Abstract: An optical substrate is provided with a surface of a desired shape by coating the surface with a thin layer of an optical glass and subsequently modifying the shape of the external surface of the layer. In preferred embodiments, the temperature of the substrate is maintained at substantially less than 400° C., the substrate is an optical component other than a simple window, and the refractive index o the optical glass is within 20% of the refractive index of the material providing the surface to be coated. One particular use is when both the substrate (e.g. a non-linear optical layer) and the optical glass are optically transmissive in the near infra-red and/or mid infra-red ranges. The glass layer can compensate for physical imperfections in the surface. It can be polished to optical quality, or provide with detail across the coated surface, e.g. as a “moth-eye” anti-reflection layer, or a diffractive or interference structure.