Abstract: The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.

Abstract: Presently described are microstructured articles such as a brightness enhancing film or optical turning film. The microstructured articles comprise a brightness enhancing polymerized structure comprising the reaction product of a composition comprising an organic component having at least one oligomeric urethane (meth)acrylate and surface modified silica nanoparticles.

Abstract: A durable optical film or element includes a polymerized structure having a microstructured surface and a plurality of surface modified colloidal nanoparticles of silica, zirconia, or mixtures thereof. Display devices including the durable microstructured film are also described.

Abstract: Polymerizable compositions comprising nanopartilces particularly useful for brightness enhancing films.

Abstract: Presently described are microstructured articles such as a brightness enhancing film or optical turning film. The microstructured articles comprise a brightness enhancing polymerized structure comprising the reaction product of a composition comprising an organic component having at least one oligomeric urethane (meth)acrylate and surface modified silica nanoparticles.

Abstract: Presently described are (e.g. brightness enhancing film) optical articles comprising the reaction product of a polymerizable resin and surface modified inorganic nanoparticles, methods of surface modifying inorganic nanoparticles, and surface modified inorganic nanoparticles. The surface treatment comprises at least one monocarboxylic acid having a refractive index of at least 1.50 and/or at least one monocarboxylic acid having a Mn of at least 200 g/mole and an ethylenically unsaturated group and/or at least one dicarboxylic acid.

Abstract: Microstructured optical films, assemblies of films including at least one microstructured optical film, and (e.g. illuminated) display devices including a single microstructured optical film or assembly.

Abstract: Polymerizable compositions comprising particularly useful for brightness enhancing films.

Abstract: Presently described are microstructured articles such as a brightness enhancing film or optical turning film comprising a polymerized structure comprising the reaction product of a polymerizable composition comprising an (A) organic component comprising (i) at least one monofunctional acrylic monomer selected from t-alkyl (meth)acrylates, N-substituted or N,N-disubstituted (meth)acrylamides, and C1-8 primary or secondary alkyl (meth)acrylate; (ii) at least one multifunctional (meth)acrylate or (meth)acrylamide monomer; (iii) optionally, at least one oligomeric (meth)acrylate; and (iv) at least one photoinitiator; and (B) at least 10 wt-% inorganic nanoparticles.

Abstract: Light management films and methods of making light management films are described. The light management films contain an optical layer that contains polymeric material and zirconia particles. The zirconia particles are colloidal, crystalline, substantially non-associated, and have a narrow size distribution.

Abstract: A durable optical film or element includes a polymerized structure having a microstructured surface and a plurality of surface modified colloidal nanoparticles of silica, zirconia, or mixtures thereof. Display devices including the durable microstructured film are also described.

Abstract: The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.

Abstract: The present invention includes ultraviolet curable compositions preferably containing discrete, crystalline zirconia nanoparticles with reactive, or copolymerizable, surface modification, in a polymerizable monomer/oligomer resin mixture. It is believed that copolymerizable surface modification provides a functional group that enables the functionalized particle to co-polmerize with the reactive monomers, oligomers, and crosslinkers in the formulation. Relative to surface modifation of the nanoparticles, acrylate functionality is preferred over methacrylate functionality. On the other hand, methacrylate functionality is preferred over non-reactive, or nonpolymerizable, functionality. As the nanocomposite cures, the resultant network is heavily crosslinked by selection of raw materials with substantial acrylate functionality.

Abstract: Polymerizable compositions comprising nanopartilces particularly useful for brightness enhancing films.

Abstract: Plastic articles can be coated with polymerizable compositions containing a vinyl-functional crosslinkable film former, a large amount of benzotriazole and a copolymerizable monomer that solubilizes the benzotriazole. The cured compositions help protect the article from UV exposure and other weathering effects.

Abstract: A durable optical film includes a polymerized optical film structure having a microstructured surface and a scratch contrast ratio value in a range of 1.0 to 1.65 or 1.0 to 1. 15. These durable optical films can include a plurality of nanoparticles and a rounded prism apexes microstructure.

Abstract: A durable optical film or element includes a polymerized structure having a microstructured surface and a plurality of surface modified colloidal nanoparticles of silica, zirconia, or mixtures thereof. Display devices including the durable microstructured film are also described.