Abstract: Process for producing a titanium alloy material, such as a titanium aluminum alloy, are provided. The process includes reduction of TiCl4), which includes a titanium ion (Ti4+), through intermediate ionic states (e.g., Ti3+) to Ti2+, which may then undergo a disproportionation reaction to form the titanium aluminum alloy.

Abstract: A method of making a hollow metal component comprising the steps of providing at least one core comprising a first side and a reverse side; utilizing a first metal spray process to apply at least one metal or metal alloy to the first side of the core, resulting in a partially-formed structure comprising a first side and a reverse side; and utilizing a second metal spray process to apply at least one metal or metal alloy to the reverse sides of the partially-formed structure and the core, resulting in a rough structure. A hollow metal component comprising a first side having interior and exterior surfaces, a reverse side having interior and exterior surfaces, the interior surfaces of the first side and the reverse side defining at least one cavity. The component is integrally formed and has regions comprising relatively different material compositions, the regions having gradual transitions of materials therebetween.

Abstract: Process for producing a titanium alloy material, such as a titanium aluminum alloy, are provided. The process includes reduction of TiCl4, which includes a titanium ion (Ti4+), through intermediate ionic states (e.g., Ti3+) to Ti2+, which may then undergo a disproportionation reaction to form the titanium aluminum alloy.

Abstract: A method for preparing an article of a base metal alloyed with an alloying element includes the steps of preparing a compound mixture by the steps of providing a chemically reducible nonmetallic base-metal precursor compound of a base metal, providing a chemically reducible nonmetallic alloying-element precursor compound of an alloying element, and thereafter mixing the base-metal precursor compound and the alloying-element precursor compound to form a compound mixture. The compound mixture is thereafter reduced to a metallic alloy, without melting the metallic alloy. The step of preparing or the step of chemically reducing includes the step of adding an other additive constituent. The metallic alloy is thereafter consolidated to produce a consolidated metallic article, without melting the metallic alloy and without melting the consolidated metallic article.

Abstract: A method of making a hollow metal component comprising the steps of providing at least one core comprising a first side and a reverse side; utilizing a first metal spray process to apply at least one metal or metal alloy to the first side of the core, resulting in a partially-formed structure comprising a first side and a reverse side; and utilizing a second metal spray process to apply at least one metal or metal alloy to the reverse sides of the partially-formed structure and the core, resulting in a rough structure. A hollow metal component comprising a first side having interior and exterior surfaces, a reverse side having interior and exterior surfaces, the interior surfaces of the first side and the reverse side defining at least one cavity. The component is integrally formed and has regions comprising relatively different material compositions, the regions having gradual transitions of materials therebetween.

Abstract: A method for manufacturing a three-dimensional part. The method includes: performing partial densification processing on loose machining powder, to form a densified and sealed enclosure, where there is still loose machining powder accommodated inside the enclosure; and performing overall densification processing on the enclosure and the machining powder inside the enclosure, so as to implement metallurgical bonding between the machining powder inside the enclosure and the enclosure during the densification, thereby forming a target three-dimensional part.

Abstract: An article includes a microscale composite material having a matrix with titanium boride particles configured to form an insert in a metallic mass being comprised of material other than a consolidated titanium-based metallic composition having titanium particles.

Abstract: A method for preparing an article of a base metal alloyed with an alloying element includes the steps of preparing a compound mixture by the steps of providing a chemically reducible nonmetallic base-metal precursor compound of a base metal, providing a chemically reducible nonmetallic alloying-element precursor compound of an alloying element, and thereafter mixing the base-metal precursor compound and the alloying-element precursor compound to form a compound mixture. The compound mixture is thereafter reduced to a metallic alloy, without melting the metallic alloy. The step of preparing or the step of chemically reducing includes the step of adding an other additive constituent. The metallic alloy is thereafter consolidated to produce a consolidated metallic article, without melting the metallic alloy and without melting the consolidated metallic article.

Abstract: A method for preparing an article of a base metal alloyed with an alloying element includes the steps of preparing a compound mixture by the steps of providing a chemically reducible nonmetallic base-metal precursor compound of a base metal, providing a chemically reducible nonmetallic alloying-element precursor compound of an alloying element, and thereafter mixing the base-metal precursor compound and the alloying-element precursor compound to form a compound mixture. The compound mixture is thereafter reduced to a metallic alloy, without melting the metallic alloy. The step of preparing or the step of chemically reducing includes the step of adding an other additive constituent. The metallic alloy is thereafter consolidated to produce a consolidated metallic article, without melting the metallic alloy and without melting the consolidated metallic article.

Abstract: A metallic article is prepared by first furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively containing the constituent elements of the metallic article in their respective constituent-element proportions. The constituent elements together form a titanium-base alloy having a stable-oxide-forming additive element therein, such as magnesium, calcium, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, and mixtures thereof. The stable-oxide-forming additive element forms a stable oxide in a titanium-based alloy. At least one additive element is present at a level greater than its room-temperature solid solubility limit in the titanium-base alloy. The precursor compounds are chemically reduced to produce an alloy material, without melting the alloy material. The alloy material may be consolidated.

Abstract: A compositionally graded gas turbine disk is made by preparing a rotationally symmetric radially inner segment of a gas turbine disk preform, rotating the inner segment about a central axis, spray applying a radially outer-segment material onto the radially inner segment as it rotates about the central axis, preferably achieving a gradual transition in composition, and thereafter further processing the gas turbine disk preform to produce the compositionally graded gas turbine disk.

Abstract: An elongated rod assembly is made by preparing a plurality of rods. Each rod is prepared by the steps of furnishing at least one nonmetallic precursor compound, thereafter chemically reducing the precursor compounds to produce the metallic material, and thereafter consolidating the metallic material to form the rod, wherein the rod has a rod length equal to the assembly length. The rods are bundled together to form a bundled rod assembly. The rod assembly may be used as a consumable feedstock in a melting-and-casting operation.

Abstract: An article made of constituent elements is prepared by furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively contain the constituent elements. The constituent elements include a titanium-base metallic composition, boron present at a level greater than its room-temperature solid solubility limit, and, optionally, a stable-oxide-forming additive element present at a level greater than its room-temperature solid solubility limit. The precursor compounds are chemically reduced to produce a material comprising a titanium-base metallic composition having titanium boride particles therein, without melting the titanium-base metallic composition. The titanium-base metallic composition having the titanium boride particles therein is consolidated without melting.

Abstract: A metallic article is prepared by first furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively containing the constituent elements of the metallic article in their respective constituent-element proportions. The constituent elements together form a titanium-base alloy having a stable-oxide-forming additive element therein, such as magnesium, calcium, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, and mixtures thereof. The stable-oxide-forming additive element forms a stable oxide in a titanium-based alloy. At least one additive element is present at a level greater than its room-temperature solid solubility limit in the titanium-base alloy. The precursor compounds are chemically reduced to produce an alloy material, without melting the alloy material. The alloy material may be consolidated.

Abstract: An article is prepared by furnishing a plurality of powder particle substrates made of a substrate metal, providing a nonmetallic precursor of a metallic coating material, wherein the metallic coating material comprises an alloying element that is thermophysically melt incompatible with the substrate metal, contacting the powder particle substrates with the nonmetallic precursor, chemically reducing the nonmetallic precursor to form coated powder particles comprising the powder particle substrates having a surface-enriched layer of the metallic coating material thereon without melting the powder particle substrates, and processing the coated powder particles to form the article, without melting the powder particle substrates.

Abstract: A metallic article is produced by furnishing one or more nonmetallic precursor compound comprising the metallic constituent element(s), and chemically reducing the nonmetallic precursor compound(s) to produce an initial metallic particle, preferably having a size of no greater than about 0.070 inch, without melting the initial metallic particle. The initial metallic particle is thereafter melted and solidified to produce the metallic article. By this approach, the incidence of chemical defects in the metal article is minimized. The melted-and-solidified metal may be used in the as-cast form, or it may be converted to billet and further worked to the final form.

Abstract: A metallic article is produced by furnishing one or more nonmetallic precursor compound comprising the metallic constituent element(s), and chemically reducing the nonmetallic precursor compound(s) to produce an initial metallic particle, preferably having a size of no greater than about 0.070 inch, without melting the initial metallic particle. The initial metallic particle is thereafter melted and solidified to produce the metallic article. By this approach, the incidence of chemical defects in the metal article is minimized. The melted-and-solidified metal may be used in the as-cast form, or it may be converted to billet and further worked to the final form.

Abstract: An article made of a metallic material having its constituent elements is made by furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively include the constituent elements of the metallic material in their respective constituent-element proportions. The precursor compounds are chemically reduced to produce particles comprising the metallic material, without melting the precursor compounds and without melting the metallic material. The particles may be consolidated into a rod, which may be used as a welding rod in a welding operation. Alternatively, the nonmetallic precursor compounds may be consolidated prior to the chemical reduction.

Abstract: A metallic article made of metallic constituent elements is fabricated from a mixture of nonmetallic precursor compounds of the metallic constituent elements. The mixture of nonmetallic precursor compounds is chemically reduced to produce an initial metallic material, without melting the initial metallic material. The initial metallic material is consolidated to produce a consolidated metallic article, without melting the initial metallic material and without melting the consolidated metallic article.

Abstract: A metallic article is produced by furnishing one or more nonmetallic precursor compound comprising the metallic base nickel, cobalt, iron, iron-nickel, or iron-nickel-cobalt, and at least one alloying element. The nonmetallic precursor compound(s) are chemically reduced to produce an initial metallic particle without melting the initial metallic particle. The initial metallic particle is thereafter melted and solidified to produce the metallic article. The melted-and-solidified metal may be used in the as-cast form, or it may be converted to billet and further worked to the final form.