Patents by Inventor Eric D. Metzger

Eric D. Metzger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11926696
    Abstract: Low molecular weight, high Tg resins, with applications including tire additives and adhesives. An oligomer is obtained by ring opening metathesis polymerization (ROMP) of a sterically encumbered cyclic monomer with an olefinic chain transfer agent. The sterically encumbered cyclic monomer and the olefinic chain transfer agent are present in the polymerization at a molar ratio of from 2:1 to about 40:1. Also, methods for making the oligomer by ROMP.
    Type: Grant
    Filed: February 2, 2021
    Date of Patent: March 12, 2024
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Eric D. Metzger, Mika L. Shiramizu, Brian J. Rohde, Alan A. Galuska
  • Publication number: 20230365479
    Abstract: Processes for converting C8 aromatic hydrocarbons. In some embodiments, a process for converting a hydrocarbon feed that can include C8 aromatic hydrocarbons can include feeding the hydrocarbon feed into a conversion zone and contacting the hydrocarbon feed at least partly in a liquid phase with an isomerization catalyst composition in the conversion zone under conversion conditions to effect isomerization of at least a portion of the C8 aromatic hydrocarbons to produce a conversion product rich in para-xylene. In some embodiments, the isomerization catalyst composition can include a zeolite (preferably a ZSM-5 zeolite) that can have a silica (SiO2) to alumina (AI2O3) molar ratio of 10 to 100, a total surface area of 200 m2/g to 700 m2/g, a micropore surface area of 50 m2/g to 600 m2/g, and an external surface area of 55 m2/g to 550 m2/g.
    Type: Application
    Filed: September 1, 2021
    Publication date: November 16, 2023
    Inventors: Eric D. Metzger, Ali A. Kheir, Maria Milina, Kathleen M. Keville
  • Publication number: 20230212094
    Abstract: Processes for converting C8 aromatic hydrocarbons. In some embodiments, the process can include feeding a gaseous hydrocarbon feed that can include meta-xylene, ortho-xylene, or both into a conversion zone. The process can also include contacting the gaseous hydrocarbon feed with a catalyst that can include a ZSM-11 zeolite in the conversion zone under conversion conditions to effect isomerization of at least a portion of any meta-xylene, or at least a portion of any ortho-xylene, or both to produce a conversion product rich in para-xylene. In some embodiments, the ZSM-11 zeolite can have an alpha value of 1 to 3,000 and a molar ratio of silica to alumina of from 15 to 200.
    Type: Application
    Filed: March 12, 2021
    Publication date: July 6, 2023
    Inventors: Eric D. Metzger, Mayank Shekhar, Wenyih F. Lai, Paul Podsiadlo, Dominick A. Zurlo, Kathleen M. Keville
  • Publication number: 20230023923
    Abstract: Disclosed are catalyst compositions comprising two or more metal elements with high performances for selective alkyl-demethylation of C2+-hydrocarbyl-substituted aromatics, processes for making such catalyst compositions, and alkyl-demethylation processes using same. Also disclosed are preferred processes for making alkyl-demethylation catalyst compositions including a high-temperature calcination step, and preferred alkyl-demethylation processes having a high H2/HC molar ratio.
    Type: Application
    Filed: December 1, 2020
    Publication date: January 26, 2023
    Inventors: Chuansheng Bai, Ali A. Kheir, Eric D. Metzger, Christian A. Diaz Urrutia, Meha Rungta, Umar Aslam
  • Publication number: 20220144725
    Abstract: Novel MEL framework type zeolites can be made to have small crystallite sizes and desirable silica/SiO2 molar ratios. Catalyst compositions comprising such MEL framework type zeolites can be particularly advantageous in isomerization C8 aromatic mixtures. An isomerization process for converting C8 aromatic hydrocarbons can advantageously utilize a catalyst composition comprising a MEL framework type zeolite.
    Type: Application
    Filed: March 25, 2020
    Publication date: May 12, 2022
    Inventors: Paul Podsiadlo, Eric D. Metzger, Wenyih F. Lai, Ali A. Kheir, Dominick A. Zurlo, Jocelyn A. Gilcrest, Kathleen M. Keville
  • Publication number: 20220134318
    Abstract: Novel MEL framework type zeolites can be made to have small crystallite sizes and desirable silica/SiCb molar ratios. Catalyst compositions comprising such MEL framework type zeolites can be particularly advantageous in isomerization C8 aromatic mixtures. An isomerization process for converting C8 aromatic hydrocarbons can advantageously utilize a catalyst composition comprising a MEL framework type zeolite.
    Type: Application
    Filed: March 25, 2020
    Publication date: May 5, 2022
    Inventors: Wenyih F. Lai, Paul Podsiadlo, Eric D. Metzger, Ivy D. Johnson, Ali A. Kheir, Dominick A. Zurlo, Kathleen M. Keville
  • Publication number: 20210253784
    Abstract: Low molecular weight, high Tg resins, with applications including tire additives and adhesives. An oligomer is obtained by ring opening metathesis polymerization (ROMP) of a sterically encumbered cyclic monomer with an olefinic chain transfer agent. The sterically encumbered cyclic monomer and the olefinic chain transfer agent are present in the polymerization at a molar ratio of from 2:1 to about 40:1. Also, methods for making the oligomer by ROMP.
    Type: Application
    Filed: February 2, 2021
    Publication date: August 19, 2021
    Inventors: Eric D. Metzger, Mika L. Shiramizu, Brian J. Rohde, Alan A. Galuska
  • Publication number: 20210246260
    Abstract: Low molecular weight, high Tg resins, with applications including tire additives and adhesives. An oligomer is obtained by ring opening metathesis polymerization (ROMP) of a sterically encumbered cyclic monomer with an olefinic chain transfer agent. The sterically encumbered cyclic monomer and the olefinic chain transfer agent are present in the polymerization at a molar ratio of from 2:1 to about 40:1. Also, methods for making the oligomer by ROMP.
    Type: Application
    Filed: February 2, 2021
    Publication date: August 12, 2021
    Inventors: Eric D. Metzger, Mika L. Shiramizu, Brian J. Rohde, Alan A. Galuska
  • Patent number: 10493441
    Abstract: Compositions and methods for selective olefin (e.g., ethylene) oligomerization comprising metal organic frameworks (MOFs) are generally provided In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core.
    Type: Grant
    Filed: September 14, 2016
    Date of Patent: December 3, 2019
    Assignee: Massachusetts Institute of Technology
    Inventors: Mircea Dinca, Eric D. Metzger, Carl K. Brozek