Abstract: Provided herein are compositions which are useful as catalysts in the production of polyisocyanurate foams. The compositions of the invention comprise N, N, N?-trimethylaminoethyl-ethanolanine in combination with one other catalysts useful in promoting trimerization of isocyanates. By promoting trimerization, isocyanate content of the foam is decreased which leads to a foam having better bum properties over prior art isocyanurate foams. Decreasing the isocyanate content of a foam should also lead to quicker de-mold of a molded foam because of reduced stickiness.