Patents by Inventor Ernst Grigat
Ernst Grigat has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 6472497Abstract: Thermoplastic starch compositions formed by converting native starch or starch derivatives into thermoplastic starch by at least one hydrophobic biodegradable polymer that functions as a plasticizer for starch. The hydrophobic biodegradable polymer may be a polymer selected from the following list: an aliphatic polyester, a copolyester with aliphatic and aromatic blocks, a polyester amide, a polyester urethane, a polyethylene oxide polymer and/or a polyglycol, and/or mixtures of these. When the starch, such as in particular native starch or derivatives thereof, is mixed in the melt with the hydrophobic biodegradable polymer as a plasticizer or swelling agent, to homogenize the mixture, the water content is reduced to less than about 5% by weight based on the weight of the mixture.Type: GrantFiled: April 30, 2001Date of Patent: October 29, 2002Assignee: Biotec Biologische Naturverpackungen & Co KGInventors: Jurgen Loercks, Winfried Pommeranz, Harald Schmidt, Ralf Timmermann, Ernst Grigat, Wolfgang Schulz-Schlitte
-
Publication number: 20010039303Abstract: Thermoplastic starch compositions formed by converting native starch or starch derivatives into thermoplastic starch by at least one hydrophobic biodegradable polymer that functions as a plasticizer for starch. The hydrophobic biodegradable polymer may be a polymer selected from the following list: an aliphatic polyester, a copolyester with aliphatic and aromatic blocks, a polyester amide, a polyester urethane, a polyethylene oxide polymer and/or a polyglycol, and/or mixtures of these. When the starch, such as in particular native starch or derivatives thereof, is mixed in the melt with the hydrophobic biodegradable polymer as a plasticizer or swelling agent, to homogenize the mixture, the water content is reduced to less than about 5% by weight based on the weight of the mixture.Type: ApplicationFiled: April 30, 2001Publication date: November 8, 2001Inventors: Jurgen Loercks, Winfried Pommeranz, Harald Schmidt, Ralf Timmermann, Ernst Grigat, Wolfgang Schulz-Schlitte
-
Patent number: 6307003Abstract: The present invention relates to a compostable adhesive, to a method of producing the same, and to the use of the adhesive for the adhesive bonding of materials.Type: GrantFiled: March 15, 1999Date of Patent: October 23, 2001Assignees: Bayer AG, Biotec BiologischeInventors: Ernst Grigat, Karsten-Josef Idel, Uwe Westeppe, Wolfgang Schulz-Schlitte, Winfried Pommeranz, Jürgen Lörcks, Harald Schmidt
-
Patent number: 6235815Abstract: For converting native starch or starch derivatives into thermoplastic starch, added to the starch is at least one hydrophobic biodegradable polymer. This hydrophobic biodegradable polymer, which serves as a plasticizer or swelling agent, may be a polymer selected from the following list: an aliphatic polyester, a copolyester with aliphatic and aromatic blocks, a polyester amide, a polyester urethane, a polyethylene oxide polymer and/or a polyglycol, and/or mixtures of these. When the starch, such as in particular native starch or derivatives thereof, is mixed in the melt with the hydrophobic biodegradable polymer as a plasticizer or swelling agent, to homogenize the mixture, the water content is reduced to <1% by weight based on the weight of the mixture.Type: GrantFiled: December 18, 1998Date of Patent: May 22, 2001Assignee: Bio-tec Biologische Naturverpackungen & Co. KGInventors: Jurgen Loercks, Winfried Pommeranz, Harald Schmidt, Ralf Timmermann, Ernst Grigat, Wolfgang Schulz-Schlitte
-
Patent number: 6071984Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: June 25, 1998Date of Patent: June 6, 2000Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
-
Patent number: 5827905Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: September 18, 1996Date of Patent: October 27, 1998Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
-
Patent number: 5726227Abstract: Thermoplastic moulding compositions containingA) polymers selected from the group comprising polyolefines, styrene polymers, polyamides, polyalkyl methacrylates, polyphenylene sulphides, ABS graft polymers, and thermoplastic polyurethanes, andB) esters of phosphorous acid which contain at least one oxetane group and at least one radical of a dihydric or polyhydric phenol per molecule, andoptionallyC) fillers and reinforcing materials,D) flame retardant additives,E) elastomeric modifiers.Type: GrantFiled: November 20, 1996Date of Patent: March 10, 1998Assignee: Bayer AGInventors: Herbert Magerstedt, Ernst Grigat
-
Patent number: 5455311Abstract: The object of the present invention is the production of thermoplastically workable copolymers capable of being composted, characterized in that they consist of partially crystalline soft segments formed from aliphatic esters and also of amorphous hard segments and that the proportion of soft segments amounts to 70% to 95% by weight.Type: GrantFiled: August 8, 1994Date of Patent: October 3, 1995Assignee: Bayer AGInventors: Ernst Grigat, Ralf Dujardin, Ralf Timmermann, Hans-Georg Rast
-
Patent number: 5256702Abstract: A method of foaming thermoplastic aromatic polycarbonates is disclosed. Accordingly, a polycarbonate resin is mixed with 0.01 to 10%, the percent being relative to the total weight of polycarbonate resin and polysaccharide, of a particular polysaccharide and the mixture then processed thermoplastically without the application of negative pressure in an extruder, at temperatures of 180.degree. C. to 320.degree. C., or in an injection molding machine, at temperatures of 190.degree. C. to 330.degree. C., to obtain foamed molded articles.Type: GrantFiled: April 14, 1993Date of Patent: October 26, 1993Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Wolfgang Ebert, Burkhard Kohler, Wolfgang Beer, Ralf Dujardin, Klaus Horn
-
Patent number: 5223548Abstract: A method of foaming thermoplastic aromatic polycarbonates is disclosed. Accordingly, a polycarbonate resin is mixed with 0.01 to 10%, the percent being relative to the total weight of polycarbonate resin and polysaccharide, of a particular polysaccharide and the mixture then processed thermoplastically without the application of negative pressure in an extruder, at temperatures of 180.degree. C. to 320.degree. C., or in an injection molding machine, at temperatures of 190.degree. C. to 330.degree. C., to obtain foamed molded articles.Type: GrantFiled: December 11, 1992Date of Patent: June 29, 1993Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Wolfgang Ebert, Burkhard Kohler, Wolfgang Beer, Ralf Dujardin, Klaus Horn
-
Patent number: 5009925Abstract: Magnetic recording carriers having improved mechanical properties are obtained by using, as dispersing agents, compounds corresponding to the general formula ##STR1## which are attached to the magnetic pigment by their SO.sub.3 H group and which have reactive groups by which they are linked to the reactive groups of the polymeric binder through a difunctional or higher functional isocyanate.Type: GrantFiled: October 5, 1988Date of Patent: April 23, 1991Assignee: Agfa Gevaert AktiengesellschaftInventors: Ernst Grigat, Walter Meckel, Burkhard Nippe
-
Process for producing higher molecular weight amino compounds having reduced monomeric amine content
Patent number: 4855504Abstract: High molecular weight amines having reduced low molecular weight amine contents are obtained by reacting a mixture of (1) a high molecular weight amine and (2) a low molecular weight amine with (3) an isocyanate in quantities such that from 0.5 to 10 equivalents of isocyanate are present for each equivalent of low molecular weight amine. The product of high molecular weight amines is particularly useful in the production of isocyanate addition products such as polyurethane plastics and foams.Type: GrantFiled: September 23, 1985Date of Patent: August 8, 1989Assignee: Bayer AktiengesellschaftInventors: Werner Rasshofer, Ernst Grigat, Gerhard Grogler, Heinrich Hess, Richard Kopp -
Patent number: 4511680Abstract: A process for the continuous glycolytic cleavage of polyurethane plastics waste in multi-shaft screw machines by the addition of optionally preheated diols, at a degradation temperature of 250.degree. C., while maintaining a pressure at least such that the polyurethane-diol mixture is in the liquid phase, by the discharge of the glycolysate mixture after short residence times of from 2 to 30 minutes in the reaction screw, and by rapid cooling of the glycolysate mixture.Type: GrantFiled: August 24, 1983Date of Patent: April 16, 1985Assignee: Bayer AktiengesellschaftInventors: Georg Niederdellmann, Ernst Grigat
-
Patent number: 4399236Abstract: The present invention is directed to a process for separating polyurethane hydrolyzates, preferably polyurethane foam hydrolyzates, into substantially amine-free foamable polyethers and diamines, comprising (a) (i) briefly expanding a hot polyurethane hydrolyzate obtained in a continuous screw extruder to normal pressure or in vacuo and, without using readily volatile components (ii) spraying said hydrolyzate directly into a tubular coil evaporator which is heated to 180.degree.-300.degree. C. and at the end of which a pressure of from 0.1 to 20 mbar is applied and (iii) separating a hydrolyzate containing less than 1% by weight of NH.sub.Type: GrantFiled: September 4, 1981Date of Patent: August 16, 1983Assignee: Bayer AktiengesellschaftInventors: Georg Niederdellmann, Norbert Roemer, Jurgen Schenk, Hartmut Hetzel, Ernst Grigat
-
Patent number: 4282367Abstract: The instant invention is directed to a process for the separation of polyurethane hydrolysates into polyamines and polyols which can be used again for the production of polyurethanes, comprising introducing gaseous hydrogen chloride into the hydrolysate mixture which has optionally been diluted with an inert solvent, and removing the precipitated amine salt by filtration, characterized in that(a) gaseous hydrogen chloride is optionally first introduced into the hydrolysate in a quantity of from 0.02 to 0.07 mol per amine equivalent, the reaction mixture is filtered and the filter residue is discarded, then(b) from 0.20 to 0.Type: GrantFiled: December 19, 1979Date of Patent: August 4, 1981Assignee: Bayer AktiengesellschaftInventors: Georg Niederdellmann, Norbert Roemer, Ernst Grigat
-
Patent number: 4195132Abstract: The present invention relates to novel, substantially insoluble and infusible plastics which are cross-linked by way of triazine rings and, optionally, by way of tri-substituted bis-oxymethylene urea groups or urethane groups.Type: GrantFiled: May 5, 1977Date of Patent: March 25, 1980Assignee: Bayer AktiengesellschaftInventors: Rudolf Sundermann, Gunther Rottloff, Ernst Grigat
-
Patent number: 4136967Abstract: An apparatus for hydrolytic degradation of plastics in which plastic material is deposited into a tubular housing via a feed hopper. An elongated screw shaft has a first section in the form of a high pitch screw thread disposed below the feed hopper to receive and advance the material to a second section. The second section of the screw shaft is in the form of a lower pitch thread for compressing the plastic material and transferring it to a longer, third section in the form of kneading discs, from which material passes through an outlet nozzle section to a cyclone separator where trapped gases and liquid may be withdrawn. The tubular housing is vented upstream of the feed hopper and a water inlet pipe is disposed adjacent to the second section of the screw shaft, downstream of the feed hopper. The outlet nozzle section is provided with pressure measuring and regulating means and a liquid level measuring and regulating device.Type: GrantFiled: July 18, 1977Date of Patent: January 30, 1979Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hartmut Hetzel
-
Patent number: 4094852Abstract: A polytrimerizable mixture of30 to 99.9% by weight of at least one aromatic, polyfunctional cyanic acid ester or a prepolymer thereof, and0.1 to 70% by weight of at least one high-boiling ester with a boiling point above 250.degree. C at 760 Torr,Said mixture results in polytriazines having a significant improvement in elasticity, flexibility and resistance to hydrolysis.Type: GrantFiled: July 22, 1976Date of Patent: June 13, 1978Assignee: Bayer AktiengesellschaftInventors: Rudolf Sundermann, Gunther Rottloff, Ernst Grigat, Rolf Putter
-
Patent number: 4094861Abstract: Non-inflammable, high molecular weight polytriazines are obtained by condensing less than 3 mols of polyfunctional (amino)phenols with 1 mol phosphorus (oxy) trihalide in the presence of a base, subsequently reacting the still free primary amino or phenolic hydroxyl groups with cyanogen halide in the presence of a base to form cyanamide or organic ester groups and polymerizing thereafter the reaction product at a temperature of up to 350.degree. C, optionally in the presence of polymerization promoters. The polytriazine may be used as plastics and lacquers.Type: GrantFiled: July 22, 1976Date of Patent: June 13, 1978Assignee: Bayer AktiengesellschaftInventors: Rudolf Sundermann, Gunther Rottloff, Ernst Grigat, Rolf Putter
-
Patent number: 4066577Abstract: High molecular weight temperature-resistant polymers of polytriazine structure obtained by heating cyanamides of the formula Ir -- (nh-cn).sub.nin which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical, optionally interrupted by oxygen and n is a number from 2 to 5, with polyfunctional, aromatic cyanic acid esters into a fusible or in organic solvents soluble polymeric N-cyano-isourea ether and completing the reaction at elevated temperatures and optionally in the presence of a catalyst to form said polymer of polytriazine structure.Type: GrantFiled: July 22, 1976Date of Patent: January 3, 1978Assignee: Bayer AktiengesellschaftInventors: Rudolf Sundermann, Gunther Rottloff, Ernst Grigat