Abstract: A terpolymer having units of Formula I wherein X is a C2-10 alkyl, C6-12 aryl, or C4-12 alkoxy radical, d is from about 3 to about 50, R is a fluoroalkyl radical Rf—(A)v—(B)w—, Rf is a fully fluorinated straight or branched aliphatic radical optionally interrupted by at least one oxygen atom, A is a divalent radical selected from —SO2N(R″)—, —CON(R″)—, —S—, or —SO2—, where R″ is H, or a C1-6 alkyl radical, B is a divalent linear hydrocarbon radical —CtH2t—, where t is 1 to 12, Y is a divalent radical —CH2—O—, u, v, and w are each independently zero or 1, R′ is hydrogen or methyl, e is from about 0.05 to about 10, M is hydrogen, alkali metal, or ammonium, and f is from about 5 to about 40, and its use to provide soil resistance and resistance to staining by acid dyes for fiber substrates is disclosed.

Abstract: A terpolymer having units of Formula I wherein X is a C2-10 alkyl, C6-12 aryl, or C4-12 alkoxy radical, d is from about 3 to about 50, R is a fluoroalkyl radical Rf—(A)v—(B)w—, Rf is a fully fluorinated straight or branched aliphatic radical optionally interrupted by at least one oxygen atom, A is a divalent radical selected from —SO2N(R″)—, —CON(R″)—, —S—, or —SO2—, where R″ is H, or a C1-6 alkyl radical, B is a divalent linear hydrocarbon radical —CtH2t—, where t is 1 to 12, Y is a divalent radical —CH2—O—, u, v, and w are each independently zero or 1, R′ is hydrogen or methyl, e is from about 0.05 to about 10, M is hydrogen, alkali metal, or ammonium, and f is from about 5 to about 40, and its use to provide soil resistance and resistance to staining by acid dyes for fiber substrates is disclosed.

Abstract: Polymers having pendant fluoroalkylsulfide side chains and processes for their preparation by nucleophilic displacement of halides in preformed polymers using fluoroalkylthiols are disclosed which provide oil and water repellency and antisoil properties to substrates.

Abstract: A terpolymer having units of Formula I ##STR1## wherein X is a C.sub.2-10 alkyl, C.sub.6-12 aryl, or C.sub.4-12 alkoxy radical,d is from about 3 to about 50,R is a fluoroalkyl radical R.sub.f (A).sub.v --(B).sub.w --,R.sub.f is a fully fluorinated straight or branched aliphatic radical optionally interrupted by at least one oxygen atom,A is a divalent radical selected from --SO.sub.2 N(R")--, --CON(R")--, --S--, or --SO.sub.2 --, where R" is H, or a C.sub.1-6 alkyl radical,B is a divalent linear hydrocarbon radical -CtH.sub.2 t-, where t is 1 to 12,Y is a divalent radical --CH.sub.2 --O--,u, v, and w are each independently zero or 1,R' is hydrogen or methyl,e is from about 0.05 to about 10,M is hydrogen, alkali metal, or ammonium, andf is from about 5 to about 40,and its use to provide soil resistance and resistance to staining by acid dyes for fiber substrates is disclosed.

Abstract: A polyamide fibrous substrate having deposited on it an amount of a composition effective to impart stain-resistance comprising a water-soluble or water-dispersible alpha-olefin/maleic anhydride polymer or a mixture of said polymers, and processes for preparing the substrates. The maleic anhydride polymer is used either in hydrolyzed form or in the form resulting from reacting it with a lower alkyl alcohol so as to form an alpha-olefin/maleic acid monalkyl ester polymer.

Abstract: A copolymer having units of Formula II: ##STR1## wherein M is H, alkali metal, anmonium cation, or a mixture thereof;N is OM or a mixture of OM, OR, and NR.sub.1 R.sub.2 in a molar ratio of (OM):(OR):(NR.sub.1 R.sub.2) of ?1-(e+f)!:e:f, wherein e and f are each independently 0 to 0.5, provided that (e+f) is less than 0.8;R, R.sub.1, and R.sub.2 are each independently H or a branched or straight chain C.sub.1-20 alkyl;Y is a C.sub.2-10 alkyl, C.sub.6-12 aryl, or C.sub.4-12 alkoxy;X is a fluorinated thiol radical;Z is H; andv and w are each a positive number such that the molar ratio of v to w is from about 0.4:1 to about 1.3:1 is disclosed.

Abstract: A composition of partial esters or thioesters formed from copolymers of maleic anhydride and perfluoroalkyl alcohols or perfluoroalkyl thiols is disclosed, and a process for providing soil and stain resistance to fibers by application of such partial esters or thioesters.

Abstract: The present invention comprises a process for providing soil resistance and resistance to staining by acid dyes to fibers and textiles by simultaneous or sequential application of a sulfonated phenol-formaldehyde condensation product and partial fluoroesters or fluorothioesters formed from copolymers of maleic anhydride and perfluoroalkyl alcohols or perfluoroalkyl thiols.

Abstract: A copolymer having units of Formula II: ##STR1## wherein M is H, alkali metal, ammonium cation, or a mixture thereof;N is OM or a mixture of OM, OR, and NR.sub.1 R.sub.2 in a molar ratio of (OM):(OR):(NR.sub.1 R.sub.2) of ?1-(e+f)!:e:f, wherein e and f are each independently 0 to 0.5, provided that (e+f) is less than 0.8;R, R.sub.1, and R.sub.2 are each independently H or a branched or straight chain C.sub.1-20 alkyl;Y is a C.sub.2-10 alkyl, C.sub.6-12 aryl, or C.sub.4-12 alkoxy;X is a fluorinated thiol radical;Z is H; andv and w are each a positive number such that the molar ratio of v to w is from about 0.4:1 to about 1.3:1 is disclosed.

Abstract: A composition which provides polyamide substrates with resistance to staining by acid dyes comprising(A) carboxylic acid-containing stain-resist polymers selected from:(i) methacrylic acid polymers, or(ii) hydrolyzed copolymers of maleic anhydride with ethylenically unsaturated aromatics, alpha-olefins, alkyl vinyl ethers or alkyl allyl ethers or(iii) mixtures of (i) and (ii),and(B) resole condensates prepared by reacting bis(hydroxyphenyl)sulfone which contains no sulfonate or carboxylate groups with formaldehyde in the presence of an alkali metal hydroxide, at a bis(hydroxyphenyl)sulfone resole resin:carboxylic acid-containing stain-resist polymer weight ratio in the range between about 1:20 and 2.5:1.0 is disclosed.

Abstract: A polyamide fibrous substrate having deposited on it an amount of a composition effective to impart stain-resistance comprising a water-soluble or water-dispersible alpha-olefin/maleic anhydride polymer or a mixture of said polymers, and processes for preparing the substrates. The maleic anhydride polymer is used either in hydrolyzed form or in the form resulting from reacting it with a lower alkyl alcohol so as to form an alpha-olefin/maleic acid monalkyl ester polymer.

Abstract: The present invention comprises a process for providing soil resistance and resistance to staining by acid dyes to fibers and textiles by simultaneous or sequential application of a sulfonated phenol-formaldehyde condensation product and partial fluoroesters or fluorothioesters formed from copolymers of maleic anhydride and perfluoroalkyl alcohols or perfluoroalkyl thiols.

Abstract: A stain-resist for polyamide textiles comprises blends of maleic anhydride/alpha-olefin polymers with sulfonated phenol-formaldehyde condensation products. The stain-resist blends are water-soluble at low pH, even in the absence of surfactant, and are strongly substantive and more resistant to yellowing than the condensation products.

Abstract: Polyamide substrates treated with stain-resists which comprise blends of maleic anhydride/alpha-olefin polymers and sulfonated phenol-formaldehyde condensation products. Some of the stain-resist blends are water-soluble at low pH, even in the absence of surfactant, and are strongly substantive and more resistant to yellowing than the condensation products.

Abstract: Polyamide fibrous substrates which resist staining by acid dyes and discoloration upon exposure to UV light, and processes for preparing the same which comprise applying, at pH 2 to 10, a base-catalyzed condensation product formed by the reaction of a bis(hydroxyphenyl)sulfone with formaldehyde to give a product known as a resole.

Abstract: Polyamide fibrous substrates which resist staining by acid dyes and discoloration upon exposure to UV light, and processes for preparing the same which comprise applying, at pH 2 to 10, a base-catalyzed condensation product formed by the reaction of a bis(hydroxyphenyl)sulfone with formaldehyde to give a product known as a resole.

Abstract: Processes and compositions which at the same time impart resistance to staining of polyamide substrates caused by acid dyes and improved durability to shampooing and resistance to yellowing caused by exposure to UV and/or NO.sub.x, whereby the stain-resist performance of hydrolyzed maleic anhydride copolymers can be dramatically improved either by co-applying the stain with a water-dispersed epoxy resin or by post-treatment of the stain-resist-treated polyamide fiber substrate with a water-dispersed epoxy resin.

Abstract: Process for imparting to polyamide substrates resistance to staining by acid dyes which is durable to shampooing and resistance to yellowing caused by exposure to UV and/or NO.sub.x, comprising applying to said substrate (A) one or more epoxy resins and (B) a polymeric stain-resist agent consisting essentially of (i) copolymers containing more than 75 weight percent methacrylic acid and less than 25 weight percent of one or more other ethylenically unsaturated monomers, or (ii) polymers prepared by polymerizing (a) methacrylic acid or (b) mixtures of methacrylic acid and one or more other ethylenically unsaturated monomers, in the presence of a sulfonated hydroxyaromatic-formaldehyde condensation product.

Abstract: A polyamide fibrous substrate having deposited on it an amount of a composition effective to impart stain-resistance comprising a water-soluble or water-dispersible maleic anhydride/allyl ether or vinyl ether polymer or a mixture of said polymers, and processes for preparing the substates. The maleic anhydride polymer is used either in hydrolyzed form.

Abstract: A stain-resist agent for polyamide fibers, its preparation and use are disclosed. The stain-resist agent is the condensation product of bis-hydroxyphenylsulfone with 0.5 to 1.0 mole of formaldehyde, per mole of bis-hydroxyphenylsulfone, and 0.15 to 1.5 moles of mercaptoacetic acid or mercaptosuccinic acid per mole of bis-hydroxyphenylsulfone and ammonium hydroxide or an alkali metal hydroxide in an amount sufficient to neutralize the mercapto acid plus an excess of about 0.2 to 0.6 mole of hydroxide per mole of bis-hydroxyphenylsulfone. Generally the reaction is carried out at 110.degree. to 180.degree. C. for 1 to 48 hours, with 130.degree. to 160.degree. C. for 3 to 24 hours being preferred. The product is applied to the polyamide fibers from an aqueous bath to provide a coating of 0.5 to 5.0 wt % stain-resist agent. The stain-resist is applied in the presence of a magnesium salt.