present invention further relates to a composition that includes a photoluminescent silicon nanoparticle having a surface that is uniformly hydrogen-terminated and essentially free of residual oxygen. The present invention also relates to a composition including a photoluminescent silicon nanoparticle having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen. The present invention additionally relates to a composition including a photoluminescent silicon nanoparticle stably dispersed in an organic solvent and having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen.

Abstract: A method is provided for the preparation of a hydrogen storage medium having a high hydrogen storage capacity, high reversibility and fast reaction time. A high storage capacity Li3N-containing media with high reversibility is also provided.

Abstract: A method is provided for the preparation of a hydrogen storage medium having a high hydrogen storage capacity, high reversibility and fast reaction time. A high storage capacity Li2NH -containing media with high reversibility is also provided. The method comprises an ultra-fast solid reaction between Li3N and LiNH2 to provide an effective Li2NH material, which can reversibly store 6.8 wt % hydrogen with fast kinetics and excellent stability.

Abstract: A method is provided for the preparation of a hydrogen storage medium having a high hydrogen storage capacity, high reversibility and fast reaction time. A high storage capacity Li3N-containing media with high reversibility is also provided.

Abstract: The present invention provides a method for the preparation of graft, block, and star-shaped copolymers. The method involves in situ coupling reaction between a living anionic backbone polymer possessing epoxy side chains and other living anionic polymers. The present method is simple, the coupling reaction is fast, pure copolymers are produced and the molecular weight, graft number and grafting position can be controlled to a greater extent than in existing methods.

Abstract: The present invention relates to a continuous method of preparing a block-graft or star-shaped copolymer. This method involves providing a living polymer, mixing the living polymer with a first monomer under conditions effective to produce a block copolymer, wherein the first monomer includes a polymerization site and a polymerization initiation site, and mixing the block copolymer with a second monomer under conditions effective to produce a block-graft or star-shaped copolymer. The present invention also relates to a continuous method of preparing a graft or graft-block copolymer.

Abstract: The present invention discloses the synthesis of a novel crosslinker having the following structure: R1 is C(R8) (R9) wherein (R8) is H, or an alkyl group having 1-5 carbon atoms, and (R9) is H, or an alkyl group having 1-5 carbon atoms. R2 is H, or an alkyl group having 1-5 carbon atoms. R3 is H or an alkyl group having 1-5 carbon atoms. R4 is an alkyl group having 1-5 carbon atoms. R5 is H or an alkyl group having 1-5 carbon atoms. R6 is H or an alkyl group having 1-5 carbon atoms. R7 is C(R10) (R11) wherein (R10) is H, or an alkyl group having 1-5 carbon atoms, and (R11) is H, or an alkyl group having 1-5 carbon atoms. The crosslinker is stable in a basic environment, but decomposable in an acidic environment.

Abstract: This invention relates to a microporous or macroporous affinity filtration membrane wherein the matrix of the membrane is composed of chitin and the pores are made by dissolution of porogen during the preparation of the membrane. The invention also relates to a method for the purification of wheat germ agglutinin using chitin microprous or macroporous membranes.

Abstract: This invention relates to a microporous or macroporous affinity filtration membrane wherein the matrix is composed of chitosan or chitin and the pores are made by dissolution of porogen during the preparation of the membrane. The invention also relates to a method of preparation of the membrane comprising preparing an acidic chitosan solution containing porogen, shaping the suspension into a membrane, and dissolving the porogen by immersing the membrane in an alkaline solution. To prepare chitin membranes, the chitosan membranes are acetylated. The special feature of the membrane is that the pore size can be controlled by varying the size of the porogen. The membranes are suitable for affinity purification of macromolecules.

Abstract: The present invention relates to a method for preparing polymer composites. The method includes providing a mixture of concentrated emulsions and polymerizing the mixture of concentrated emulsions under conditions effective to form a polymer composite. The mixture of concentrated emulsions includes either a divinyl-terminated macromonomer and a first partially polymerized concentrated emulsion of a first monomer or a first partially copolymerized concentrated emulsion of a divinyl-terminated macromonomer and a first monomer. The mixture of concentrated emulsions further includes either a second partially polymerized concentrated emulsion of a second monomer or a second partially copolymerized concentrated emulsion of a divinyl-terminated macromonomer and a second monomer. Using the methods of the present invention, polymer blends and/or polymer networks containing compatibilizers can be produced.

Abstract: A composite is formed wherein particles of a conductive polymer are uniformly distributed within a processable non-conductive polymer. In the method of the invention, an inverted emulsion is formed by dispersing an aqueous solution of oxidant in an organic solvent comprising a host polymer and an oil-soluble surfactant. A monomer whose polymerization yields a conductive polymer which is dissolved in a solvent miscible with the organic solvent of the emulsion is then added dropwise to the emulsion with agitation. The composite is separated from the emulsion and the precipitate is washed and dried.

Abstract: A paste including a thermally conducting solid filler, a nonaqueous liquid carrier and a stabilizing dispersant. The pastes are highly concentrated, of low viscosity, electrically resistive, highly thermally conducting and stable. The pastes are easily applicable to electrical and electronic devices and may be removed therefrom with common solvents to access components where necessary.

Abstract: A polymer composite, a method of making a polymer composite and a polymer composite membrane. The polymer composite comprises a uniform dispersion of hydrophobic polymeric particles in a continuous phase of a hydrophilic polymer. The new method of forming a polymer composite includes the formation of a concentrated emulsion of a hydrophilic monomer and a hydrophobic monomer and heating the concentrated emulsion at a predetermined temperature. The polymer composites of this invention may be useful as permselective membranes.

Abstract: A polymer article and a method for making the polymer article. The polymer article includes a hydrophobic polymer substrate and a block copolymer. The block copolymer has at least first and second blocks. The first block is more hydrophobic than the second block. The molecules of the block copolymer are secured into the surface of said substrate by means of the first block and at least a portion of the second block, outwardly extends from the surface of the substrate into the environment.The method for making the polymer article, comprising a block copolymer and a hydrophobic substrate, comprises the steps of: (a) forming a solution of a block copolymer and a solvent which will solubilize said block copolymer and swell said substrate. The block copolymer has at least a first and second block.