Abstract: A gel paste composition including (A) a crosslinking organopolysiloxane and (B) a liquid oil, the crosslinking organopolysiloxane (A) being obtained by reacting an organohydrogenpolysiloxane shown by the following general formula (I) with a polyoxyalkylene compound shown by the following general formula (II) in the presence of a catalyst for hydrosilylation reaction, the component (A) containing polyoxyethylene units in an amount of 20 wt % or more. As a result, the gel paste composition that contains a crosslinking organopolysiloxane having improved compatibility with ethylhexyl methoxycinnamate and water, and thus exhibits excellent dispersibility when blended to a cosmetic thereby providing good feeling and cosmetic sustainability. R1aHbSiO(4-a-b)/2??(I) CcH2c-1O(C2H4O)d(C3H6O)eCcH2c-1??(II).

Abstract: A silicone compound is represented by the formula (1) and has a weight average molecular weight of 500 to 200000. A polyhydric alcohol-modified silicone compound can provide a stable composition (emulsified product, powder dispersion, etc.) having a silicone oil and other oil as a continuous phase. R1aR2bR3cR4dSiO(4-a-b-c-d)/2??(1) (R1 represents an organic group, R2 is a group represented by —Y—O—X (Y represents a divalent hydrocarbon group having 3 to 20 carbons and optionally containing at least one of an ether bond and an ester bond, and X represents a polyhydric alcohol-substituted hydrocarbon group having at least two hydroxyl groups); R3 is a monovalent branched type organosiloxane group represented by the formula (4); and R4 is a monovalent organosiloxane group represented by the formula (5) or the formula (6).

Abstract: A water-absorbing polymer obtained from polymerization of (A) and (B) in aqueous medium wherein (A) is a phosphate-containing (meth)acrylic monomer and/or a salt thereof, and (B) is a monomer having one (meth)acrylic group within the molecule and/or a salt thereof that is different from component (A); and reacting the reaction product of (A) and (B) with (C) an organopolysiloxane having a (meth)acrylic group at both ends.

Abstract: A silicone compound is represented by the formula (1) and has a weight average molecular weight of 500 to 200000. A polyhydric alcohol-modified silicone compound can provide a stable composition (emulsified product, powder dispersion, etc.) having a silicone oil and other oil as a continuous phase. R1aR2bR3cR4dSiO(4-a-b-c-d)/2??(1) (R1 represents an organic group, R2 is a group represented by —Y—O—X (Y represents a divalent hydrocarbon group having 3 to 20 carbons and optionally containing at least one of an ether bond and an ester bond, and X represents a polyhydric alcohol-substituted hydrocarbon group having at least two hydroxyl groups); R3 is a monovalent branched type organosiloxane group represented by the formula (4); and R4 is a monovalent organosiloxane group represented by the formula (5) or the formula (6).

Abstract: A film-forming composition containing a polymer obtained by polymerizing (A) 5 to 80 mass % of a silicone resin having an R3SiO1/2 unit, an R2R?SiO1/2 unit, and an SiO2 unit, where R may be the same or different and represents a monovalent hydrocarbon group having 1 to 6 carbon atoms, and R? represents a —C3H6SH group, wherein a total amount of the R3SiO1/2 unit, R2R?SiO1/2 unit, and SiO2 unit is 80 mol % or more with respect to all structural units, and a mole ratio expressed by (sum of R3SiO1/2 unit and R2R?SiO1/2 unit)/(SiO2 unit) ranges from 0.5 to 1.5 and (B) 20 to 95 mass % of one or more radically polymerizable compounds, wherein component (B) includes (B-1) one or more radically polymerizable monomers having no SiO unit in a structure thereof. This composition is capable of forming a transparent film that is excellent in adhesiveness without exhibiting stickiness and secondary adhesion.

Abstract: A water-absorbing polymer obtained from polymerization of (A) and (B) in aqueous medium wherein (A) is a phosphate-containing (meth)acrylic monomer and/or a salt thereof, and (B) is a monomer having one (meth)acrylic group within the molecule and/or a salt thereof that is different from component (A); and reacting the reaction product of (A) and (B) with (C) an organopolysiloxane having a (meth)acrylic group at both ends

Abstract: The present invention is a mono-functional branched organosiloxane compound that is liquid and shown by the following general formula (1) Ma-1MRa-2Db-1DRb-2Tc-1TRc-2Qd-1??(1) wherein M=R13SiO0.5, MR=R12R2SiO0.5, D=R12SiO, DR=R2R1SiO, T=R1SiO1.5, TR=R2SiO1.5, and Q=SiO2, where R1 represents a group selected from an alkyl group having 1 to 30 carbon atoms, and so on, R2 represents a hydrogen atom, and so on, a-1 represents an integer of 1 or more, b-1 and c-1 each represent an integer of 0 or more, and a-2, b-2, c-2, and d-1 each represent 0 or 1, provided that c-1, c-2, and d-1 are not simultaneously 0, a total of a-2, b-2, and c-2 is 1, and when b-1 is 0, a-1 is 2 or more and a total of c-1 and d-1 is 1 or more. There can be provided a novel mono-functional branched organosiloxane compound having a branched structure, and a method for producing the same.

Abstract: The present invention provides a silicone compound shown by the formula (1) and having a weight-average molecular weight in the range of 500 to 200,000, R1aR2bR3cR4dSiO(4-a-b-c-d)/2 (1), wherein R1 represents the same or different organic group, R2 represents a polyoxyalkylene group shown by —CmH2m—O—(C2H4O)g(C3H6O)hR6, R3 represents a branched type monovalent organosiloxane group shown by the following general formula (4), MoMRpDqDRrTsTRtQu (4), and R4 represents a monovalent organosiloxane group shown by the following general formula (5) or the general formula (6), MMRDv-1 (5), MwDv-1DRv-2TRv-3 (6). This provides a silicone compound which has excellent emulsification ability and emulsion stability to silicone oil, and can secure high temporal stability.

Abstract: A film-forming composition containing a polymer obtained by polymerizing (A) 5 to 80 mass % of a silicone resin having an R3SiO1/2 unit, an R2R?SiO1/2 unit, and an SiO2 unit, where R may be the same or different and represents a monovalent hydrocarbon group having 1 to 6 carbon atoms, and R? represents a —C3H6SH group, wherein a total amount of the R3SiO1/2 unit, R2R?SiO1/2 unit, and SiO2 unit is 80 mol % or more with respect to all structural units, and a mole ratio expressed by (sum of R3SiO1/2 unit and R2R?SiO1/2 unit)/(SiO2 unit) ranges from 0.5 to 1.5 and (B) 20 to 95 mass % of one or more radically polymerizable compounds, wherein component (B) includes (B-1) one or more radically polymerizable monomers having no SiO unit in a structure thereof. This composition is capable of forming a transparent film that is excellent in adhesiveness without exhibiting stickiness and secondary adhesion.

Abstract: The present invention provides a silicone compound shown by the formula (1) and having a weight-average molecular weight in the range of 500 to 200,000, R1aR2bR3cR4dSiO(4-a-b-c-d)/2 (1), wherein R1 represents the same or different organic group, R2 represents a polyoxyalkylene group shown by —CmH2m—O—(C2H4O)g(C3H6O)hR6, R3 represents a branched type monovalent organosiloxane group shown by the following general formula (4), MoMRpDqDRrTsTRtQu (4), and R4 represents a monovalent organosiloxane group shown by the following general formula (5) or the general formula (6), MMRDv-1 (5), MwDv-1DRv-2TRv-3 (6). This provides a silicone compound which has excellent emulsification ability and emulsion stability to silicone oil, and can secure high temporal stability.

Abstract: The present invention is a mono-functional branched organosiloxane compound that is liquid and shown by the following general formula (1) Ma-1MRa-2Db-1DRb-2Tc-1TRc-2Qd-1??(1) wherein M=R13SiO0.5, MR=R12R2SiO0.5, D=R12SiO, DR=R2R1SiO, T=R1SiO1.5, TR=R2SiO1.5, and Q=SiO2, where R1 represents a group selected from an alkyl group having 1 to 30 carbon atoms, and so on, R2 represents a hydrogen atom, and so on, a-1 represents an integer of 1 or more, b-1 and c-1 each represent an integer of 0 or more, and a-2, b-2, c-2, and d-1 each represent 0 or 1, provided that c-1, c-2, and d-1 are not simultaneously 0, a total of a-2, b-2, and c-2 is 1, and when b-1 is 0, a-1 is 2 or more and a total of c-1 and d-1 is 1 or more. There can be provided a novel mono-functional branched organosiloxane compound having a branched structure, and a method for producing the same.

Abstract: A water-absorbing polymer obtained from (A) a phosphate-containing (meth)acrylic monomer and/or a salt thereof, (B) a monomer having one (meth)acrylic group within the molecule and/or a salt thereof other than component (A), and (C) an organopolysiloxane having a (meth)acrylic group at both ends and related compositions.

Abstract: A gel paste composition including (A) a crosslinking organopolysiloxane and (B) a liquid oil, the crosslinking organopolysiloxane (A) being obtained by reacting an organohydrogenpolysiloxane shown by the following general formula (I) with a polyoxyalkylene compound shown by the following general formula (II) in the presence of a catalyst for hydrosilylation reaction, the component (A) containing polyoxyethylene units in an amount of 20 wt % or more. As a result, the gel paste composition that contains a crosslinking organopolysiloxane having improved compatibility with ethylhexyl methoxycinnamate and water, and thus exhibits excellent dispersibility when blended to a cosmetic thereby providing good feeling and cosmetic sustainability. R1aHbSiO(4-a-b)/2??(I) CcH2c-1O(C2H4O)d(C3H6O)eCcH2c-1??(II).

Abstract: A cosmetic has a polymer (A) having a content of an oxyalkylene unit and/or a glycerin unit of 0.5% by mass or more and under 5.0% by mass; and a polymer (B) having a content of an oxyethylene unit and/or a glycerin unit of 5.0% by mass or more and 20.0% by mass or less, the polymer (A) and the polymer (B) being a crosslinking organopolysiloxane polymer obtained by reacting organohydrogen polysiloxane having two or more hydrogen atoms bonded to a silicon atom in one molecule and polyoxyalkylene and/or polyglycerin having two or more aliphatic unsaturated bonds in one molecule, wherein the mass ratio of the polymer (A) to the polymer (B) is 5:95 to 60:40.

Abstract: A water-absorbing polymer obtained from (A) a phosphate-containing (meth)acrylic monomer and/or a salt thereof, (B) a monomer having one (meth)acrylic group within the molecule and/or a salt thereof other than component (A), and (C) an organopolysiloxane having a (meth)acrylic group at both ends and related compositions.

Abstract: A cosmetic has a polymer (A) having a content of an oxyalkylene unit and/or a glycerin unit of 0.5% by mass or more and under 5.0% by mass; and a polymer (B) having a content of an oxyethylene unit and/or a glycerin unit of 5.0% by mass or more and 20.0% by mass or less, the polymer (A) and the polymer (B) being a crosslinking organopolysiloxane polymer obtained by reacting organohydrogen polysiloxane having two or more hydrogen atoms bonded to a silicon atom in one molecule and polyoxyalkylene and/or polyglycerin having two or more aliphatic unsaturated bonds in one molecule, wherein the mass ratio of the polymer (A) to the polymer (B) is 5:95 to 60:40.

Abstract: The present invention provides a novel (meth)acrylic silicone-based graft copolymer that is preferably used for cosmetics and the like. The (meth)acrylic silicone-based graft copolymer of the present invention is a copolymer obtained by reacting the following radically polymerizable monomers (a) to (d): (a) a compound represented by the following general formula (I); (b) at least one selected from a compound represented by the following general formula (II) and a compound represented by the following formula (III); (c) a compound represented by the following general formula (IV); and (d) a compound represented by the following general formula (V), wherein the copolymer is dissolved at a level of 50 mass % or more in 99.5% ethanol at 25° C.

Abstract: The present invention provides a novel (meth)acrylic silicone-based graft copolymer that is preferably used for cosmetics and the like. The (meth)acrylic silicone-based graft copolymer of the present invention is a copolymer obtained by reacting the following radically polymerizable monomers (a) to (d): (a) a compound represented by the following general formula (I); (b) at least one selected from a compound represented by the following general formula (II) and a compound represented by the following formula (III); (c) a compound represented by the following general formula (IV); and (d) a compound represented by the following general formula (V), wherein the copolymer is dissolved at a level of 50 mass % or more in 99.5% ethanol at 25° C.

Abstract: A glycerin-modified silicone represented by the following formula (1): R1aR2bR3cSiO(4-a-b-c)/2 ??(1) wherein R1 is, independently, an unsubstituted or a partially halogen-substituted alkyl, aryl, aralkyl, aminoalkyl, or carboxyalkyl group, of 1 to 30 carbon atoms, R2 is, independently, an organosiloxyalkyl group represented by the following formula (3): wherein R5 is an unsubstituted or a partially halogen-substituted alkyl group of 1 to 30 carbon atoms, g is a number of from 1 to 5, and h is a number of from 1 to 500, R3 is a group represented by the following formula (4): wherein Q is a C2-20 divalent group, r is a number of from 1 to 200, s is a number of from 1 to 200, R6 is a hydrogen atom, a C1-30 alkyl group or an organic group of the formula: —(CO)—R7, wherein R7 is a C1-30 hydrocarbon group, and t is a number of from 1 to 10, a is a number of from 0.5 to 2.5, b is a number of from 0 to 1.5, and c is a number of from 0.001 to 1.5.