Abstract: A process for producing a coated lightweight metal substrate, in particular, an aluminium substrate, by a wet-chemical application of a coating composition to the lightweight metal substrate and thermally curing the coating composition is provided. A coating material composition is also described that is formed from a sol-gel material.

Abstract: A process for producing a coated lightweight metal substrate, in particular, an aluminium substrate, by a wet-chemical application of a coating composition to the lightweight metal substrate and thermally curing the coating composition is provided. A coating material composition is also described that is formed from a sol-gel material.

Abstract: The invention relates to a composition for producing abrasion-resistant and alkali-resistant layers or molded bodies having a low-energy surface, said composition comprising a) a hardenable binder system containing at least one organic polymer or oligomer comprising at least one functional group, or a precursor thereof, b) at least one fluorine-containing polymer or oligomer containing at least one functional group that can react with a functional group of the binder system, and c) inorganic particles, and to the products thus obtained. The coatings and molded bodies obtained are especially suitable for surfaces to be kept clean.

Abstract: Disclosed is a process of preparing a moulded article, comprising 1) hydrolyzing a) at least one silane having one non-hydrolysable organic group, and b) at least one compound selected from b1) a silane having two non-hydrolysable organic groups, and b2) a hydrolysable polysiloxane, or a mixture thereof, and c) optionally at least one silane having no non-hydrolysable organic group, to prepare a composite composition comprising a hydrolysate or condensate, 2) placing the composite composition in a mould, 3) curing the composite composition to increase the degree of condensation, 4) removing the moulded article from the mould, and 5) heat treating the moulded article at a temperature of at least 100° C. The moulded article is preferably an optical lens which may be used for automobile headlights.

Abstract: An article which comprises a surface of light metal. The surface is provided with an alkali-resistant protective coat comprising (a) an oxide layer which comprises silicon and boron as a basecoat and (b) an oxide layer which comprises silicon as a vitreous topcoat.

Abstract: Disclosed is a process of preparing a moulded article, comprising 1) hydrolysing a) at least one silane having one non-hydrolysable organic group, and b) at least one compound selected from b1) a silane having two non-hydrolysable organic groups, and b2) a hydrolysable polysiloxane, or a mixture thereof, and c) optionally at least one silane having no non-hydrolysable organic group, to prepare a composite composition comprising a hydrolysate or condensate, 2) placing the composite composition in a mould, 3) curing the composite composition to increase the degree of condensation, 4) removing the moulded article from the mould, and 5) heat treating the moulded article at a temperature of at least 100° C. The moulded article is preferably an optical lens which may be used for automobile headlights.

Abstract: The invention relates to amphiphilic, nanoscalar particles comprising lipophilic hydrolyzable groups on their surface. The invention also relates to methods for producing amphiphilic, nanoscalar particles and to compositions containing said particles.

Abstract: An article which comprises a surface of light metal. The surface is provided with an alkali-resistant protective coat comprising (a) an oxide layer which comprises silicon and boron as a basecoat and (b) an oxide layer which comprises silicon as a vitreous topcoat.

Abstract: Substrates comprising a photocatalytic layer containing TiO2 are produced using TiO2 particles which may optionally be doped with metallic or non-metallic elements or compounds. The photocatalytic layer exhibits a concentration gradient of the TiO2 particles. An organically modified inorganic hybrid layer may be provided between the substrate and the photocatalytic layer.

Abstract: The invention relates to amphiphilic, nanoscalar particles comprising lipophilic hydrolyzable groups on their surface. The invention also relates to methods for producing amphiphilic, nanoscalar particles and to compositions containing said particles.

Abstract: The invention relates to a composition for producing abrasion-resistant and alkali-resistant layers or moulded bodies having a low-energy surface, said composition comprising a) a hardenable binder system containing at least one organic polymer or oligomer comprising at least one functional group, or a precursor thereof, b) at least one fluorine-containing polymer or oligomer containing at least one functional group that can react with a functional group of the binder system, and c) inorganic particles, and to the products thus obtained. The coatings and moulded bodies obtained are especially suitable for surfaces to be kept clean.

Abstract: Substrates comprising a photocatalytic layer containing TiO2 are produced using TiO2 particles which may optionally be doped with metallic or non-metallic elements or compounds. The photocatalytic layer exhibits a concentration gradient of the TiO2 particles. An organically modified inorganic hybrid layer may be provided between the substrate and the photocatalytic layer.

Abstract: A process for preparing a composition for producing nanostructured mouldings and layers comprises contacting an aqueous and/or alcoholic sol of a compound of an element selected from silicon sand metals of the main groups and transition groups of the Periodic Table with species possessing hydrolysable alkoxy groups and comprising at least one organically modified alkoxysilane or a precondensate derived therefrom, under conditions which lead to (further) hydrolysis of the species, and subsequent removal of the alcohol formed and any alcohol already present originally. The process is characterized in that the alcohol is removed in an amount such that the residual alcohol content of the composition is not more than 20% by weight.

Abstract: Described are nanostructured molded articles and layers which are produced by a wet chemical process comprising the following steps: a) provision of a free-flowing composition containing solid nanoscaled inorganic particles having polymerizable and/or polycondensable organic surface groups; b) introduction of said composition of step a) into a mold; or b2) application of said composition of step a) onto a substrate; and c) polymerization and/or polycondensation of the surface groups of said solid particles with formation of a cured molded article or a cured layer.

Abstract: A process is disclosed for the production of compounds based on hydrolyzable silanes containing epoxy groups. The process involves adding one of the following substances to a pre-hydrolyzed silicon compound A with at least one hydrolytically non-separable group which includes an epoxy ring: i) a particulate substance B which can be selected from oxides, oxyhydrates, nitrides or carbides of Si, Al and B, and of transition metals, the particle size being 1-100 nm; ii) a surface-active agent, preferably non-ionic; iii) an aromatic polyol with an average molecular weight not exceeding 1000. The compounds obtained through this process can be used to produce coatings and molded bodies with a range of properties, in particular high scratch resistance, lasting hydrophilic characteristics, corrosion resistance, good adhesion and transparency.

Abstract: A process is disclosed for the production of compounds based on hydrolyzable silanes containing epoxy groups. The process involves adding one of the following substances to a pre-hydrolyzed silicon compound A with at least one hydrolytically non-separable group which includes an epoxy ring in the presence of an alcoholate of zirconium or aluminum: i) a particulate substance B which can be selected from oxides, oxyhydrates, nitrides or carbides of Si, Al and B, and of transition metals, the particle size being 1-100 nm;ii) a surface-active agent, preferably non-ionic;iii) an aromatic polyol with an average molecular weight not exceeding 1000, the resulting compounds being useful to produce coatings and molded bodies with a range of properties, in particular high scratch resistance, lasting hydrophilic characteristics, corrosion resistance, good adhesion and transparency.

Abstract: TiN sintered bodies and coatings are produced by dispersing nanocrystalline TiN powder in water and/or a polar organic solvent as dispersing agent in the presence of at least one low molecular organic compound having at least one functional group which can react or interact with groups on the surface of the powder particles, removing the dispersing agent and sintering the surface-modified TiN which has been processed into green bodies or coatings before or after the removal of the dispersing agent.

Abstract: Metal and ceramic sintered bodies and coatings are produced using a combination of:(a) nanocrystalline metal or ceramic powder wherein less than 1% of the individual particles have a deviation of more than 40%, and no individual particles have a deviation of more than 60%, from the average grain size, and(b) at least one low molecular-weight organic compound having at least one functional group that can react and/or interact with groups present on the surface of the powder particles, the materials (a) and (b) being dispersed in water and/or a polar organic solvent as dispersion medium.

Abstract: A process for producing UV or UV/IR or IR/UV-hardened coatings on substrates by applying a coating compound to the substrate to be coated and by the action of UV radiation, or combined UV/IR or IR/UV radiation, as well as UV or UV/IR or IR/UV-hardenable coating compounds comprising a component A, which is a solution of a complexed, metal organic Ti or Zr compound with polymerizable ligands, a component B, which is a hydrolyzate of one or more radically polymerizable alkoxy silanes of general formula ##STR1## and 0.1 to 5% by weight of a component C, which is an initiator for the polymerization.

Abstract: Composite materials that contain nanoscaled particles are produced in thata) a compound, which is soluble in the solvent and belongs to a metal of the groups 6 to 15 of the periodic system or lanthanides,is reacted in an organic solvent withb) a precipitating reagent in order to form antimonides, arsenides, chalcogenides, halogenides or phosphides of the metal of the metal compound (a) in the present ofc) a bifunctional compound, which exhibits at least one electron pair-donor group and at least one group, which can be converted through polymerization or polycondensation into an organic or inorganic network;the resulting stabilized sol of nanoscaled particles is mixed withd) a compound, which can be polymerized or cured thermally or photochemically into a polymer, ande) a polymerization initiator;a hydrolysis and polycondensation of the optionally present groups that can be converted into an inorganic network is conducted; and the material is cured thermally of photochemically.