Abstract: Method for preparing a synthesis gas suitable for the synthesis of ammonia or methanol, the method comprises the step of feeding to the radiant portion of a primary reformer an oxygen-enriched air obtained by mixing air with an oxygen stream generated by water electrolysis.

Abstract: A process for producing methanol from an adjusted make-up gas comprising the steps of adjusting the stoichiometric number of the make-up gas fed to the methanol loop with a first stream of hydrogen recovered from a minor portion of makeup gas separated from the main stream, and a second stream of hydrogen recovered from the loop purge; the process further comprises the step of feeding at least a portion of a tail gas rich in methane to a reforming stage for use as a feedstock to produce the make-up gas.

Abstract: A process of making ammonium nitrate from nitric acid and ammonia in a tubular reactor internally coated with a ceramic coating.

Abstract: Process including the production of a hydrogen-containing synthesis gas by conversion of a hydrocarbon feedstock, wherein said process has a heat input provided by combustion of a plurality of process fuel streams and said plurality of process fuel streams comprises at least one fuel stream of ammonia. Combustion of said at least one fuel stream of ammonia is performed non-catalytically in at least one fired equipment.

Abstract: Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock, and the Wobbe Index of said fuel is increased by a step of carbon dioxide removal or methanation.

Abstract: A process for the catalytic oxidation of ammonia, comprising: passing an ammonia-containing gas, in the presence of oxygen, over a catalyst contained in a reactor, obtaining a process gas containing nitrogen oxides, and cooling said process gas with a heat exchanger accommodated in the reactor, wherein a portion of said process gas, located in the shell side, bypasses the heat exchanger and forms a hot current which mixes with cooled gas downstream the heat exchanger, and the bypass is regulated on the basis of a target outlet temperature of the mixed process gas.

Abstract: Radial or axial-radial flow catalytic chemical reactor comprising a cylindrical shell and at least one catalytic bed and comprising a plurality of perforated tubes, said tubes having an open end communicating with an inlet of a gaseous flow of reagents in the reactor, said tubes being provided with a plurality of holes on their side surface, said tubes being arranged around the catalytic bed so as to form an outer wall which bounds the catalytic bed and which distributes the reagents inside said bed; each of said tubes being formed by means of longitudinal or helical butt welding of a perforated strip.

Abstract: Reactor for catalytic chemical reactions comprising a catalyst bed with an annular-cylindrical form crossed by a radial flow or mixed axial-radial flow, wherein the bed is delimited by cylindrical walls made gas-permeable by means of slits and the catalyst bed is formed by particles of catalyst with a nominal minimum size such that: the ratio between a transverse dimension of the slits and the nominal minimum size of the particles of catalyst is smaller than or equal to 0.6; the catalyst bed contains no more than 3% by weight of particles with an actual size smaller than said nominal size.

Abstract: Process for the synthesis of ammonia comprising the steps of reforming of a hydrocarbon feedstock into a raw product gas, purification of said raw product gas obtaining a make-up synthesis gas, conversion of said synthesis gas into ammonia; said purification includes shift conversion of carbon monoxide into carbon dioxide and the reforming process requires a heat input which is at least partially recovered from at least one of said step of shift conversion, which is carried out with a peak temperature of at least 450° C., and said step of conversion into ammonia.

Abstract: Integrated process for the synthesis of ammonia and nitric acid including: a) production of an ammonia make-up synthesis gas, comprising steam reforming of a hydrocarbon feedstock under provision of steam reforming heat; catalytic conversion of said make-up synthesis gas into ammonia; catalytic oxidation of a stream of ammonia obtaining a process gas; absorption of said process gas with water obtaining nitric acid, wherein at least a portion of the steam reforming heat is recovered from said hot process gas.

Abstract: Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

Abstract: Process including the production of a hydrogen-containing synthesis gas by conversion of a hydrocarbon feedstock, wherein said process has a heat input provided by combustion of a plurality of process fuel streams and said plurality of process fuel streams comprises at least one fuel stream of ammonia. Combustion of said at least one fuel stream of ammonia is performed non-catalytically in at least one fired equipment.

Abstract: A process for producing ammonia make-up synthesis gas and a procedure for revamping a front-end of an ammonia plant for producing ammonia make-up synthesis gas are disclosed, wherein the make-up synthesis gas is produced by means of steam reforming of a hydrocarbon gaseous feedstock; said front-end includes a primary reformer, a secondary reformer, a shift conversion section, a CO2 removal section and optionally a methanation section; a shell-and-tube gas-heated reformer is installed after said secondary reformer, and a portion of the available feedstock is reformed in the tubes of said gas-heated reformer, and heat is provided to the shell side of said gas-heated reformer by at least a portion of product gas leaving the secondary reformer, possibly mixed with product gas leaving the tubes of said gas-heated reformer.

Abstract: A method for revamping a reforming section of a chemical plant, wherein the reforming section treats a first hydrocarbon feed stream, and an apparatus downstream of the reforming section, designed as a steam generator, is converted into a GHR by means of the following steps: replacing the heat exchange bodies of said steam generator with heat exchange bodies containing a reforming catalyst; directing a second hydrocarbon feed stream inside said heat exchange bodies containing catalyst; extracting a reformed gas stream from said heat exchange bodies.

Abstract: A process for purification of a current of hydrogen synthesis gas (100), particularly in the front-end of an ammonia plant, wherein said gas contains hydrogen and minor amounts of carbon monoxide, carbon dioxide, water and impurities, said process including steps of methanation (13) of said current (100), converting residual amounts of carbon monoxide and carbon dioxide to methane and water, dehydration (14) of the gas to remove water, and then a cryogenic purification (15) such as liquid nitrogen wash, to remove methane and Argon; a corresponding plant and method for revamping an ammonia plant are also disclosed.

Abstract: Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

Abstract: Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

Abstract: Process for the synthesis of ammonia comprising the steps of reforming of a hydrocarbon feedstock into a raw product gas, purification of said raw product gas obtaining a make-up synthesis gas, conversion of said synthesis gas into ammonia; said purification includes shift conversion of carbon monoxide into carbon dioxide and the reforming process requires a heat input which is at least partially recovered from at least one of said step of shift conversion, which is carried out with a peak temperature of at least 450° C., and said step of conversion into ammonia.

Abstract: Process for the synthesis of ammonia comprising the steps of reforming of a hydrocarbon feedstock into a raw product gas, purification of said raw product gas obtaining a make-up synthesis gas, conversion of said synthesis gas into ammonia; said purification includes shift conversion of carbon monoxide into carbon dioxide and the reforming process requires a heat input which is at least partially recovered from at least one of said step of shift conversion, which is carried out with a peak temperature of at least 450° C., and said step of conversion into ammonia.

Abstract: A shell-and-tube apparatus (1), suitable for use as a waste heat boiler, comprising a vessel with an exchanging section (2) and a separating section (3), wherein: said exchanging section (2) contains a bundle of U-tubes (4) fed with an evaporable liquid medium such as water (W) and exposed to a hot gas (G) flowing in a hot chamber around said tubes, so that said medium is partially evaporated in the tubes while recovering heat from hot gas flowing in the hot chamber (7); said separating section (3) comprises a collection chamber (16) in communication with outlet of the tubes (4) to receive the partially evaporated medium leaving the tubes; said separating section (3) is arranged to provide separation of vapour fraction and liquid fraction from the partially evaporated medium at least partially by gravity; the apparatus also comprises means for controlling the liquid level in the collection chamber and for a partial recycle of the non-evaporated liquid.