Patents by Inventor Erik-Andreas Klohr

Erik-Andreas Klohr has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8197699
    Abstract: The present invention describes a process for preparing methylhydroxyalkylcellulose having a small number of colored particles by separation of methylhydroxyalkylcellulose from aqueous suspension with subsequent washing of the methylhydroxyalkylcellulose using a specially equipped rotary pressure filter.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: June 12, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Martin Kowollik, Wolfgang Dannhorn, Erik-Andreas Klohr, Hartwig Schlesiger, Bernhard Kranz, Helmut Holste, Gerd Sonnenberg
  • Publication number: 20100099862
    Abstract: The present invention relates to a novel process for removing and purifying polysaccharide derivatives, preferably cellulose ethers, from a suspension using a continuous filter device with a multitude of working zones with intermediate resuspension of the filtercake.
    Type: Application
    Filed: April 18, 2007
    Publication date: April 22, 2010
    Inventors: Matthias Sprehe, Erik-Andreas Klohr, Martin Kowollik, Werner Viereck
  • Patent number: 7683110
    Abstract: The present invention relates to a process for preparing cellulose ether products which is characterized in that superabsorbent polymers (SAPs) are dried and milled, or mill-dried, conjointly with moist cellulose ether and also to the cellulose ether products resulting from this process.
    Type: Grant
    Filed: August 15, 2006
    Date of Patent: March 23, 2010
    Assignee: Dow Global Technologies Inc
    Inventors: Hartwig Schlesiger, Roland Bayer, Daniel Auriel, Jürgen Engelhardt, Frank Höhl, Erik-Andreas Klohr, Arne Henning Kull, Jörn-Bernd Pannek, Marc Oliver Schmidt
  • Patent number: 7402668
    Abstract: A process of preparing alkylhydroxyalkylcellulose (e.g., methylhydroxyethylcellulose and methylhydroxypropylcellulose) by reaction of cellulose in the presence of alkali metal hydroxide with an alkylating agent and a hydroxyalkylating agent is described. The process includes: (a) alkalizing cellulose by means of 0.9 to 2.9 equivalents of an alkali metal hydroxide I/AGU of the cellulose in the form of an aqueous alkali metal hydroxide solution, in the presence of a suspension medium containing at least 0.2 equivalents of an alkylating agent I/AGU of the cellulose; (b) reacting the alkalized cellulose of step (a) with alkylating agent I and a hydroxyalkylating agent at a temperature above 65° C.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: July 22, 2008
    Assignee: Dow Wolff Cellulosics GmbH
    Inventors: Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Hartwig Schlesiger, Jörn-Bernd Pannek
  • Publication number: 20070297280
    Abstract: The present invention relates to a novel double-cone mixer, if necessary of enamelled construction, and its use in the production and/or processing of polysaccharide products, preferably based on cellulose.
    Type: Application
    Filed: June 20, 2007
    Publication date: December 27, 2007
    Applicant: Wolff Cellulosics GmbH & Co. KG
    Inventors: Martin Kowollik, Andreas Rogenhofer, Wolfgang Dannhorn, Erik-Andreas Klohr
  • Publication number: 20070210014
    Abstract: The present invention describes a process for preparing methylhydroxyalkylcellulose having a small number of coloured particles by separation of methylhydroxyalkylcellulose from aqueous suspension with subsequent washing of the methylhydroxyalkylcellulose using a specially equipped rotary pressure filter.
    Type: Application
    Filed: September 15, 2006
    Publication date: September 13, 2007
    Applicant: Wolff Cellulosics GmbH & Co. KG
    Inventors: Martin Kowollik, Wolfgang Dannhorn, Erik-Andreas Klohr, Hartwig Schlesiger, Bernhard Kranz, Helmut Holste, Gerd Sonnenberg
  • Publication number: 20070088106
    Abstract: The present invention relates to a process for preparing cellulose ether products which is characterized in that superabsorbent polymers (SAPs) are dried and milled, or mill-dried, conjointly with moist cellulose ether and also to the cellulose ether products resulting from this process.
    Type: Application
    Filed: August 15, 2006
    Publication date: April 19, 2007
    Applicant: Wolff Cellulosics GmbH & Co. KG
    Inventors: Hartwig Schlesiger, Roland Bayer, Daniel Auriel, Jurgen Engelhardt, Frank Hohl, Erik-Andreas Klohr, Arne Kull, Jorn-Bernd Pannek, Marc Schmidt
  • Publication number: 20050282939
    Abstract: A description is given of particle compositions of polysaccharides and/or polysaccharide derivatives and at least one synthetic polymer and if appropriate other aids, characterized in that I. the particles contain a plurality of solid phases, II. the solid phase of the synthetic polymer being contained in the solid phase of the polysaccharide and/or polysaccharide derivative. Likewise a description is given of a process for producing these particle compositions and also of their use in construction material mixtures, for example mortars, plasters, fillers or thin-bed adhesives.
    Type: Application
    Filed: November 4, 2004
    Publication date: December 22, 2005
    Inventors: Gunter Weber, Meinolf Brackhagen, Hartwig Schlesiger, Grit Siegmund, Arne Kull, Hans-Jurgen Juhl, Roland Bayer, Erik-Andreas Klohr
  • Publication number: 20050240016
    Abstract: A process of producing methylhydroxyalkyl cellulose (MHAC) is described and involves in a first step (a), (i) introducing cellulose and a suspension medium into an autoclave, the suspension medium comprising 20 wt. % to 50 wt. % of chloromethane, based on the total weight of the said suspension medium, and (ii) spraying the cellulose in the autoclave with an aqueous alkali metal hydroxide solution, thereby alkalizing the cellulose and reacting the cellulose with chloromethane. In a second step (b), hydroxyalkylating agent is optionally introduced into the autoclave at a temperature above 60° C. In a third step (c) alkali metal hydroxide is introduced into the autoclave in a hyperstoichiometric quantity of at least +0.1 mol eq., relative to the chloromethane utilised. In a fourth step (d), at least one hydroxyalkylating agent is optionally introduced into the autoclave at a temperature above 60° C., and the introduced hydroxyalkylating agent is allowed to react for at least 20 min.
    Type: Application
    Filed: April 14, 2005
    Publication date: October 27, 2005
    Inventors: Hartwig Schlesiger, Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Marc Schmidt
  • Patent number: 6958393
    Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that: a) cellulose is alkalized with aqueous alkali metal hydroxide solution in the presence of a suspension medium, b) the alkalized cellulose is reacted with one or more alkylene oxides, c) then reacted with an alkyl halide present in the suspension medium d) subsequently or simultaneously the alkalized cellulose is reacted with a crosslinking agent in an amount of 0.0001 to 0.05 eq, where the unit “eq” represents the molar ratio of crosslinking agent relative to the anhydroglucose unit (AGU) of the cellulose used, and e) after, if appropriate, further addition of alkali metal hydroxide and/or alkylating agent, the resultant irreversibly crosslinked cellulose derivative is separated off from the reaction mixture, if appropriate purified and dried.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: October 25, 2005
    Assignee: Wolff Cellulosics GmbH & Co. KG
    Inventors: Hartwig Schlesiger, Arne Henning Kull, Erik-Andreas Klohr
  • Patent number: 6939960
    Abstract: A cellulose ether that is predominantly substituted in the C3 position of the anhydroglucose unit of the cellulose is described. In an embodiment of the present invention, the partial degree of substitution in the C3 position of the cellulose ether is ?60%, based on the total degree of substitution.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: September 6, 2005
    Assignee: Wolff Walsrode AG
    Inventors: Erik-Andreas Klohr, Jörg Neubauer, Wolfgang Koch, Klaus Szablikowski, Detmar Redeker, Wolfgang Wagenknecht, Fritz Loth
  • Patent number: 6852852
    Abstract: A method of producing a cellueose ether that is predominantly substituted in the C2 position of the anhydroglucose unit of the cellulose is described. The regioselectively substituted saccharide ester produced according to the method of the present invention is selected from the group consisting of oligo-saccharide ester and polysaccharide ester, having a partial average degree of substitution (AS) at the C2 position of its anhydroglucose unit of at least 90% relative to the total AS. Also described is a blood plasma expander comprising the regioselectively substituted ester.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: February 8, 2005
    Assignee: Wolff Walsrode AG
    Inventors: Erik-Andreas Klohr, Wolfgang Koch, Dieter Klemm, René Dicke
  • Publication number: 20040225035
    Abstract: The present invention encompasses cellulose ether blends comprising
    Type: Application
    Filed: January 30, 2004
    Publication date: November 11, 2004
    Inventors: Hartwig Schlesiger, Erik-Andreas Klohr, Wolfgang Dannhorn, Hans-Jurgen Juhl, Arne-Henning Kull, Gunter Weber, Peter Wolbers
  • Publication number: 20040127700
    Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that:
    Type: Application
    Filed: July 23, 2003
    Publication date: July 1, 2004
    Inventors: Hartwig Schlesiger, Arne Henning Kull, Erik-Andreas Klohr
  • Publication number: 20030162745
    Abstract: A regioselectively substituted member selected from the group consisting of oligo-saccharide ester and polysaccharide ester is disclosed. The ester has a partial average degree of substitution AS at the C2 position of its anhydroglucose unit of at least 90% relative to the total AS. Also disclosed is a method of producing the regioselectively substituted ester. The method entails reacting in the presence of a catalyst a dissolved or a highly swollen oligo-saccharide or polysaccharide with an esterification reagent.
    Type: Application
    Filed: October 17, 2002
    Publication date: August 28, 2003
    Inventors: Erik-Andreas Klohr, Wolfgang Koch, Dieter Klemm, Rene Dicke
  • Publication number: 20030065165
    Abstract: A process of preparing alkylhydroxyalkylcellulose (e.g., methylhydroxyethylcellulose and methylhydroxypropylcellulose) by reaction of cellulose in the presence of alkali metal hydroxide with an alkylating agent and a hydroxyalkylating agent is described. The process includes: (a) alkalizing cellulose by means of 0.9 to 2.9 equivalents of an alkali metal hydroxide I/AGU of the cellulose in the form of an aqueous alkali metal hydroxide solution, in the presence of a suspension medium containing at least 0.2 equivalents of an alkylating agent I/AGU of the cellulose; (b) reacting the alkalized cellulose of step (a) with alkylating agent I and a hydroxyalkylating agent at a temperature above 65° C.
    Type: Application
    Filed: July 17, 2002
    Publication date: April 3, 2003
    Inventors: Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Hartwig Schlesiger, Jorn-Bernd Pannek
  • Publication number: 20030032798
    Abstract: Cellulose ethers with a specific substitution pattern, wherein they are substituted predominantly in the C3 position of the anhydroglucose unit of the cellulose.
    Type: Application
    Filed: September 30, 2002
    Publication date: February 13, 2003
    Inventors: Erik-Andreas Klohr, Jorg Neubauer, Wolfgang Koch, Klaus Szablikowski, Detmar Redeker, Wolfgang Wagenknecht, Fritz Loth
  • Patent number: 6489468
    Abstract: A regioselectively substituted member selected from the group consisting of oligo-saccharide ester and polysaccharide ester is disclosed. The ester has a partial average degree of substitution AS at the C2 position of its anhydroglucose unit of at least 90% relative to the total AS. Also disclosed is a method of producing the regioselectively substituted ester. The method entails reacting in the presence of a catalyst a dissolved or a highly swollen oligo-saccharide or polysaccharide with an esterification reagent.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: December 3, 2002
    Assignee: Wolff Walsrode AG
    Inventors: Erik-Andreas Klohr, Wolfgang Koch, Dieter Klemm, René Dicke
  • Patent number: 6482940
    Abstract: A cellulose ether that is predominantly substituted in the C3 position of the anhydroglucose unit of the cellulose is described. In an embodiment of the present invention, the partial degree of substitution in the C3 position of the cellulose ether is ≧60%, based on the total degree of substitution. Also described is a process for preparing the cellulose ether of the present invention. The process involves, reacting cellulose, dissolved in N-methylmorpholine-N-oxide monohydrate (NMMNO) and optionally other inert organic solvents, with alkylation reagents. The reaction takes place in the presence of: (i) an insoluble solid phase catalyst, e.g., solid ion exchange resins based on polystyrene having quaternary ammonium groups; (ii) stabilizers, e.g., propyl gallate; and (iii) optionally additional soluble co-catalysts, e.g., trimethylbenzylammonium hydroxide.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: November 19, 2002
    Assignee: Wolff Walsrode AG
    Inventors: Erik-Andreas Klohr, Jörg Neubauer, Wolfgang Koch, Klaus Szablikowski, Detmar Redeker, Wolfgang Wagenknecht, Fritz Loth