Patents by Inventor Eric B. Sirota

Eric B. Sirota has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240068132
    Abstract: Nucleation enhancement and/or growth rate improvement of mesophase in pitch compositions derived from hydrocarbon feedstocks can be achieved by: reacting in a reaction zone a blend comprising an isotropic feed and a seeding agent, to produce a reacted pitch having a mesophase content of about 10 vol % to 100 vol %, based on the total volume of the reacted pitch, and a softening point (Tsp) below 400° C.; wherein the seeding agent is about 50 wt % or less, based on the total weight of the blend; wherein the seeding agent has a mesophase content of about 0.01 vol % to 100 vol %, based on the total volume of the seeding agent.
    Type: Application
    Filed: November 10, 2021
    Publication date: February 29, 2024
    Applicant: ExxonMobil Technology and Engineering Company
    Inventors: Manesh Gopinadhan, Stuart E. Smith, Nicole M. Callen, Clarence E. Chase, Kazem V. Edmond, Srinivasan Rajagopalan, Eric B. Sirota, Daniel J. Ryan
  • Patent number: 11598758
    Abstract: Systems and methods are provided for determining an asphaltene solubility distribution for a petroleum sample and/or other hydrocarbon sample. A vessel for performing the method can include both packing material(s) and sidewall(s) that correspond to substantially inert materials. The vessel can initially contain a precipitating solvent suitable for causing precipitation of asphaltenes from a hydrocarbon sample. Examples of a precipitating solvents can correspond to n-heptane, toluene, and mixtures of n-heptane and toluene. The petroleum sample is then introduced into the vessel, along with a carrier solvent. The volume of the precipitating solvent can be large relative to the sample, so that the solubility of asphaltenes in the sample becomes dependent on the properties of the precipitating solvent. If asphaltenes are precipitated, the asphaltenes can be washed out of the column using a dissolution solvent.
    Type: Grant
    Filed: July 16, 2020
    Date of Patent: March 7, 2023
    Assignee: ExxonMobil Technology and Engineering Company
    Inventors: Eric B. Sirota, Bridget E. Lang, Birbal Chawla
  • Publication number: 20210018477
    Abstract: Systems and methods are provided for determining an asphaltene solubility distribution for a petroleum sample and/or other hydrocarbon sample. A vessel for performing the method can include both packing material(s) and sidewall(s) that correspond to substantially inert materials. The vessel can initially contain a precipitating solvent suitable for causing precipitation of asphaltenes from a hydrocarbon sample. Examples of a precipitating solvents can correspond to n-heptane, toluene, and mixtures of n-heptane and toluene. The petroleum sample is then introduced into the vessel, along with a carrier solvent. The volume of the precipitating solvent can be large relative to the sample, so that the solubility of asphaltenes in the sample becomes dependent on the properties of the precipitating solvent. If asphaltenes are precipitated, the asphaltenes can be washed out of the column using a dissolution solvent.
    Type: Application
    Filed: July 16, 2020
    Publication date: January 21, 2021
    Inventors: Eric B. Sirota, Bridget E. Lang, Birbal Chawla
  • Publication number: 20190382664
    Abstract: Methods are provided for reducing or minimizing the temperature dependence of a pitch feed or fraction for use in carbon fiber production, such as a mesophase pitch feed or fraction or an isotropic pitch feed or fraction. A pitch sample can be characterized to determine a characteristic temperature and a characteristic viscosity for the sample. One or more solvent extraction processes can also be performed on the pitch and/or the extract and raffinate fractions formed by the solvent extraction(s). The resulting raffinate and extract fractions are then used to form a modified pitch fraction with a T0 value that is lower than the T0 value of the original pitch. The modified pitch fraction can optionally also have a different ?inf value relative to the original pitch.
    Type: Application
    Filed: May 29, 2019
    Publication date: December 19, 2019
    Inventors: Stuart E. Smith, Eric B. Sirota, Stephen H. Brown
  • Patent number: 10329427
    Abstract: Methods are provided for predicting the properties of an asphalt fraction that contains two or more asphalt components based on measurements of the viscosity versus temperature profile for the components of the asphalt fraction. The viscosity versus temperature profile for each component can be used to determine characteristic (such as limiting) values for the viscosity and temperature for a component. Based on this ability to determine characteristic values for an asphalt blend based on the properties of individual blend components, appropriate blends of asphalts can be selected in order to arrive at an asphalt blend with desired properties.
    Type: Grant
    Filed: May 21, 2018
    Date of Patent: June 25, 2019
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventor: Eric B. Sirota
  • Publication number: 20180265703
    Abstract: Methods are provided for predicting the properties of an asphalt fraction that contains two or more asphalt components based on measurements of the viscosity versus temperature profile for the components of the asphalt fraction. The viscosity versus temperature profile for each component can be used to determine characteristic (such as limiting) values for the viscosity and temperature for a components. Examples of characteristic values for an asphalt component are the asymptotic values of viscosity at infinite temperature (?inf) and the finite temperature at which the viscosity diverges (T0). Once these characteristic values are determined, the characteristic values for each component can be combined in a weighted average to determine ?inf and T0 for the asphalt blend.
    Type: Application
    Filed: May 21, 2018
    Publication date: September 20, 2018
    Inventor: Eric B. Sirota
  • Patent number: 10005907
    Abstract: Methods are provided for predicting the properties of an asphalt fraction that contains two or more asphalt components based on measurements of the viscosity versus temperature profile for the components of the asphalt fraction. The viscosity versus temperature profile for each component can be used to determine characteristic (such as limiting) values for the viscosity and temperature for a component. Based on this ability to determine characteristic values for an asphalt blend based on the properties of individual blend components, appropriate blends of asphalts can be selected in order to arrive at an asphalt blend with desired properties.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: June 26, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventor: Eric B. Sirota
  • Patent number: 9725657
    Abstract: Provided is a process for cracking a hydrocarbon feedstock. The process having the steps of (a) continuously passing the feedstock through a vapor-liquid separator in which the feedstock is separated into a volatile stream and a non-volatile stream; (b) continuously passing the non-volatile stream to a cracker; and (c) continuously recycling a portion of the volatile stream to the feedstock. There is also an apparatus for cracking a hydrocarbon feedstock.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: August 8, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Eric B. Sirota
  • Patent number: 9175240
    Abstract: Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include from about 35 wt. % to about 60 wt. % of units derived from ethylene and at least 1.0 wt. % of one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers are substantially amorphous and have a polydispersity index of about 2.8 or less.
    Type: Grant
    Filed: October 12, 2012
    Date of Patent: November 3, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Rainer Kolb, Sudhin Datta, Liehpao O. Farng, Vera Minak-Bernero, Eric B. Sirota, Thomas T. Sun, Mun-Fu Tse
  • Publication number: 20150191598
    Abstract: Methods are provided for predicting the properties of an asphalt fraction that contains two or more asphalt components based on measurements of the viscosity versus temperature profile for the components of the asphalt fraction. The viscosity versus temperature profile for each component can be used to determine characteristic (such as limiting) values for the viscosity and temperature for a components. Examples of characteristic values for an asphalt component are the asymptotic values of viscosity at infinite temperature (?inf) and the finite temperature at which the viscosity diverges (T0). Once these characteristic values are determined, the characteristic values for each component can be combined in a weighted average to determine ?inf and T0 for the asphalt blend.
    Type: Application
    Filed: December 19, 2014
    Publication date: July 9, 2015
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventor: Eric B. Sirota
  • Patent number: 9006161
    Abstract: Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: April 14, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, JoAnn M. Canich, Liehpao O. Farng, Rainer Kolb, Vera Minak-Bernero, Eric B. Sirota, Thomas T. Sun, Mun F. Tse, Manika Varma-Nair
  • Patent number: 8999907
    Abstract: Polymeric compositions and methods for making and using the same are provided. The polymeric composition can include a first ethylene-based copolymer and a second ethylene-based copolymer. The first ethylene-based copolymer can have a weight percent of ethylene-derived units based on a weight of the polymeric composition (EA) ranging from about 35 wt % to about 52 wt % and a weight-average molecular weight (MwA) of less than or equal to 130,000. The second ethylene-based copolymer can have a weight percent of ethylene-derived units based on the weight of the polymeric composition (EB) ranging from about 65 wt % to about 85 wt % and a weight-average molecular weight (MwB) of less than 130,000.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: April 7, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Rainer Kolb, Liehpao Oscar Farng, Vera Minak-Bernero, Mun Fu Tse, Eric B. Sirota, Diana Smirnova
  • Publication number: 20150027849
    Abstract: The present invention relates to methods and systems for removing polar molecule contaminants from a refinery stream in connection with the processing of hydrocarbon fluids, chemicals, whole crude oils, blends and fractions in refineries and chemical plants that include adding high surface energy and/or high surface area nanoparticle compounds to a refinery stream to remove the polar molecule contaminants.
    Type: Application
    Filed: October 6, 2014
    Publication date: January 29, 2015
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Mohsen Shahmirzadi Yeganeh, Peter W. Jacobs, Ian Alfred Cody, Steven Webster Levine, Eric B. Sirota, Ramesh Gupta, Walter Weissman
  • Patent number: 8852427
    Abstract: The present invention relates to methods and systems for removing polar molecule contaminants from a refinery stream in connection with the processing of hydrocarbon fluids, chemicals, whole crude oils, blends and fractions in refineries and chemical plants that include adding high surface energy and/or high surface area nanoparticle compounds to a refinery stream to remove the polar molecule contaminants.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: October 7, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Mohsen S. Yeganeh, Peter W. Jacobs, Ian A. Cody, Steven W. Levine, Eric B. Sirota, Ramesh Gupta, Walter Weissman
  • Patent number: 8752623
    Abstract: In solvent-dominated recovery processes for recovering In situ oil, including bitumen, the produced fluid stream includes oil and solvent. The solvent is preferably recovered and reinjected into the reservoir. In previously described methods, solvent is removed from the oil/solvent mixture. In the present method, the oil/solvent mixture is first separated into a heavier stream and a lighter stream from which solvent is independently removed.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: June 17, 2014
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Eric B. Sirota, Owen J. Hehmeyer
  • Publication number: 20140083906
    Abstract: Provided is a process for cracking a hydrocarbon feedstock. The process having the steps of (a) continuously passing the feedstock through a vapor-liquid separator in which the feedstock is separated into a volatile stream and a non-volatile stream; (b) continuously passing the non-volatile stream to a cracker; and (c) continuously recycling a portion of the volatile stream to the feedstock. There is also an apparatus for cracking a hydrocarbon feedstock.
    Type: Application
    Filed: September 27, 2012
    Publication date: March 27, 2014
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventor: Eric B. Sirota
  • Patent number: 8613852
    Abstract: Self-compatible heavy oil streams are produced from converted and/or desulfurized fractions. In a preferred embodiment, an incompatibility stream is added to the converted and/or desulfurized stream to reduce the solubility number of the stream. After using a water wash to remove incompatible material, a lighter fraction is removed from the stream to increase the solubility number.
    Type: Grant
    Filed: December 14, 2010
    Date of Patent: December 24, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Daniel P. Leta, Walter D. Vann, David T. Ferrughelli, Eric B. Sirota, Howard Freund
  • Publication number: 20130281339
    Abstract: Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include from about 35 wt. % to about 60 wt. % of units derived from ethylene and at least 1.0 wt. % of one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers are substantially amorphous and have a polydispersity index of about 2.8 or less.
    Type: Application
    Filed: October 12, 2012
    Publication date: October 24, 2013
    Applicant: ExxonMobil Chemical Company
    Inventors: Rainer KOLB, Sudhin DATTA, Liehpao O. FARNG, Vera MINAK-BERNERO, Eric B. SIROTA, Thomas T. SUN, Mun Fu TSE
  • Publication number: 20130131256
    Abstract: Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity.
    Type: Application
    Filed: January 18, 2013
    Publication date: May 23, 2013
    Applicant: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Jo Ann M. Canich, Liehpao O. Farng, Rainer Kolb, Vera Minak-Bernero, Eric B. Sirota, Thomas T. Sun, Mun-Fu Tse, Manika Varma-Nair
  • Patent number: 8431012
    Abstract: The present invention is directed to a heavy hydrocarbon composition useful as a heavy lubricant oil base stock and to a heavy lubricant composition derived from the heavy lubricant oil base stock that remains clear and bright even after being cooled to room temperature and stored for an extended period of time.
    Type: Grant
    Filed: October 13, 2009
    Date of Patent: April 30, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Eric B. Sirota, Roland Saeger