Patents by Inventor Enrique A. Reyes

Enrique A. Reyes has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9193899
    Abstract: Alkali metal ions may lead to the production of insoluble materials during the course of stimulating a subterranean formation, particularly when acidizing a siliceous formation or a formation containing a siliceous material. Alkali metal ions may be sequestered using an alkali metal complexing agent in order to reduce their propensity toward forming insoluble materials in a subterranean formation. Methods for stimulating a subterranean formation can comprise: providing a treatment fluid that comprises an alkali metal complexing agent comprising a cyclic polyether having between 3 and 6 ether oxygen atoms present therein, and hydrofluoric acid, a hydrofluoric acid-generating compound, or any combination thereof; and introducing the treatment fluid into a subterranean formation.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: November 24, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith
  • Publication number: 20150329764
    Abstract: Treatment fluids for use in subterranean formations, particularly sandstone and other siliceous formations, may contain a source of fluoride ions to aid in mineral dissolution. In some cases, it may be desirable to generate the fluoride ions from a fluoride ion precursor, particularly a hydrofluoric acid precursor, such as a boron trifluoride complex. Methods described herein can comprise providing a treatment fluid that comprises an aqueous base fluid, a boron trifluoride complex, and a chelating agent composition, and introducing the treatment fluid into a subterranean formation.
    Type: Application
    Filed: July 28, 2015
    Publication date: November 19, 2015
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Patent number: 9127194
    Abstract: Treatment fluids for use in subterranean formations, particularly sandstone and other siliceous formations, may contain a source of fluoride ions to aid in mineral dissolution. In some cases, it may be desirable to generate the fluoride ions from a fluoride ion precursor, particularly a hydrofluoric acid precursor, such as a boron trifluoride complex. Methods for treating a subterranean formation can comprise providing a treatment fluid that comprises an aqueous base fluid, a boron trifluoride complex, and a chelating agent composition, and introducing the treatment fluid into a subterranean formation.
    Type: Grant
    Filed: January 20, 2012
    Date of Patent: September 8, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Patent number: 9120964
    Abstract: Treatment fluids containing biodegradable chelating agents can be used in various treatment methods. The methods can comprise providing a treatment fluid that comprises an aqueous base fluid and a chelating agent composition, and introducing the treatment fluid into at least a portion of a subterranean formation. The treatment fluids can also be used for treatment of pipes or tubing such as, for example, well bore pipes or tubing penetrating a subterranean formation and above-ground pipelines. Illustrative biodegradable chelating agents include, but are not limited to, glutamic acid diacetic acid, methylglycine diacetic acid, ?-alanine diacetic acid, S,S-ethylenediaminedisuccinic acid, iminodisuccinic acid, hydroxyiminodisuccinic acid, any salt thereof, any derivative thereof, and any combination thereof. The treatment fluids can optionally comprise an acid, which can include hydrofluoric acid or a hydrofluoric acid generating compound.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: September 1, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Thomas D. Welton
  • Publication number: 20150211345
    Abstract: Chelating agents may be used to mitigate the presence of metal ions in a subterranean formation, thereby decreasing the likelihood of the metal ions forming damaging insoluble compounds within the subterranean formation. Methods for treating a subterranean formation can comprise: providing a treatment fluid comprising an aqueous carrier fluid and a chelating agent comprising hydroxyiminodisuccinic acid or any salt thereof; introducing the treatment fluid into a subterranean formation comprising a carbonate mineral; and complexing a metal ion in the subterranean formation with the chelating agent.
    Type: Application
    Filed: April 6, 2015
    Publication date: July 30, 2015
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Aaron M. Beuterbaugh, Alyssa Lynn LaBlanc
  • Patent number: 9027647
    Abstract: Methods for treating a subterranean formation can include: providing a treatment fluid that comprises: an aqueous base fluid; a hydrofluoric acid source selected from the group consisting of hydrofluoric acid, a hydrofluoric acid generating compound, and a combination thereof; and a biodegradable chelating agent comprising one of the following selected from the group consisting of: glutamic acid diacetic acid, a glutamic acid diacetic acid salt, a derivative thereof, and a combination thereof. The treatment fluid may then be introduced into at least a portion of a subterranean formation.
    Type: Grant
    Filed: March 18, 2011
    Date of Patent: May 12, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Thomas D. Welton
  • Patent number: 9004168
    Abstract: Treatment fluids comprising a silicate complexing agent can be used in conjunction with acidizing a subterranean formation that contains a siliceous material. Inclusion of the silicate complexing agent in the treatment fluids may eliminate or reduce the production of insoluble fluorosilicates and aluminosilicates that can occur when an acidizing operation is conducted. Methods for treating a subterranean formation can comprise: introducing to a subterranean formation a treatment fluid that comprises a silicate complexing agent comprising a tertiary amine compound, a functionalized pyridine compound, any salt thereof, or any combination thereof; and hydrofluoric acid, a hydrofluoric acid-generating compound, or any combination thereof.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: April 14, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith
  • Publication number: 20150038645
    Abstract: Biomimetic adhesive compositions can be used in various aspects of subterranean treatment operations. Methods for treating a subterranean formation can comprise: providing an adhesive composition that comprises a first polymer comprising a plurality of monomers that comprise a phenolic moiety, a biopolymer that is crosslinkable with the first polymer, a crosslinking agent, and an oxidizing agent; introducing the adhesive composition into a subterranean formation; and forming a coacervate-bound surface in the subterranean formation by crosslinking the first polymer.
    Type: Application
    Filed: October 22, 2014
    Publication date: February 5, 2015
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Pinmanee Boontheung, Narongsak Tonmukayakul
  • Patent number: 8904853
    Abstract: Methods comprising: placing particulates in a test column; adding a fluid medium comprising a salt solution to the test column; placing the column under test conditions, wherein the test conditions comprise target temperature and target pressure; maintaining test conditions for a target test duration; and, analyzing the particulates. Some methods also measure a permeability value of the column after placing particulates in a test column and before placing the column under test conditions; continuously flow the salt solution through the particulates during the test; measure a permeability value after maintaining the test conditions for the target test duration; and, calculate a retained permeability value.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: December 9, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Jimmie D. Weaver, Richard D. Rickman, Hongyu Luo
  • Patent number: 8893790
    Abstract: Biomimetic adhesive compositions can be used in various aspects of subterranean treatment operations. Methods for treating a subterranean formation can comprise: providing an adhesive composition that comprises a first polymer comprising a plurality of monomers that comprise a phenolic moiety, a biopolymer that is crosslinkable with the first polymer, a crosslinking agent, and an oxidizing agent; introducing the adhesive composition into a subterranean formation; and forming a coacervate-bound surface in the subterranean formation by crosslinking the first polymer.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: November 25, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Pinmanee Boontheung, Narongsak Tonmukayakul
  • Patent number: 8887805
    Abstract: Trivalent-ion chelating agents may be useful in mitigating the formation aluminum and ferric precipitates in subterranean formations during acidizing operations. An acidizing operation may include introducing an acidizing fluid into a wellbore penetrating a subterranean formation, the acidizing fluid comprising an aqueous fluid, an acid source, and a trivalent-ion chelating agent, e.g., hydroxamates, 6,7-dihydroxyquinoline, 3-hydroxy-4-pyridinones, and any combination thereof. In some instances, trivalent-ion chelating agents with a pKa of less than about 7 may be particularly useful in acidizing operations.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: November 18, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Patent number: 8881811
    Abstract: Treatments and compounds for use in subterranean formations where surfaces may be subject to silica scale build-up. Certain embodiments pertain to utilizing silica scale control additives with remediation and stimulation treatments. One example of a suitable method of treatment includes providing an acidic treatment fluid comprising: a base fluid, an acid, and a silica scale control additive; contacting at least a portion of a subterranean formation with the acidic treatment fluid; and allowing the acidic treatment fluid to interact with silica scale buildup in the subterranean formation so that at least a portion of the silica scale buildup is removed.
    Type: Grant
    Filed: November 1, 2010
    Date of Patent: November 11, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Publication number: 20140262289
    Abstract: Acidizing fluids may be formulated to minimize the detrimental effects of precipitation during an acidizing operation by promoting production of precipitates from a subterranean formation. Methods for acidizing a subterranean formation can comprise: providing an acidizing fluid comprising a stabilized microemulsion carrier fluid, a chelating agent, and an acid source; introducing the acidizing fluid into a subterranean formation; at least partially dissolving a surface in the subterranean formation with the acidizing fluid, thereby forming a spent fluid; and producing the spent fluid from the subterranean formation.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith
  • Patent number: 8796187
    Abstract: Composition comprising a plurality of particulates wherein at least some particulates are at least partially covered with a coating that impedes the intrusion of water into the particulates; and, a silica scale control additive, wherein the silica scale control additive is capable of suppressing silica scale build-up proximate the plurality of particulates. Some compositions further include a treatment fluid wherein and the silica scale control additive are present in the treatment fluid.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: August 5, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
  • Patent number: 8794322
    Abstract: Treatments and compounds can be useful in subterranean formations where particulates and/or surfaces may be subject to silica scale build-up. Certain embodiments pertain to utilizing silica scale control additives with particulate packs. Of these, certain methods may treat particulate packs in a subterranean formation with silica scale control additives, certain methods may combine silica scale control additives with particulates prior to formation of a particulate pack, and certain compounds may provide the features of both silica scale control additives and particulates.
    Type: Grant
    Filed: October 6, 2009
    Date of Patent: August 5, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
  • Publication number: 20140116696
    Abstract: Trivalent-ion chelating agents may be useful in mitigating the formation aluminum and ferric precipitates in subterranean formations during acidizing operations. An acidizing operation may include introducing an acidizing fluid into a wellbore penetrating a subterranean formation, the acidizing fluid comprising an aqueous fluid, an acid source, and a trivalent-ion chelating agent, e.g., hydroxamates, 6,7-dihydroxyquinoline, 3-hydroxy-4-pyridinones, and any combination thereof. In some instances, trivalent-ion chelating agents with a pKa of less than about 7 may be particularly useful in acidizing operations.
    Type: Application
    Filed: October 30, 2012
    Publication date: May 1, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Publication number: 20140048261
    Abstract: Methods for mitigating precipitation during matrix acidizing of a subterranean formation. The methods generally comprise introducing a treatment fluid into a subterranean formation. The treatment fluid comprises a chelating agent; a hydrofluoric acid source; and a stabilizing compound. The stabilizing compound has two or more quaternized amine groups. In some cases the treatment fluid further comprises alkali metal ions.
    Type: Application
    Filed: August 17, 2012
    Publication date: February 20, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Publication number: 20130312961
    Abstract: Biomimetic adhesive compositions can be used in various aspects of subterranean treatment operations. Methods for treating a subterranean formation can comprise: providing an adhesive composition that comprises a first polymer comprising a plurality of monomers that comprise a phenolic moiety, a biopolymer that is crosslinkable with the first polymer, a crosslinking agent, and an oxidizing agent; introducing the adhesive composition into a subterranean formation; and forming a coacervate-bound surface in the subterranean formation by crosslinking the first polymer.
    Type: Application
    Filed: May 23, 2012
    Publication date: November 28, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Pinmanee Boontheung, Narongsak Tonmukayakul
  • Publication number: 20130269936
    Abstract: Treatment fluids comprising a silicate complexing agent can be used in conjunction with acidizing a subterranean formation that contains a siliceous material. Inclusion of the silicate complexing agent in the treatment fluids may eliminate or reduce the production of insoluble fluorosilicates and aluminosilicates that can occur when an acidizing operation is conducted. Methods for treating a subterranean formation can comprise: providing a treatment fluid that comprises a silicate complexing agent comprising a tertiary amine compound, a functionalized pyridine compound, any salt thereof, or any combination thereof; and hydrofluoric acid, a hydrofluoric acid-generating compound, or any combination thereof; and introducing the treatment fluid into a subterranean formation.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 17, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith
  • Publication number: 20130269944
    Abstract: Alkali metal ions may lead to the production of insoluble materials during the course of stimulating a subterranean formation, particularly when acidizing a siliceous formation or a formation containing a siliceous material. Alkali metal ions may be sequestered using an alkali metal complexing agent in order to reduce their propensity toward forming insoluble materials in a subterranean formation. Methods for stimulating a subterranean formation can comprise: providing a treatment fluid that comprises an alkali metal complexing agent comprising a cyclic polyether having between 3 and 6 ether oxygen atoms present therein, and hydrofluoric acid, a hydrofluoric acid-generating compound, or any combination thereof; and introducing the treatment fluid into a subterranean formation.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 17, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith