Abstract: Provided is a curable composition including the following components: (i) a first alkoxysilane which is unhydrolyzed; (ii) a second alkoxysilane which is 5 to 45 percent hydrolyzed; and (iii) an ethylenically unsaturated monomer. The invention also provides coatings formed from the curable composition and articles coated with the curable composition.

Abstract: A coated optical article includes: an optical substrate; a first coating layer applied directly over at least a portion of an optical substrate, the first coating layer formed from a first coating composition including an aqueous medium and keto and/or aldo functional polymeric materials that are dispersed in the aqueous medium; and a second coating layer applied directly over at least a portion of the first coating layer, the second coating layer including a sol-gel and which is formed from a second coating composition. The first coating composition and second coating composition are each independently substantially free of hydrazine and hydrazide functional components.

Abstract: A batch process for preparing a molded optical article includes introducing (i) a dithiol component or (ii) a polyisocyanate component into a reaction vessel; adding a first catalyst of organotin halide to form a first reaction mixture; heating the first reaction mixture; introducing a second catalyst of tertiary amine to the first reaction mixture; mixing a polyisocyanate (ii) into the reaction vessel containing the first reaction mixture if dithiol (i) was first added, or mixing a dithiol (i) into the first reaction mixture if the polyisocyanate (ii) was first added, to form a second reaction mixture; filling a mold with the second reaction mixture to provide a filled mold to form a molded optical article. The molar ratio of elemental tin present in the first catalyst to tertiary amine compound present in the second catalyst ranges from 0.04:1 to 0.29:1.